Publications

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2021

Scholarly publications

van Koten, G., Kirchner, K., & Moret, M. E. (Eds.) (2021). Metal-Ligand Co-operativity: Catalysis and the Pincer-Metal Platform. (1 ed.) (Topics in Organometallic Chemistry; Vol. 68). Springer Cham. https://doi.org/10.1016/B978-0-444-82312-0.50004-9

Canty, A. J., Ariafard, A., & van Koten, G. (2021). Computational Study of Bridge Splitting, Aryl Halide Oxidative Addition to PtII , and Reductive Elimination from PtIV: Route to Pincer-PtII Reagents with Chemical and Biological Applications. Chemistry-A European Journal, 27(62), 15426-15433. https://doi.org/10.1002/chem.202102687

Batema, G. D., Korstanje, T. J., Guillena, G., Rodríguez, G., Lutz, M., Van Klink, G., Gossage, R. A., & Van Koten, G. (2021). Replacing the Z-phenyl Ring in Tamoxifen® with a para-Connected NCN Pincer-Pt-Cl Grouping by Post-Modification. Molecules, 26(7), 1-18. [1888]. https://doi.org/10.3390/molecules26071888

2018

Scholarly publications

Batema, G. D., van Walree, C. A., van Klink, G. P. M., de Mello Donegá, C., Meijerink, A., Perez-Moreno, J., Clays, K., & van Koten, G. (2018). Octupolar organometallic Pt(II) NCN-pincer complexes; Synthesis, electronic, photophysical, and NLO properties. Journal of Organometallic Chemistry, 867, 246-252. https://doi.org/10.1016/j.jorganchem.2017.12.028

2017

Scholarly publications

Van Koten, G. (2017). Highlights of 45 years of research: A personal account. Journal of Organometallic Chemistry, 845, 4-18. https://doi.org/10.1016/j.jorganchem.2017.05.001

2015

Scholarly publications

Chase, P. A., Gossage, R. A., & van Koten, G. (2015). Modern organometallic multidentate ligand design strategies: The birth of the privileged “pincer” ligand platform. Topics in Organometallic Chemistry, 54, 1-16. https://doi.org/10.1007/3418_2015_131

Jastrzebski, J. T. B. H., Van Klaveren, M., & Van Koten, G. (2015). Stable Divalent Triarylstannates R₃SnLi Derived from 2-[(Dimethylamino)methyl]phenyllithium and SnCl₂ or R₂Sn. Organometallics, 34(11), 2600-2607. https://doi.org/10.1021/om5012215

2014

Scholarly publications

Batema, G. D., Lutz, M., Spek, A. L., van Walree, C. A., van Klink, G. P. M., & van Koten, G. (2014). Organometallic benzylidene anilines: donor-acceptor features in NCN-pincer Pt(II) complexes with a 4-(E)-[(4-R-phenyl)imino]methyl substituent. Dalton Transactions, 43(32), 12200-12209. https://doi.org/10.1039/c4dt01023j

Pijnenburg, N. J. M., Tomás-Mendivil, E., Mayland, K. E., Kleijn, H., Lutz, M., Spek, A. L., Van Koten, G., & Klein Gebbink, B. (2014). Monomeric and dendritic second generation Grubbs- and Hoveyda-Grubbs-type catalysts for olefin metathesis Metallodendrimers Special Issue. Inorganica Chimica Acta, 409(PART A), 163-173. https://doi.org/10.1016/j.ica.2013.06.018

2011

Scholarly publications

Wieczorek, B., Träff, A., Krumlinde, P., Dijkstra, H. P., Egmond, M. R., van Koten, G., Bäckvall, J-E., & Klein Gebbink, R. J. M. (2011). Covalent anchoring of a racemization catalyst to CALB-beads: towards dual immobilization of DKR catalysts. Tetrahedron Letters, 52(14), 1601-1604. https://doi.org/10.1016/j.tetlet.2011.01.106

Snelders, D. J. M., Siegler, M. A. M., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2011). Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines. Dalton Transactions, 40(11), 2588-2600. https://doi.org/10.1039/C0DT01105C

2010

Scholarly publications

Wadman, S. H., van Leeuwen, Y. M., Havenith, R. W. A., van Klink, G. P. M., & van Koten, G. (2010). A redox asymmetric, cyclometalated ruthenium dimer: toward upconversion dyes in dye-sensitized TiO2 solar cells. Organometallics, 29(21), 5635-5645. https://doi.org/10.1021/om100865k

Li, J., Lutz, M., Spek, A. L., van Klink, G. P. M., van Koten, G., & Klein Gebbink, R. J. M. (2010). Chiral amino alcohol derived bis-phosphoramidite pincer palladium complexes and their applications in asymmetric allylation of aldimines. Organometallics, 29(6), 1379-1387. https://doi.org/10.1021/om100021p

2009

Scholarly publications

van Koten, G., & Jastrzebski, J. T. B. H. (2009). Structural organocopper chemistry. In Z. Rappoport, & I. Marek (Eds.), The chemistry of organocopper compounds (Patai series : the chemistry of functional groups). Wiley-Blackwell.

Wander, M., Hausoul, P. J. C., Sliedregt, L. A. J. M., van Steen, B. J., van Koten, G., & Klein Gebbink, R. J. M. (2009). Synthesis of polyaryl rigid-core carbosilane dendrimers for supported organic synthesis. Organometallics, 28, 4406-4415. http://www.acs.org/

2008

Scholarly publications

Bruijnincx, P. C. A., van Koten, G., & Klein Gebbink, R. J. M. (2008). Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies. Chemical Society Reviews, 37(12), 2716-2744.
https://dspace.library.uu.nl/bitstream/handle/1874/32821/2.ChemSoc.Rev.37%282008%292716-2744_Bruijnincx.pdf?sequence=1

Köcher, S., Walfort, B., Mills, A. M., Spek, A. L., van Klink, G. P. M., van Koten, G., & Lang, H. (2008). Synthesis and reaction chemistry of 4-nitrile-substituted NCN-pincer palladium(II) and platinum(II) complexes (NCN = [NC-4-C6H2(CH2NMe2)2-2,6]−). Journal of Organometallic Chemistry, 693(11), 1991-1996.
https://dspace.library.uu.nl/bitstream/handle/1874/33212/788.pdf?sequence=1

Kruithof, C. A., Dijkstra, H. P., Lutz, M., Spek, A. L., Egmond, M. R., Klein Gebbink, R. J. M., & van Koten, G. (2008). Non-tethered organometallic phosphonate inhibitors for lipase inhibition: positioning of the metal center in the active site of cutinase. European Journal of Inorganic Chemistry, 2008(28), 4425-4432.
https://dspace.library.uu.nl/bitstream/handle/1874/33216/790.pdf?sequence=1

Chase, P. A., Lutz, M., Spek, A. L., Gossage, R. A., & van Koten, G. (2008). Solid-state and solution structures of hetero-aggregates formed between nBuLi and NCN pincer aryl lithium. Dalton Transactions, 2008(42), 5783-5790.
https://dspace.library.uu.nl/bitstream/handle/1874/33260/794.pdf?sequence=1

