Publicaties
2021
Wetenschappelijke publicaties
Canty, A. J., Ariafard, A.
, & van Koten, G. (2021).
Computational Study of Bridge Splitting, Aryl Halide Oxidative Addition to PtII , and Reductive Elimination from PtIV: Route to Pincer-PtII Reagents with Chemical and Biological Applications.
Chemistry-A European Journal,
27(62), 15426-15433.
https://doi.org/10.1002/chem.202102687Batema, G. D.
, Korstanje, T. J., Guillena, G., Rodríguez, G.
, Lutz, M., Van Klink, G., Gossage, R. A.
, & Van Koten, G. (2021).
Replacing the Z-phenyl Ring in Tamoxifen® with a para-Connected NCN Pincer-Pt-Cl Grouping by Post-Modification.
Molecules,
26(7), 1-18. [1888].
https://doi.org/10.3390/molecules260718882018
Wetenschappelijke publicaties
Batema, G. D.
, van Walree, C. A., van Klink, G. P. M., de Mello Donegá, C., Meijerink, A., Perez-Moreno, J., Clays, K.
, & van Koten, G. (2018).
Octupolar organometallic Pt(II) NCN-pincer complexes; Synthesis, electronic, photophysical, and NLO properties.
Journal of Organometallic Chemistry,
867, 246-252.
https://doi.org/10.1016/j.jorganchem.2017.12.0282017
Wetenschappelijke publicaties
2015
Wetenschappelijke publicaties
Chase, P. A., Gossage, R. A.
, & van Koten, G. (2015).
Modern organometallic multidentate ligand design strategies: The birth of the privileged “pincer” ligand platform.
Topics in Organometallic Chemistry,
54, 1-16.
https://doi.org/10.1007/3418_2015_131Jastrzebski, J. T. B. H., Van Klaveren, M.
, & Van Koten, G. (2015).
Stable Divalent Triarylstannates R3SnLi Derived from 2-[(Dimethylamino)methyl]phenyllithium and SnCl2 or R2Sn.
Organometallics,
34(11), 2600-2607.
https://doi.org/10.1021/om5012215 2014
Wetenschappelijke publicaties
Batema, G. D.
, Lutz, M., Spek, A. L., van Walree, C. A., van Klink, G. P. M., & van Koten, G. (2014).
Organometallic benzylidene anilines: donor-acceptor features in NCN-pincer Pt(II) complexes with a 4-(E)-[(4-R-phenyl)imino]methyl substituent.
Dalton Transactions,
43(32), 12200-12209.
https://doi.org/10.1039/c4dt01023jPijnenburg, N. J. M., Tomás-Mendivil, E., Mayland, K. E., Kleijn, H.
, Lutz, M., Spek, A. L., Van Koten, G., & Klein Gebbink, B. (2014).
Monomeric and dendritic second generation Grubbs- and Hoveyda-Grubbs-type catalysts for olefin metathesis Metallodendrimers Special Issue.
Inorganica Chimica Acta,
409(PART A), 163-173.
https://doi.org/10.1016/j.ica.2013.06.018 2011
Wetenschappelijke publicaties
Wieczorek, B., Träff, A., Krumlinde, P.
, Dijkstra, H. P., Egmond, M. R., van Koten, G., Bäckvall, J-E.
, & Klein Gebbink, R. J. M. (2011).
Covalent anchoring of a racemization catalyst to CALB-beads: towards dual immobilization of DKR catalysts.
Tetrahedron Letters,
52(14), 1601-1604.
https://doi.org/10.1016/j.tetlet.2011.01.106 Snelders, D. J. M., Siegler, M. A. M., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2011).
Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines.
Dalton Transactions,
40(11), 2588-2600.
https://doi.org/10.1039/C0DT01105C 2010
Wetenschappelijke publicaties
Wadman, S. H., van Leeuwen, Y. M., Havenith, R. W. A., van Klink, G. P. M., & van Koten, G. (2010).
A redox asymmetric, cyclometalated ruthenium dimer: toward upconversion dyes in dye-sensitized TiO2 solar cells.
Organometallics,
29(21), 5635-5645.
https://doi.org/10.1021/om100865k Li, J., Lutz, M., Spek, A. L., van Klink, G. P. M., van Koten, G., & Klein Gebbink, R. J. M. (2010).