2007

Scholarly publications

Suijkerbuijk, B. M. J. M., Tooke, D. M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2007). One-Dimensional, Cofacial Porphyrin Polymers Formed by Self-Assembly of meso-Tetrakis(ERE Donor) Zinc(II) Porphyrins. Chemistry - An Asian Journal, 2(7), 889-903.
https://dspace.library.uu.nl/bitstream/handle/1874/26805/754.pdf?sequence=1

2006

Scholarly publications

Gosiewska, S., Veld, M. H. I., de Pater, J. J. M., Bruijnincx, P. C. A., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2006). Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with l-proline chiral auxiliaries: mer η3-N,C,N versus square planar η4-N,C,N,O coordination. Tetrahedron Asymmetry, 17(4), 674-686. https://doi.org/10.1016/j.tetasy.2005.12.040

Beletskaya, I. P., Kashin, A. N., Litvinov, A. E., Tyurin, V. S., Valetsky, P. M., & van Koten, G. (2006). Palladium Colloid Stabilized by Block Copolymer Micelles as an Efficient Catalyst for Reactions of C-C and C-Heteroatom Bond Formation. Organometallics, 25(1), 154-158.
https://dspace.library.uu.nl/bitstream/handle/1874/20010/719.pdf?sequence=1

Köcher, S., Lutz, M., Spek, A. L., Prasad, R., van Klink, G. P. M., van Koten, G., & Lang, H. (2006). Heterobimetallic Fe–Pd and Fe–Pt NCN pincer complexes (NCN = [C6H2(CH2NMe2)2-2,6][1]). Inorganica Chimica Acta, 359, 4454-4462.
https://dspace.library.uu.nl/bitstream/handle/1874/21191/728.pdf?sequence=1

Kleijn, H., Kleij, A. W., de Pater, J. J. M., Lutz, M., Spek, A. L., Jastrzebski, J. T. B. H., Deelman, B. J., & van Koten, G. (2006). 2-(1-(Dimethylamino)ethyl)phenylpalladium(II) complexes 5-functionalized with fluorous silyl tails. Inorganica Chimica Acta, 359, 2674-2682.
https://dspace.library.uu.nl/bitstream/handle/1874/20011/720.pdf?sequence=1

2005

Scholarly publications

Bruijnincx, PCA., Lutz, M., Spek, AL., van Faassen, EE., Weckhuysen, BM., van Koten, G., & Gebbink, RJMK. (2005). Bis(1-methylimidazol-2-yl)propionates and bis(1-methylbenzimidazol-2-yl)-propionates: A new family of biomimetic N,N,O Ligands - Synthesis, structures and Cu-II coordination complexes. European Journal of Inorganic Chemistry, (4), 779-787. https://doi.org/10.1002/ejic.200400830

Merle, P. G., Cheron, V., Hagen, H., Lutz, M. H., Deelman, B. J., & van Koten, G. (2005). Fluorous Zirconocene(IV) Complexes and Their Olefin Polymerization Activity in Toluene and Fluorous Biphasic Solvent Systems. Organometallics, 24, 1620-1630.
https://dspace.library.uu.nl/bitstream/handle/1874/14715/om049507z.pdf?sequence=2

Bruijnincx, P. C. A., Lutz, M. H., Spek, A. L., van Faassen, E. E. H., Weckhuysen, B. M., van Koten, G., & Klein Gebbink, R. J. M. (2005). Bis(1-methylimidazol-2-yl)propionates and Bis(1-methylbenzimidazol-2-yl)propionates: A New Family of Biomimetic N,N,O Ligands - Synthesis, Structures and CuII Coordination Complexes. European Journal of Inorganic Chemistry, 779-787.
https://dspace.library.uu.nl/bitstream/handle/1874/14698/ejic.200400830.pdf?sequence=1

2004

Scholarly publications

Tromp, M., Van Bokhoven, J. A., Slagt, M. Q., Klein Gebbink, R. J. M., Van Koten, G., Ramaker, D. E., & Koningsberger, D. C. (2004). AXAFS as a Probe of Charge Redistribution within Organometallic Complexes. Journal of the American Chemical Society, 126(13), 4090-4091. https://doi.org/10.1021/ja031885s

Arink, A. M., Braam, T. W., Keeris, R., Jastrzebski, J. T. B. H., Benhaim, C., Rosset, S., Alexakis, A., & Van Koten, G. (2004). Copper(I) thiolate catalysts in asymmetric conjugate addition reactions. Organic Letters, 6(12), 1959-1962.

Slagt, M. Q., van Zwieten, D. A. P., Moerkerk, A. J. C. M., Klein Gebbink, R. J. M., & van Koten, G. (2004). NCN-Pincer Palladium Complexes with Multiple Anchoring Points for Functional Groups. Coordination Chemistry Reviews, 248, 2275-2282.
https://dspace.library.uu.nl/bitstream/handle/1874/25915/672.pdf?sequence=1

2003

Scholarly publications

van Klink, G. P. M., Dijkstra, H. P., & van Koten, G. (2003). Recyclable nanosize homogeneous catalysts. Comptes rendus de l'Academie des Sciences. Serie 2 fascicule c, chimie = chemistry, 6, 1079-1085.
https://dspace.library.uu.nl/bitstream/handle/1874/6442/13079.pdf?sequence=2

Professional publications

Köcher, S., van Klink, G. P. M., van Koten, G., & Lang, H. (2003). Ferrocene-bridged Pd-NCN-pincer complexes. Journal of Organometallic Chemistry, 684, 230-234.
https://dspace.library.uu.nl/bitstream/handle/1874/31976/656.pdf?sequence=1

2002

Scholarly publications

Kronenburg, C. M. P., Jastrzebski, J. T. B. H., Boersma, J., Lutz, M., Spek, A. L., & Van Koten, G. (2002). The first homologous series of self-assembled aryl bromo- and aryl cyanocuprates, -argentates, and -aurates; MLi2XAr2(M = CuI, AgI, AuI; X = Br, C≡N; Ar = [C6H4CH2N(Et)CH2CH2NEt2-2]-). Journal of the American Chemical Society, 124(39), 11675-11683. https://doi.org/10.1021/ja026945t

Slagt, M. Q., Stiriba, S-E., Klein Gebbink, R. J. M., Kautz, H., Frey, H., & van Koten, G. (2002). Encapsulation of hydrophilic pincer-platinum(II) complexes in amphiphilic hyperbranched polyglycerol nanocapsules. Macromolecules, 35, 5734-5737.
https://dspace.library.uu.nl/bitstream/handle/1874/6219/13057.pdf?sequence=2

2000

Scholarly publications

Richter, B., De Wolf, E., Van Koten, G., & Deelman, B-J. (2000). Synthesis and properties of a novel family of fluorous triphenylphosphine derivatives. Journal of Organic Chemistry, 65(13), 3885-3893. https://doi.org/10.1021/jo991548v

Richter, B., Spek, A. L., Van Koten, G., & Deelman, B-J. (2000). Fluorous versions of Wilkinson's catalyst. Activity in fluorous hydrogenation of 1-alkenes and recycling by fluorous biphasic separation. Journal of the American Chemical Society, 122(16), 3945-3951. https://doi.org/10.1021/ja993562v

De Wolf, E., Richter, B., Deelman, B-J., & Van Koten, G. (2000). Highly fluorous derivatives of 1,2-bis(diphenylphosphino)ethane. Journal of Organic Chemistry, 65(17), 5424-5427. https://doi.org/10.1021/jo000312k

Beerens, H. I., Wijkens, P., Jastrzebski, J. T. B. H., Verpoort, F., Verdonck, L., & Van Koten, G. (2000). Coordination of a Ru(II)-complex to a tetrafunctional P-ligand: A model for Ru-P carbosilane dendrimers. Journal of Organometallic Chemistry, 603(2), 244-248.

Wijkens, P., Jastrzebski, J. T. B. H., Van Der Schaaf, P. A., Kolly, R., Hafner, A., & Van Koten, G. (2000). Synthesis of Periphery-Functionalized Dendritic Molecules Using Polylithiated Dendrimers as Starting Material. Organic Letters, 2(11), 1621-1624.

Kronenburg, C. M. P., Jastrzebski, J. T. B. H., & Van Koten, G. (2000). Structure and reactivity of cyanocuprates containing the monoanionic C,N-chelating aminoaryl ligand [C6H4CH2NMe2-2 ] -. Polyhedron, 19(5), 553-555. https://doi.org/10.1016/S0277-5387(99)00406-4

Kleij, A. W., Gossage, R. A., Jastrzebski, J. T. B. H., Boersma, J., & Van Koten, G. (2000). The 'dendritic effect' in homogeneous catalysis with carbosilane- supported arylnickel(II) catalysts: Observation of active-site proximity effects in atom-transfer radical addition. Angewandte Chemie - International Edition, 39(1), 176-178. https://doi.org/10.1002/(SICI)1521-3773(20000103)39:1<176::AID-ANIE176>3.0.CO;2-3

Kleij, A. W., Gossage, R. A., Klein Gebbink, R. J. M., Brinkmann, N., Reijerse, E. J., Kragl, U., Lutz, M., Spek, A. L., & Van Koten, G. (2000). A "Dendritic Effect" in homogeneous catalysis with carbosilane-supported arylnickel(II) catalysts: Observation of active-site proximity effects in atom-transfer radical addition. Journal of the American Chemical Society, 122(49), 12112-12124. https://doi.org/10.1021/ja0026612

Kooijman, H., Spek, A. L., Kleijn, H., van Maanen, H. L., Jastrzebski, J. T., & van Koten, G. (2000). (3R,4S)-3-phenyl-1-[(R)-1-phenylethyl]-4-[(R)-1-phenylethyliminomethyl] azetidin-2-one. Acta Crystallographica. Section C, Crystal Structure Communications, 56, Pt 4/-.

Hovestad, N. J., Ford, A., Jastrzebski, J. T. B. H., & Van Koten, G. (2000). Functionalized carbosilane dendritic species as soluble supports in organic synthesis. Journal of Organic Chemistry, 65(20), 6338-6344. https://doi.org/10.1021/jo991726k

Eggeling, E. B., Hovestad, N. J., Jastrzebski, J. T. B. H., Vogt, D., & Van Koten, G. (2000). Phosphino carboxylic acid ester functionalized carbosilane dendrimers: Nanoscale ligands for the Pd-catalyzed hydrovinylation reaction in a membrane reactor. Journal of Organic Chemistry, 65(26), 8857-8865. https://doi.org/10.1021/jo000433k

1999

Scholarly publications

Hovestad, N. J., Eggeling, E. B., Heidbüchel, H. J., Jastrzebski, J. T. B. H., Kragl, U., Keim, W., Vogt, D., & Van Koten, G. (1999). Selective hydrovinylation of styrene in a membrane reactor: Use of carbosilane dendrimers with hemilabile P,O ligands. Angewandte Chemie - International Edition, 38(11), 1655-1658. https://doi.org/10.1002/(SICI)1521-3773(19990601)38:11<1655::AID-ANIE1655>3.0.CO;2-2

Kleij, A. W., Kleijn, H., Jastrzebski, J. T. B. H., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1999). Dendritic Carbosilanes Containing Silicon-Bonded 1-[C₆H₂(CH₂NMe₂) ₂-3,5-Li-4] or 1-[C₆H₃(CH₂NMe₂)-4-Li-3] Mono- And Bis(amino)aryllithium End Groups: Structure of {[CH₂SiMe₂C₆H₃(CH ₂NMe₂)-4-Li-3]₂}₂. Organometallics, 18(2), 268-276.

Kleij, A. W., Kleijn, H., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1999). Carbosilane Molecules with Mono- And Bis(amino)arylmetal End Groups: Structures of {NiI[C₆H₂(CH₂NMe₂) ₂-2,6-SiMe₃-4]} and Tetranuclear {[CH₂Si(Me)₂C₆H₃(CH ₂NMe₂)-4-(PdCl)-3]₂}₂. Organometallics, 18(2), 277-285.

Van Koten, G., & Jastrzebski, J. T. B. H. (1999). Periphery-functionalized organometallic dendrimers for homogeneous catalysis. Journal of Molecular Catalysis A-Chemical, 146(1-2), 317-323. https://doi.org/10.1016/S1381-1169(99)00091-6

Hovestad, N. J., Jastrzebski, J. T. B. H., Van Koten, G., Bon, S. A. F., Waterson, C., & Haddleton, D. M. (1999). Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 40, pp. 393-394). American Chemical Society.

Hovestad, N. J., Hoare, J. L., Jastrzebski, J. T. B. H., Canty, A. J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1999). Periphery-palladated carbosilane dendrimers: Synthesis and reactivity of organopalladium(II) and -(IV) dendritic complexes. Crystal structure of [PdMe(C6H4(OCH2Ph)-4)(bpy)] (bpy = 2,2′-bipyridine). Organometallics, 18(16), 2970-2980.

Kleijn, H., Rijnberg, E., Jastrzebski, J. T. B. H., & Van Koten, G. (1999). Synthesis of arylzinc thiolates containing perfluoroalkyl chains. Model catalyst precursors for the enantioselective zinc-mediated 1,2-addition of dialkylzincs to aldehydes in fluorous biphase systems. Organic Letters, 1(6), 853-855.

Brandts, J. A. M., Kruiswijk, E., Boersma, J., Spek, A. L., & van Koten, G. (1999). C-H activation of a MeN grouping in one of the CH2NMe2 ortho substituents of a NCN 'pincer' ligand in tungsten chemistry: X-ray structure of [WCl2(NPh)(C6H3{CH2NMeCH2}-2-{CH2NMe2}-6)]. Journal of Organometallic Chemistry, 585, 93-99.
https://dspace.library.uu.nl/bitstream/handle/1874/14437/10.1016-S0022-328X%2899%2900199-0.pdf?sequence=1

1998

Scholarly publications

Donkervoort, J. G., Vicario, J. L., Jastrzebski, J. T. B. H., Gossage, R. A., Cahiez, G., & Van Koten, G. (1998). Novel tridentate diamino organomanganese(II) complexes as homogeneous catalysts in manganese(II)/copper(I) catalyzed carbon-carbon bond forming reactions. Journal of Organometallic Chemistry, 558(1-2), 61-69.