Chiral amino alcohol derived bis-phosphoramidite pincer palladium complexes and their applications in asymmetric allylation of aldimines.
Organometallics,
29(6), 1379-1387.
https://doi.org/10.1021/om100021p 2009
Wetenschappelijke publicaties
van Koten, G., & Jastrzebski, J. T. B. H. (2009). Structural organocopper chemistry. In Z. Rappoport, & I. Marek (Eds.), The chemistry of organocopper compounds (Patai series : the chemistry of functional groups). Wiley-Blackwell.
Wander, M., Hausoul, P. J. C., Sliedregt, L. A. J. M., van Steen, B. J.
, van Koten, G., & Klein Gebbink, R. J. M. (2009).
Synthesis of polyaryl rigid-core carbosilane dendrimers for supported organic synthesis.
Organometallics,
28, 4406-4415.
http://www.acs.org/ 2008
Wetenschappelijke publicaties
Köcher, S., Walfort, B., Mills, A. M.
, Spek, A. L., van Klink, G. P. M., van Koten, G., & Lang, H. (2008).
Synthesis and reaction chemistry of 4-nitrile-substituted NCN-pincer palladium(II) and platinum(II) complexes (NCN = [NC-4-C6H2(CH2NMe2)2-2,6]−).
Journal of Organometallic Chemistry,
693(11), 1991-1996.
https://dspace.library.uu.nl/bitstream/handle/1874/33212/788.pdf?sequence=1Kruithof, C. A., Dijkstra, H. P., Lutz, M., Spek, A. L., Egmond, M. R., Klein Gebbink, R. J. M., & van Koten, G. (2008).
Non-tethered organometallic phosphonate inhibitors for lipase inhibition: positioning of the metal center in the active site of cutinase.
European Journal of Inorganic Chemistry,
2008(28), 4425-4432.
https://dspace.library.uu.nl/bitstream/handle/1874/33216/790.pdf?sequence=1 Chase, P. A.
, Lutz, M., Spek, A. L., Gossage, R. A.
, & van Koten, G. (2008).
Solid-state and solution structures of hetero-aggregates formed between nBuLi and NCN pincer aryl lithium.
Dalton Transactions,
2008(42), 5783-5790.
https://dspace.library.uu.nl/bitstream/handle/1874/33260/794.pdf?sequence=12007
Wetenschappelijke publicaties
Suijkerbuijk, B. M. J. M., Tooke, D. M.
, Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2007).
One-Dimensional, Cofacial Porphyrin Polymers Formed by Self-Assembly of meso-Tetrakis(ERE Donor) Zinc(II) Porphyrins.
Chemistry - An Asian Journal,
2(7), 889-903.
https://dspace.library.uu.nl/bitstream/handle/1874/26805/754.pdf?sequence=12006
Wetenschappelijke publicaties
Gosiewska, S., Veld, M. H. I.
, de Pater, J. J. M., Bruijnincx, P. C. A., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2006).
Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with l-proline chiral auxiliaries: mer η3-N,C,N versus square planar η4-N,C,N,O coordination.
Tetrahedron Asymmetry,
17(4), 674-686.
https://doi.org/10.1016/j.tetasy.2005.12.040Beletskaya, I. P., Kashin, A. N., Litvinov, A. E., Tyurin, V. S., Valetsky, P. M.
, & van Koten, G. (2006).
Palladium Colloid Stabilized by Block Copolymer Micelles as an Efficient Catalyst for Reactions of C-C and C-Heteroatom Bond Formation.
Organometallics,
25(1), 154-158.
https://dspace.library.uu.nl/bitstream/handle/1874/20010/719.pdf?sequence=1Köcher, S.
, Lutz, M., Spek, A. L., Prasad, R.
, van Klink, G. P. M., van Koten, G., & Lang, H. (2006).
Heterobimetallic Fe–Pd and Fe–Pt NCN pincer complexes (NCN = [C6H2(CH2NMe2)2-2,6][1]).
Inorganica Chimica Acta,
359, 4454-4462.
https://dspace.library.uu.nl/bitstream/handle/1874/21191/728.pdf?sequence=1Kleijn, H., Kleij, A. W.