Donkervoort, J. G., L. Vicario, J., Jastrzebski, J. T. B. H., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1998). Synthesis of arylplatinum(II) complexes with chiral monoanionic aryldiamine ligands. The X-ray crystal structure of (-)-[(1R,1′R)-2,6-bis{1-(dimethylamino)propyl}phenyl]chloroplatinum(II). Journal of Organometallic Chemistry, 551(1-2), 1-7.

Donkervoort, J. G., Vicario, J. L., Rijnberg, E., Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & Van Koten, G. (1998). Formation of mixed aryl-, alkyl-lithium aggregates in the heteroatom assisted lithiation of α,α′-dialkyl substituted 1,3-bis[(dimethylamino)methyl]benzene. Journal of Organometallic Chemistry, 550(1-2), 463-467.

Meijer, M. D., Rump, M., Gossage, R. A., Jastrzebski, J. H. T. B., & Van Koten, G. (1998). New 'bucky-ligands'. Potentially monoanionic terdentate diamino aryl pincer ligands anchored to C60. Tetrahedron Letters, 39(37), 6773-6776.

Kronenburg, C. M. P., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1998). A model structure for the resting state of cyanocuprate reagents R2Cu(CN)Li2. The X-ray crystal structure of [Ar2Cu(CN)Li2(THF)4](∞)1[5]. Journal of the American Chemical Society, 120(37), 9688-9689. https://doi.org/10.1021/ja9802448

Kleijn, H., Jastrzebski, J. T. B. H., Gossage, R. A., Kooijman, H., Spek, A. L., & Van Koten, G. (1998). Ortho-bis(amino)arylnickel(II) halide complexes containing perfluoroalkyl chains as model catalyst precursors for use in fluorous biphase systems. Tetrahedron, 54(7), 1145-1152. https://doi.org/10.1016/S0040-4020(97)10214-9

1997

Scholarly publications

Gerold, A., Jastrzebski, J. T. B. H., Kronenburg, C. M. P., Krause, N., & Van Koten, G. (1997). Determination of the degree of aggregation of organocopper compounds by cryoscopy in tetrahydrofuran. Angewandte Chemie: International Edition, 36(7), 755-757.

Van Koten, G., Grove, D. M., & Jastrzebski, J. T. B. H. (1997). Supramolecular aryl transition metal catalysts; Selective product formation with organometallic radicals. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (1 ed., Vol. 38, pp. 640-641)

Rijnberg, E., Boersma, J., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1997). The role of neutral and radical anionic organozinc complexes in the alkylation reactions of 1,4-diaza-1,3-butadienes with diorganozinc compounds. Organometallics, 16(14), 3158-3164.

Rijnberg, E., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Spek, A. L., & Van Koten, G. (1997). Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) ₆[Zn(CH₂Ph)₃]₂. Journal of Organometallic Chemistry, 541(1-2), 181-185.

Donkervoort, J. G., Jastrzebski, J. T. B. H., Deelman, B. J., Kooijman, H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Novel aryltitanium(IV) complexes containing η ³-NCN- pseudofacial- and η ³-NCN-meridional-bonded [C ₆H ₃(CH ₂NME ₂) ₂-2,6]-(abbreviated as NCN) ligands. Organometallics, 16(19), 4174-4184.

Donkervoort, J. G., Kronenburg, C. M. P., Deelman, B. J., Jastrzebski, J. T. B. H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Aryltitaniumf( IV) complexes with the η3-C,N,N′-pseudofacially coordinating ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]-. The X-ray crystal structure of [TiCl2( CNN)( O-i-Pr)]. Journal of Organometallic Chemistry, 547(2), 349-355.

Wijkens, P., Jastrzebski, J. T. B. H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Self-assembling of bis-ortho chelated diaminobenzyl- (NC′N) and butyl-lithium units to give 2: 2 mixed alkyllithium aggregates (NC′N)Li2Bu2Li2(NC′N) with a ladder structure. Chemical Communications, (22), 2143-2144.

Huls, D., Gunther, H., Van Koten, G., Wijkens, P., & Jastrzebski, J. T. B. H. (1997). Detection of scalar 6Li,15N coupling across coordinative Li-N bonds. Angewandte Chemie: International Edition, 36(23), 2629-2631.

Steenwinkel, P., Jastrzebski, J. T. B. H., Deelman, B. J., Grove, D. M., Kooijman, H., Veldman, N., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1997). Hypercoordinate aryltrialkylsilanes and -stannanes and their use in the synthesis of homodinuclear organometallic complexes with a 1,4-phenylene bridge. Organometallics, 16(25), 5486-5498.

Rietveld, M. H. P., Klumpers, E. G., Jastrzebski, J. T. B. H., Grove, D. M., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Alkylidene-centered rearrangement of a tantalum alkylidene alkoxide species with the N,C,N-bis-ortho-chelated 1,2,6-trisubstituted aryldiamine ligand [C6H3(CH2NMe2)2-2,6] - to a product with a C,N-mono-ortho-chelated 1,2,4-Trisubstituted aryldiamine ligand. Organometallics, 16(20), 4260-4267.

Rijnberg, E., Hovestad, N. J., Kleij, A. W., Jastrzebski, J. T. B. H., Boersma, J., Janssen, M. D., Spek, A. L., & Van Koten, G. (1997). Application of S,N-chelating chiral zinc bis(aminoarenethiolates) as new precursor catalysts in the enantioselective addition of dialkylzincs to aldehydes. Organometallics, 16(13), 2847-2857.

Rijnberg, E., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). 1: 1 and 2:1 lithium zincates with intramolecular coordination. structures of Li(thf)Zn(C₆H₄CH₂NMe₂-2)₃ and Li₂Zn(C₆H₄CH₂NMe₂-2) ₄. Organometallics, 16(11), 2239-2245.

1996

Scholarly publications

Hogerheide, M. P., Ringelberg, S. N., Grove, D. M., Jastrzebski, J. T. B. H., Boersma, J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1996). A Proposal for Positive Cooperativity in Anion-Cation Binding in Yttrium and Lutetium Complexes Based on o-Amino-Substituted Phenolate Ligands. on the Way to Coordination Polymers by Self-Assembly. Molecular Structures of [ClLu(OAr)₃Na] (X-ray) and [ClY(OAr')₃Y(OAr')₃Na] (X-ray and ⁸⁹Y-NMR). Inorganic Chemistry, 35(5), 1185-1193.

Donkervoort, J. G., Vicario, J. L., Jastrzebski, J. T. B. H., Cahiez, G., & Van Koten, G. (1996). Novel organomanganese(II) complexes active as homogeneous catalysts in manganese(II)/copper(I) catalyzed carbon-carbon bond formation reactions. Recueil des Travaux Chimiques des Pays-Bas, 115(11-12), 547-548.

1995

Scholarly publications

Hogerheide, M. P., Grove, D. M., Boersma, J., Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & van Koten, G. (1995). New Coordinatively Unsaturated Lutetium Mono‐ and Bis(alkyl) Complexes with a Bis(ortho)‐Chelating Aryldiamine Ligand—Crystal Structures of [LuCl₂{2,6‐(Me₂NCH₂)₂C₆H₃}(μ‐Cl)(μ‐Li(thf)₂)]₂ and [Lu(μ‐Cl){2,6‐(Me₂NCH₂)₂C₆H₃}(CH₂SiMe₃)]₂. Chemistry – A European Journal, 1(6), 343-350. https://doi.org/10.1002/chem.19950010604

Wijkens, P., Van Koten, E. M., Janssen, M. D., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1995). The formation of a mixed organolithium aggregate Li4R2nBu2 during the heteroatom-assisted lithiation of 1,3-bis(dimethylaminomethyl)-2,4,6-trimethylbenzene (R = 2,6-(CH2NMe2)2-3,5-Me2C 6HCH2). Angewandte Chemie: International Edition, 34(2), 219-222.

Rijnberg, E., Boersma, J., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1995). Heteroleptic metallacyclic potassium organodiamido zincate complex. Synthesis and structure of polymeric {[K(thf)][MeZn(Bu^tNCH=CHNBu ^t)]}_n. Journal of the Chemical Society, Chemical Communications, (18), 1839-1840. https://doi.org/10.1039/C39950001839

van Maanen, H. L., Kleijn, H., Jastrzebski, J. TBH., & van Koten, G. (1995). Diastereocontrol via cosolvents in the zinc ester eeolate-imine condensation route to β-lactams. Bulletin de la Societe Chimique de France, 132(1), 86-94.

Hogerheide, M. P., Wesseling, M., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Spek, A. L., & Van Koten, G. (1995). Versatility in phenolate bonding in organoaluminum complexes containing mono- and bis-ortho-chelating phenolate ligands. X-ray structures of Al{OC6H2(CH2NMe2) 2-2,6-Me-4}3, Al(Me)2{OC6H2(CH2NMe 2)2-2,6-Me-4}·N-AlMe ... Organometallics, 14(10), 4483-4492.

Van Maanen, H. L., Kleijn, H., Jastrzebski, J. T. B. H., Verweij, J., Kieboom, A. P. G., & Van Koten, G. (1995). Asymmetric synthesis of β-lactams via the zinc-mediated glycine ester enolate - Imine condensation reaction using α-amino esters as the chiral auxiliary. Journal of Organic Chemistry, 60(14), 4331-4338.

1994

Scholarly publications

van Maanen, H. L., Kleijn, H., Jastrzebski, J. T. B. H., & van Koten, G. (1994). The synthesis of 3‐alkyl‐ and 3‐aryl‐β‐lactams from zinc enolates and imines. Recueil des Travaux Chimiques des Pays‐Bas, 113(12), 567-572. https://doi.org/10.1002/recl.19941131207

Hogerheide, M. P., Jastrzebski, J. T. B. H., Boersma, J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1994). Cooperative binding of Na+ and Cl- in Na{M[OC6H2(CH2NMe2) 2-2,6-Me-4]3Cl}: Synthesis (M = Lu, Y) and X-ray structure (M = Lu) of new heterometallic complexes of lutetium and yttrium containing bis(o-amino)phenolate ligands. Inorganic Chemistry, 33(20), 4431-4432.

Van Maanen, H. L., Kleijn, H., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1994). Dualistic reactivity of lithium and zinc dienolates with imines: Effects of counterion, temperature, and substituents on α- and γ-coupling. Journal of Organic Chemistry, 59(25), 7839-7848.

Rijnberg, E., Jastrzebski, J. T. B. H., Janssen, M. D., Boersma, J., & Van Koten, G. (1994). Application of N,S-chelating chiral zinc bis(arenethiolate) complexes as new precursor catalysts in the enantioselective addition of diethylzinc to aldehydes. Tetrahedron Letters, 35(35), 6521-6524. https://doi.org/10.1016/S0040-4039(00)78262-1

Van Maanen, H. L., Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & Van Koten, G. (1994). Highly functionalized β-enamino esters via C-C coupling reactions of lithium enolates of protected glycine esters and isothiocyanates. Tetrahedron, 50(39), 11509-11526. https://doi.org/10.1016/S0040-4020(01)89288-7

1993

Scholarly publications

Wehman-Ooyevaar, I. C. M., Vedral, J. A., Jastrzebski, J. T. B. H., Grove, D. M., & van Koten, G. (1993). Novel rhodate and iridate complexes containing C,N chelating arylamine ligand systems. Journal of Organometallic Chemistry, 451(1-2), 195-204. https://doi.org/10.1016/0022-328X(93)83026-R

Wissing, E., Jastrzebski, J. T. B. H., Boersma, J., & van Koten, G. (1993). An unexpected 1,2-alkyl shift within a chelate bonded organoaluminium-enamine. Journal of Organometallic Chemistry, 459(1-2), 11-16. https://doi.org/10.1016/0022-328X(93)86050-R

Van Der Schaaf, P. A., Jastrzebski, J. T. B. H., Hogerheide, M. P., Smeets, W. J. J., Spek, A. L., Boersma, J., & Van Koten, G. (1993). Mono- and bis-ortho-chelated lithium and sodium phenolates. Molecular structures of the first lithium phenolate with a stable, trinuclear structure and of a tetranuclear sodium analog, [MOC6H2(CH2NMe2) 2-2,6-Me-4]x (M = Li, x = 3; M = Na, x = 4). Inorganic Chemistry, 32(19), 4111-4118.

Jastrzebski, J. T. B. H., & Van Koten, G. (1993). Intramolecular Coordination in Organotin Chemistry. Advances in Organometallic Chemistry, 35(C), 241-294. https://doi.org/10.1016/S0065-3055(08)60493-1

Jastrzebski, J. T. B. H., & Van Koten, G. (1993). The zinc mediated condensation of amino acid esters with imines to β- lactams. Bioorganic & Medicinal Chemistry Letters, 3(11), 2351-2356. https://doi.org/10.1016/S0960-894X(01)80954-9

Van Maanen, H. L., Jastrzebski, J. T. B. H., Verweij, J., Kieboom, A. P. G., Spek, A. L., & Van Koten, G. (1993). (R)-2-Phenylglycine as a chiral auxiliary in the asymmetric synthesis of 2-azetidinones. Tetrahedron-Asymmetry, 4(7), 1441-1444. https://doi.org/10.1016/S0957-4166(00)80336-5

1992

Scholarly publications

Abbenhuis, H. C. L., Faiken, N., Grove, D. M., Jastrzebski, J. T. B. H., Kooijman, H., Van Der Sluis, P., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1992). Use of an aryldiamine pincer ligand in the study of tantalum alkylidene-centered reactivity: Tantalum-mediated alkene synthesis via reductive rearrangements and wittig-type reactions. Journal of the American Chemical Society, 114(25), 9773-9781.

Jastrzebski, J. T. B. H., Van Der Schaaf, P. A., Boersma, J., Van Koten, G., De Ridder, D. J. A., & Heijdenrijk, D. (1992). Evidence for hexacoordinate tin centers in triorganotin halides containing two 8-(dimethylamino)-1-naphthyl ligands. Organometallics, 11(4), 1521-1526.

Kleijn, H., van Maanen, H. L., Jastrzebski, J. T. B. H., & van Koten, G. (1992). Diastereo- and enantio-selective synthesis of trans-3-phenyl- and trans-3-styryl-2-azetidinones via zinc ester enolates and imines. Recueil des Travaux Chimiques des Pays-Bas, 111(11), 497-498.