, de Pater, J. J. M., Lutz, M., Spek, A. L., Jastrzebski, J. T. B. H., Deelman, B. J., & van Koten, G. (2006).
2-(1-(Dimethylamino)ethyl)phenylpalladium(II) complexes 5-functionalized with fluorous silyl tails.
Inorganica Chimica Acta,
359, 2674-2682.
https://dspace.library.uu.nl/bitstream/handle/1874/20011/720.pdf?sequence=1 2005
Wetenschappelijke publicaties
Bruijnincx, PCA., Lutz, M., Spek, AL., van Faassen, EE., Weckhuysen, BM., van Koten, G., & Gebbink, RJMK. (2005).
Bis(1-methylimidazol-2-yl)propionates and bis(1-methylbenzimidazol-2-yl)-propionates: A new family of biomimetic N,N,O Ligands - Synthesis, structures and Cu-II coordination complexes.
European Journal of Inorganic Chemistry, (4), 779-787.
https://doi.org/10.1002/ejic.200400830 Merle, P. G., Cheron, V., Hagen, H.
, Lutz, M. H., Deelman, B. J., & van Koten, G. (2005).
Fluorous Zirconocene(IV) Complexes and Their Olefin Polymerization Activity in Toluene and Fluorous Biphasic Solvent Systems. Organometallics,
24, 1620-1630.
https://dspace.library.uu.nl/bitstream/handle/1874/14715/om049507z.pdf?sequence=2Bruijnincx, P. C. A., Lutz, M. H., Spek, A. L., van Faassen, E. E. H., Weckhuysen, B. M., van Koten, G., & Klein Gebbink, R. J. M. (2005).
Bis(1-methylimidazol-2-yl)propionates and Bis(1-methylbenzimidazol-2-yl)propionates: A New Family of Biomimetic N,N,O Ligands - Synthesis, Structures and CuII Coordination Complexes.
European Journal of Inorganic Chemistry, 779-787.
https://dspace.library.uu.nl/bitstream/handle/1874/14698/ejic.200400830.pdf?sequence=1 2004
Wetenschappelijke publicaties
Tromp, M., Van Bokhoven, J. A., Slagt, M. Q.
, Klein Gebbink, R. J. M., Van Koten, G., Ramaker, D. E.
, & Koningsberger, D. C. (2004).
AXAFS as a Probe of Charge Redistribution within Organometallic Complexes.
Journal of the American Chemical Society,
126(13), 4090-4091.
https://doi.org/10.1021/ja031885sArink, A. M., Braam, T. W., Keeris, R., Jastrzebski, J. T. B. H., Benhaim, C., Rosset, S., Alexakis, A., & Van Koten, G. (2004). Copper(I) thiolate catalysts in asymmetric conjugate addition reactions. Organic Letters, 6(12), 1959-1962.
Slagt, M. Q., van Zwieten, D. A. P., Moerkerk, A. J. C. M.
, Klein Gebbink, R. J. M., & van Koten, G. (2004).
NCN-Pincer Palladium Complexes with Multiple Anchoring Points for Functional Groups.
Coordination Chemistry Reviews,
248, 2275-2282.
https://dspace.library.uu.nl/bitstream/handle/1874/25915/672.pdf?sequence=12003
Wetenschappelijke publicaties
2002
Wetenschappelijke publicaties
Kronenburg, C. M. P.
, Jastrzebski, J. T. B. H., Boersma, J.
, Lutz, M., Spek, A. L., & Van Koten, G. (2002).
The first homologous series of self-assembled aryl bromo- and aryl cyanocuprates, -argentates, and -aurates; MLi2XAr2(M = CuI, AgI, AuI; X = Br, C≡N; Ar = [C6H4CH2N(Et)CH2CH2NEt2-2]-).
Journal of the American Chemical Society,
124(39), 11675-11683.
https://doi.org/10.1021/ja026945tSlagt, M. Q., Stiriba, S-E.
, Klein Gebbink, R. J. M., Kautz, H., Frey, H.
, & van Koten, G. (2002).
Encapsulation of hydrophilic pincer-platinum(II) complexes in amphiphilic hyperbranched polyglycerol nanocapsules.