Van Der Steen, F. H., Kleijn, H., Britovsek, G. J. P., Jastrzebski, J. T. B. H., & Van Koten, G. (1992). Enantioselective synthesis of 3-amino-2-azetidinones via the ester enolate-imine condensation. Journal of Organic Chemistry, 57(14), 3906-3916.

Brown, J. M., Pearson, M., Jastrzebski, J. T. B. H., & Van Koten, G. (1992). Intramolecular facilitation of aryl-transfer from tin in palladium-catalysed cross-coupling. Journal of the Chemical Society, Chemical Communications, (19), 1440-1441. https://doi.org/10.1039/C39920001440

Brown, J. M., Pearson, M., Jastrzebski, J. T. B. H., & Van Koten, G. (1992). Corigendum: Intramolecular facilitation of aryl-transfer from tin in palladium-catalysed cross-coupling (Journal Chemical Communications (1992) (1440)). Journal of the Chemical Society, Chemical Communications, (24), 1802.

1991

Scholarly publications

Jastrzebski, J. T. B. H., Grove, D. M., Boersma, J., van Koten, G., & Ernsting, JM. M. (1991). ¹¹⁹Sn NMR study of organotin compounds having intramolecular Sn—N coordination. Magnetic Resonance in Chemistry, 29(13), S25-S30. https://doi.org/10.1002/mrc.1260291308

Jastrzebski, J. T. B. H., Wehman, E., Boersma, J., van Koten, G., Goubitz, K., & Heijdenrijk, D. (1991). Synthesis and structure of [2-(4,4-dimethyl-2-oxazoline)-5-methylphenyl]methylphenyltin bromide. A novel triorganotin halide having a configurationally stable chiral tin center. Journal of Organometallic Chemistry, 409(1-2), 157-162. https://doi.org/10.1016/0022-328X(91)86140-L

Jastrzebski, J. T. B. H., Boersma, J., Esch, P. M., & Van Koten, G. (1991). Intramolecular penta- and hexacoordinate tetraorganotin compounds containing the 8-(dimethylamino)-1-naphthyl ligand. Organometallics, 10(4), 930-935.

Jastrzebski, J. T. B. H., Boersma, J., & van Koten, G. (1991). Organotin(IV) compounds 2-(Me₂NCHR)C₆H₄(SnR′R″Br) with a fixed s-cis arrangement of the chiral carbon and tin centers. Crystal structure of 2-(Me₂NCHBu^t)C₆H₄SnMePhBr. Journal of Organometallic Chemistry, 413(1-3), 43-53. https://doi.org/10.1016/0022-328X(91)80037-K

Jastrzebski, J. T. B. H., van der Schaaf, P. A., Boersma, J., van Koten, G., de Wit, M., Wang, Y., Heijdenrijk, D., & Stam, C. H. (1991). Oxidative-addition reactions of molecular diiodine and dibromine to divalent organotin compounds. Crystal structures of bis[8-(dimethylamino)-1-naphthyl]tin(IV) dibromide and {2,6-[bis(dimethylamino)methyl]phenyl}- (4-tolyl)tin(IV) diodide. Journal of Organometallic Chemistry, 407(3), 301-311. https://doi.org/10.1016/0022-328X(91)86308-D

Van Der Steen, F. H., Kleijn, H., Jastrzebski, J. T. B. H., & Van Koten, G. (1991). A new and efficient route to 3-amino-2-azetidinones via zinc enolates of N,N-disubstituted glycine esters. Journal of Organic Chemistry, 56(16), 5147-5158.

1990

Scholarly publications

Jastrzebski, J. T. B. H., Sypkens, H. A. J., des Tombe, F. J. A., van der Schaaf, P. A., Boersma, J., van Koten, G., Spek, A. L., & Duisenberg, A. J. M. (1990). Crystal structure of zinc[bis[3-(dimethylamino)propyl-C,N]tin]bis(dibenzoylmethanato)-(SnZn). The first example of a dialkyltin(II) compound stabilized by SnZn coordination. Journal of Organometallic Chemistry, 396(1), 25-31. https://doi.org/10.1016/0022-328X(90)85189-6

1989

Scholarly publications

Jastrzebski, J. T. B. H., van der Schaaf, P. A., Boersma, J., van Koten, G., Zoutberg, M. C., & Heijdenrijk, D. (1989). Synthesis and Characterization of {2, 6-Bis[(dimethylamino)methyl]phenyl}tin(II) Chloride and {2, 6-Bis[(dimethylamino)methyl]phenyl}4-tolyltin(II), the First Example of a Mixed Dlaryitin(II) Compound. Organometallics, 8(5), 1373-1375. https://doi.org/10.1021/om00107a038

Jastrzebski, J. T. B. H., van der Schaaf, P. A., Boersma, J., Koten, G. V., Heijdenrijk, D., Goubitz, K., & de Ridder, D. J. A. (1989). Synthesis and characterization of a stable bis-naphthyltin(II) compound. Bis[8-(dimethylamino)-1-naphthyl-C,N]tin(II) and its W(CO)5 adduct. Journal of Organometallic Chemistry, 367(1-2), 55-68. https://doi.org/10.1016/0022-328X(89)87205-5

Wehman, E., Van Koten, G., Erkamp, C. J. M., Knotter, D. M., Jastrzebski, J. T. B. H., & Stam, C. H. (1989). Bis-ortho-chelated arylcopper compounds. Synthesis and X-ray crystal structure of Cu4Br2[C6H3(CH2NMe 2)2-o,o′2. Organometallics, 8(1), 94-99.

van Koten, G., & Jastrzebski, J. T. B. H. (1989). Polynuclear aryl-copper species and neutral aryl-cuprates with a chiral-CH(Me)NMe2 ortho substituent. Tetrahedron, 45(2), 569-578. https://doi.org/10.1016/0040-4020(89)80084-5

Van Der Steen, F. H., Kleijn, H., Jastrzebski, J. T. B. H., & Van Koten, G. (1989). The synthesis of β-lactams from zinc enolates of n,n-disubstituted α-aminoacid esters and imines: Substituent and solvent effects. Tetrahedron Letters, 30(6), 765-768. https://doi.org/10.1016/S0040-4039(01)80304-X

1988

Scholarly publications

Wehman, E., Jastrzebski, J. T. B. H., Ernsting, J. M., Grove, D. M., & van Koten, G. (1988). Structural investigations of aryllithium clusters in solution II. A. ¹³C and ⁷Li NMR study of substituted phenyllithium compounds containing ortho-directing NME₂ and CH₂NMe₂ groups. Journal of Organometallic Chemistry, 353(2), 145-155. https://doi.org/10.1016/0022-328X(88)83058-4

Jastrzebski, J. T. B. H., van Koten, G., & van de Mieroop, W. F. (1988). X-ray crystal structure of the hexameric lithium enolate of ethyl N, N-diethylglycinate. Inorganica Chimica Acta, 142(2), 169-171. https://doi.org/10.1016/S0020-1693(00)81551-0

Zoet, R., Jastrzebski, J. T. B. H., Van Koten, G., Mahabiersing, T., Vrieze, K., Heijdenrijk, D., & Stam, C. H. (1988). Synthesis and characterization of two isomers of decacarbonyl(1,4-dialkyl-1,4-diaza-1,3-butadiene)triosmium: Os3(CO)10(R-DAB). Fluxional behavior of Os3(CO)10(i-Pr-DAB(4e)). Molecular structures of the 48e cluster Os3(CO)10(i-Pr-DAB(4e)) and of the 50e cluster Os3(CO)10 ... Organometallics, 7(10), 2108-2117.

Jastrzebski, J. T. B. H., Boersma, J., van Koten, G., Smeets, W. J. J., & Spek, A. L. (1988). X-ray crystal structure of the ethylzinc enolate of 1-(2,4-cyclopentadienyl)-2-(diethylamino)-1-ethanone, the unexpected reaction product from cyclopentadienyl(ethyl)zinc and ethyl N, N-diethylglycinate. Recueil des Travaux Chimiques des Pays-Bas, 107(3), 263-266.

Wehman, E., Van Koten, G., Jastrzebski, J. T. B. H., Rotteveel, M. A., & Stam, C. H. (1988). Functionally substituted arylcopper compounds: Synthesis, structure, and reactivity of (2-(2-oxazolinyl)aryl)copper(I) species. Organometallics, 7(7), 1477-1485.

Wehman, E., Jastrzebski, J. T. B. H., Ernsting, J. M., Grove, D. M., & van Koten, G. (1988). Structural investigation of aryllithium clusters in solution I. A ¹³C and ⁷Li NMR study of phenyllithium and some methyl-substituted phenyllithium derivatives. Journal of Organometallic Chemistry, 353(2), 133-143. https://doi.org/10.1016/0022-328X(88)83057-2

Wehman, E., Van Koten, G., Jastrzebski, J. T. B. H., Ossor, H., & Pfeffer, M. (1988). Synthesis of cyclometallated naphthylpalladium complexes via transmetallation reactions of naphthylmercury with palladium species. Crystal structure determination of [{Pd(mxn)(O₂CMe)}₂]. Journal of the Chemical Society, Dalton Transactions, (12), 2975-2981. https://doi.org/10.1039/DT9880002975

Van der Steen, F. H., Jastrzebski, J. T. B. H., & Van Koten, G. (1988). Stereoselective one-pot synthesis of trans-3-amino-β-lactams from zinc enolates of N-protected α-aminoacid esters and imines. Tetrahedron Letters, 29(20), 2467-2470. https://doi.org/10.1016/S0040-4039(00)87909-5

1987

Scholarly publications

Maassarani, F., Pfeffer, M., Le Borgne, G., Jastrzebski, J. T. B. H., & Van Koten, G. (1987). Organopalladium compounds with a chiral palladated carbon atom. Facile isolation of optically active cyclopalladated complexes containing the (S)- or (R)-[2-NMe2C6H4CH(SiMe3)] monoanion. Molecular structure of {2-[1-(S)-(dimethylamino)ethyl]phenyl}[2-(dimethylamino)-α- (trimethylsilyl)benzyl]palladium(II). Organometallics, 6(5), 1111-1118.

Van Vliet, M. R. P., Van Koten, G., Buysingh, P., Jastrzebski, J. T. B. H., & Spek, A. L. (1987). Reactivity of 1-Aza-4-oxa-1,3-butadienes (α -imino ketones) toward diorganozinc reagents: Regio- and chemoselective transfer of organo groups in the ZnR2/R1N=C(R2)C(R3)=O system and x-ray structure of the organozinc enolate [EtZn(Et)(t-Bu)NC(H)=C(Me)O]2. Organometallics, 6(3), 537-546.

van Vliet, M. R. P., Jastrzebski, J. T. B. H., Klaver, W. J., Goubitz, K., & van Koten, G. (1987). The unexpected formation of trans-β-lactams in the reaction of α-iminoesters (R-N=C(H)C(=O)OR′) with diethylzinc. Crystal structure of trans-1-(N-t-butyl)-3-(N-t-butyl-N-ethylamino)-4-methoxycarbonylazetidin-2-one. Recueil des Travaux Chimiques des Pays-Bas, 106(4), 132-134.

Jastrzebski, J. T. B. H., van der Steen, F. H., & van Koten, G. (1987). Selective formation of 1,3,4-Trisubstituted and 3,4-Disubstituted trans-β-lactams from Zinc enolates and imines. Recueil des Travaux Chimiques des Pays-Bas, 106(9), 516-518.

Spek, A. L., Jastrzebski, J. T. B. H., & Van Koten, G. (1987). Structure of μ‐[1,2‐bis(tert‐butylamino‐1: 2κN)‐1,2‐di(2‐pyridyl‐κN)ethane]‐bis(ethylzinc). Acta Crystallographica. Section C, Crystal Structure Communications, 43(10), 2006-2007. https://doi.org/10.1107/S0108270187089261

1986

Scholarly publications

Wehman, E., Van Koten, G., & Jastrzebski, J. T. B. H. (1986). Functionally substituted arylcopper compounds; crystal structure of the copper bromide complex of [2-(4,4-dimethyl-2-oxazoline)-4-methylphenylcopper]. Journal of Organometallic Chemistry, 302(2). https://doi.org/10.1016/0022-328X(86)80095-X

Jastrzebski, J. T. B. H., Van Koten, G., Knaap, C. T., Schreurs, A. M. M., Kroon, J., & Spek, A. L. (1986). Organotin(IV) compounds derived from 2-Me2NC6H4CH2Li and its chiral α-Me3Si derivative. X-ray structure of pentacoordinate [{2-(dimethylamino)phenyl}(trimethylsilyl)methyl-C,N]methylphenyltin bromide having a chiral Sn center. Organometallics, 5(8), 1551-1558.

1985

Scholarly publications

Jastrzebski, J. T. B. H., Van Koten, G., Christophersen, M. J. N., & Stam, C. H. (1985). The unexpected formation of a lithium-enolate from bis2-[(dimethylamino)methyl]phenyl copper lithium. X-ray structure of Li4[OC(CH2)C6H4CH2NMe2-2]4. Journal of Organometallic Chemistry, 292(3), 319-324. https://doi.org/10.1016/0022-328X(85)80217-5

Van Koten, G., Jastrzebski, J. T. B. H., Muller, F., & Stam, C. H. (1985). Crystal structure of the neutral diarylcuprate Cu2Li2(C6H4CH2NMe 2-2)4: The asymmetric bonding configuration of organo groups bridging Cu and Li. Journal of the American Chemical Society, 107(3), 697-698.

1984

Scholarly publications

Van Koten, G., Jastrzebski, J. T. B. H., Stam, C. H., & Niemann, N. C. (1984). Solid-state structure of [Au2Li2(C6H4CH2NMe 2-2)4]: A model for the reactive structure of organocuprates. Journal of the American Chemical Society, 106(6), 1880-1881.