Macromolecules,
35, 5734-5737.
https://dspace.library.uu.nl/bitstream/handle/1874/6219/13057.pdf?sequence=22000
Wetenschappelijke publicaties
Richter, B., De Wolf, E.
, Van Koten, G., & Deelman, B-J. (2000).
Synthesis and properties of a novel family of fluorous triphenylphosphine derivatives.
Journal of Organic Chemistry,
65(13), 3885-3893.
https://doi.org/10.1021/jo991548vRichter, B.
, Spek, A. L., Van Koten, G., & Deelman, B-J. (2000).
Fluorous versions of Wilkinson's catalyst. Activity in fluorous hydrogenation of 1-alkenes and recycling by fluorous biphasic separation.
Journal of the American Chemical Society,
122(16), 3945-3951.
https://doi.org/10.1021/ja993562vDe Wolf, E., Richter, B.
, Deelman, B-J., & Van Koten, G. (2000).
Highly fluorous derivatives of 1,2-bis(diphenylphosphino)ethane.
Journal of Organic Chemistry,
65(17), 5424-5427.
https://doi.org/10.1021/jo000312kBeerens, H. I., Wijkens, P., Jastrzebski, J. T. B. H., Verpoort, F., Verdonck, L., & Van Koten, G. (2000). Coordination of a Ru(II)-complex to a tetrafunctional P-ligand: A model for Ru-P carbosilane dendrimers. Journal of Organometallic Chemistry, 603(2), 244-248.
Wijkens, P., Jastrzebski, J. T. B. H., Van Der Schaaf, P. A., Kolly, R., Hafner, A., & Van Koten, G. (2000). Synthesis of Periphery-Functionalized Dendritic Molecules Using Polylithiated Dendrimers as Starting Material. Organic Letters, 2(11), 1621-1624.
Kronenburg, C. M. P.
, Jastrzebski, J. T. B. H., & Van Koten, G. (2000).
Structure and reactivity of cyanocuprates containing the monoanionic C,N-chelating aminoaryl ligand [C6H4CH2NMe2-2 ] -.
Polyhedron,
19(5), 553-555.
https://doi.org/10.1016/S0277-5387(99)00406-4Kleij, A. W., Gossage, R. A.
, Jastrzebski, J. T. B. H., Boersma, J.
, & Van Koten, G. (2000).
The 'dendritic effect' in homogeneous catalysis with carbosilane- supported arylnickel(II) catalysts: Observation of active-site proximity effects in atom-transfer radical addition.
Angewandte Chemie - International Edition,
39(1), 176-178.
https://doi.org/10.1002/(SICI)1521-3773(20000103)39:1<176::AID-ANIE176>3.0.CO;2-3Kleij, A. W., Gossage, R. A.
, Klein Gebbink, R. J. M., Brinkmann, N., Reijerse, E. J., Kragl, U.
, Lutz, M., Spek, A. L., & Van Koten, G. (2000).
A "Dendritic Effect" in homogeneous catalysis with carbosilane-supported arylnickel(II) catalysts: Observation of active-site proximity effects in atom-transfer radical addition.
Journal of the American Chemical Society,
122(49), 12112-12124.
https://doi.org/10.1021/ja0026612Kooijman, H., Spek, A. L., Kleijn, H., van Maanen, H. L., Jastrzebski, J. T., & van Koten, G. (2000). (3R,4S)-3-phenyl-1-[(R)-1-phenylethyl]-4-[(R)-1-phenylethyliminomethyl] azetidin-2-one. Acta Crystallographica. Section C, Crystal Structure Communications, 56, Pt 4/-.
Hovestad, N. J., Ford, A.
, Jastrzebski, J. T. B. H., & Van Koten, G. (2000).
Functionalized carbosilane dendritic species as soluble supports in organic synthesis.
Journal of Organic Chemistry,
65(20), 6338-6344.
https://doi.org/10.1021/jo991726kEggeling, E. B., Hovestad, N. J.
, Jastrzebski, J. T. B. H., Vogt, D.
, & Van Koten, G. (2000).