1983

Scholarly publications

Jastrzebski, J. T. B. H., van Koten, G., Goubitz, K., Arlen, C., & Pfeffer, M. (1983). Synthesis of 8-(dimethylamino)-1-naphthyllithium etherate: its structure in the solid (x-ray) and in solution (7Li and 1H NMR). Journal of Organometallic Chemistry, 246(3). https://doi.org/10.1016/S0022-328X(00)98740-0

Jastrzebski, J. T. B. H., Knaap, C. T., & van Koten, G. (1983). Pentacoordinate [8-(dimethylamino)naphthyl]diorganotin halides containing a rigid, flat NCCCSn chelate ring. An unexpected redistribution reaction between [8-(dimethylamino)naphthyl]trimethyltin and trimethyltin halide. Journal of Organometallic Chemistry, 255(3), 287-293. https://doi.org/10.1016/S0022-328X(00)99320-3

Van Vliet, M. R. P., Jastrzebski, J. T. B. H., Van Koten, G., Vrieze, K., & Spek, A. L. (1983). Novel reactions of substituted 1-aza-4-oxobutadienes (α-iminoketones) with diorganozinc reagents. Selective ethyl transfer in the Et2Zn/t-BuNC(H)C(Me)O system and x-ray crystal structure of [EtZn(Et)(T-Bu)NC(H)C(Me)O]2. Journal of Organometallic Chemistry, 251(1). https://doi.org/10.1016/0022-328X(83)80256-3

Van Koten, G., Jastrzebski, J. T. B. H., & Vrieze, K. (1983). Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic syntheses. Journal of Organometallic Chemistry, 250(1), 49-61. https://doi.org/10.1016/0022-328X(83)85039-6

1982

Scholarly publications

Klerks, J. M., Jastrzebski, J. T. B. H., & Van Koten, G. (1982). Regioselective ethyl transfer reactions between Diethylzinc and 1,4-Dialkyl-1,4-diaza-1,3-butadienes: Synthesis of EtZn[R(et)NCHCHNR]. Journal of Organometallic Chemistry, 224(2), 107-119. https://doi.org/10.1016/S0022-328X(00)89030-0

Jastrzebski, J. T. B. H., Van Koten, G., Konijn, M., & Stam, C. H. (1982). Intramolecularly chelated di- and tetranuclear aryllithium compounds: Crystal structure of Li4[C6H4(2-CH2NMe2)] 4 containing four-center two-electron-bonded C(aryl) atoms and heptacoordinate lithium atoms. Journal of the American Chemical Society, 104(20), 5490-5492.

1981

Scholarly publications

Jastrzebski, J. T. B. H., Klerks, J. M., van Koten, G., & Vrieze, K. (1981). An unexpected ethyl transfer reaction between Et2Zn and DI(t-Butyl)-glyoxaldiimine (t-BuDAB). Studies of the persistent [EtZn(t-BuDAB)] radical which is in equilibrium with its CC coupled dimer. Journal of Organometallic Chemistry, 210(3). https://doi.org/10.1016/S0022-328X(00)80905-5

1980

Scholarly publications

Van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Verhoeckx, G. J., Spek, A. L., & Kroon, J. (1980). Crystal and molecular structure of SnMePh[C₁₀H₅(OMe-5)(CH₂NMe₂-8)]Br and proton nuclear magnetic resonance study of the puckering of the chelate ring in five-co-ordinate triorganotin halides ... Journal of the Chemical Society, Dalton Transactions, (8), 1352-1358. https://doi.org/10.1039/DT9800001352

Van Koten, G., Schaap, C. A., Jastrzebski, J. T. B. H., & Noltes, J. G. (1980). Group IB organometallic chemistry. XXXIII. ArAuPPh₃, ArAu(CNR), (ArAu)_n and Ar₄Cu₂Au₂ compounds in which the aryl group contains 2-MeO, 2,6-(MeO)₂, 2-Me₂N, 2-Me₂NCH₂ and (S)- or (R)-2-Me₂NCHMe substituents as potential ligands. Journal of Organometallic Chemistry, 186(3), 427-445. https://doi.org/10.1016/S0022-328X(00)82423-7

1979

Scholarly publications

Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1979). Group IB organometallic chemistry. XXXII. Arylcopper compounds ArnCun as intermediates in organometallic synthesis. Single-step synthesis and dynamic NMR spectroscopy of diorganotin dihalides Ar2-nRnSnX2 (Ar 2-Me2NCH2C6H4 or (S)-2-Me2NCHMeC6H4; n 0 or 1). Journal of Organometallic Chemistry, 177(1), 283-292. https://doi.org/10.1016/S0022-328X(00)92354-4

1978

Scholarly publications

van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1978). Group IB organometallic chemistry. XXII. Reactions of Ar4Cu2Li2 and Ar4Au2Li2 with RhI complexes: synthesis of 2-[(dimethylamino)methyl]phenylrhodium dicarbone monoxide, and electron-transfer induced selective formation of diaryl ketones ArC(O)Ar. Journal of Organometallic Chemistry, 148(3), 317-325. https://doi.org/10.1016/S0022-328X(00)90988-4

van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Spek, A. L., & Schoone, J. C. (1978). Triorganotin cations stabilized by intramolecular SnN coordination; synthesis and characterization of {C,N,N′-2,6-bis[(dimethylamino)methyl]phenyl}diorganotin bromides {A figure is presented}. Journal of Organometallic Chemistry, 148(3), 233-245. https://doi.org/10.1016/S0022-328X(00)90980-X

Van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Pontenagel, W. M. G. F., Kroon, J., & Spek, A. L. (1978). Synthesis of C,Sn-chiral triorganotin halides via C-chiral arylcopper and arylgoldlithium intermediates. Crystal and molecular structure of one {2-[1-(S)-(dimethylamino)ethyl]phenyl}methylphenyltin bromide diastereomer. Journal of the American Chemical Society, 100(16), 5021-5028.

1977

Scholarly publications

van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977). Stable tetranuclear 4-tolyl-copperlithium ("cuprate") and -goldlithium ("aurate") compounds. Journal of Organometallic Chemistry, 140(2). https://doi.org/10.1016/S0022-328X(00)93202-9

Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977). Determination by microwave titration of the stoichiometry of phosphine and amine complexes of cuprous trifluoromethanesulphonate (copper triflate). Inorganica Chimica Acta, 21(C). https://doi.org/10.1016/S0020-1693(00)86210-6

Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977). Group 1B organometallic chemistry. 18. Novel routes to stable hexanuclear copper-silver, silver-gold, and copper-gold cluster compounds starting from polymeric 2-(dimethylamino)phenylcopper and from bis[(2-dimethylamino)pheny l]goldlithium dimer. Inorganic Chemistry, 16(7), 1782-1787.

Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977). Selective formation of biaryls via interaction of polynuclear arylcopper compounds with copper(I) trifluoromethanesulfonate [copper(I) triflate]. Journal of Organic Chemistry, 42(12), 2047-2053.

Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977). Interaction of arylmetal compounds of group 1B with copper(I) and silver(I) trifluoromethanesulphonate; a novel biaryl synthesis and a route to hexanuclear aryl-CuAg, -AgAu, and -CuAu clusters. Journal of the Chemical Society, Chemical Communications, (7), 203-204. https://doi.org/10.1039/C39770000203

1976

Scholarly publications

van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1976). Are arylcopper compounds intermediates in the exchange reaction between aryl halides and copper(I) salts? Tetrahedron Letters, 17(3), 223-226. https://doi.org/10.1016/0040-4039(76)80023-8