Phosphino carboxylic acid ester functionalized carbosilane dendrimers: Nanoscale ligands for the Pd-catalyzed hydrovinylation reaction in a membrane reactor.
Journal of Organic Chemistry,
65(26), 8857-8865.
https://doi.org/10.1021/jo000433k1999
Wetenschappelijke publicaties
Hovestad, N. J., Eggeling, E. B., Heidbüchel, H. J.
, Jastrzebski, J. T. B. H., Kragl, U., Keim, W., Vogt, D.
, & Van Koten, G. (1999).
Selective hydrovinylation of styrene in a membrane reactor: Use of carbosilane dendrimers with hemilabile P,O ligands.
Angewandte Chemie - International Edition,
38(11), 1655-1658.
https://doi.org/10.1002/(SICI)1521-3773(19990601)38:11<1655::AID-ANIE1655>3.0.CO;2-2Kleij, A. W., Kleijn, H., Jastrzebski, J. T. B. H., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1999). Dendritic Carbosilanes Containing Silicon-Bonded 1-[C6H2(CH2NMe2) 2-3,5-Li-4] or 1-[C6H3(CH2NMe2)-4-Li-3] Mono- And Bis(amino)aryllithium End Groups: Structure of {[CH2SiMe2C6H3(CH 2NMe2)-4-Li-3]2}2. Organometallics, 18(2), 268-276.
Kleij, A. W., Kleijn, H., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1999). Carbosilane Molecules with Mono- And Bis(amino)arylmetal End Groups: Structures of {NiI[C6H2(CH2NMe2) 2-2,6-SiMe3-4]} and Tetranuclear {[CH2Si(Me)2C6H3(CH 2NMe2)-4-(PdCl)-3]2}2. Organometallics, 18(2), 277-285.
Van Koten, G., & Jastrzebski, J. T. B. H. (1999).
Periphery-functionalized organometallic dendrimers for homogeneous catalysis.
Journal of Molecular Catalysis A-Chemical,
146(1-2), 317-323.
https://doi.org/10.1016/S1381-1169(99)00091-6 Hovestad, N. J., Jastrzebski, J. T. B. H., Van Koten, G., Bon, S. A. F., Waterson, C., & Haddleton, D. M. (1999). Atom transfer polymerization of methyl methacrylate initiated by carbosilane dendritic species. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 40, pp. 393-394). American Chemical Society.
Hovestad, N. J., Hoare, J. L., Jastrzebski, J. T. B. H., Canty, A. J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1999). Periphery-palladated carbosilane dendrimers: Synthesis and reactivity of organopalladium(II) and -(IV) dendritic complexes. Crystal structure of [PdMe(C6H4(OCH2Ph)-4)(bpy)] (bpy = 2,2′-bipyridine). Organometallics, 18(16), 2970-2980.
Kleijn, H., Rijnberg, E., Jastrzebski, J. T. B. H., & Van Koten, G. (1999). Synthesis of arylzinc thiolates containing perfluoroalkyl chains. Model catalyst precursors for the enantioselective zinc-mediated 1,2-addition of dialkylzincs to aldehydes in fluorous biphase systems. Organic Letters, 1(6), 853-855.
Brandts, J. A. M., Kruiswijk, E., Boersma, J.
, Spek, A. L., & van Koten, G. (1999).
C-H activation of a MeN grouping in one of the CH2NMe2 ortho substituents of a NCN 'pincer' ligand in tungsten chemistry: X-ray structure of [WCl2(NPh)(C6H3{CH2NMeCH2}-2-{CH2NMe2}-6)]. Journal of Organometallic Chemistry,
585, 93-99.
https://dspace.library.uu.nl/bitstream/handle/1874/14437/10.1016-S0022-328X%2899%2900199-0.pdf?sequence=11998
Wetenschappelijke publicaties
Donkervoort, J. G., Vicario, J. L., Jastrzebski, J. T. B. H., Gossage, R. A., Cahiez, G., & Van Koten, G. (1998). Novel tridentate diamino organomanganese(II) complexes as homogeneous catalysts in manganese(II)/copper(I) catalyzed carbon-carbon bond forming reactions. Journal of Organometallic Chemistry, 558(1-2), 61-69.
Donkervoort, J. G., L. Vicario, J., Jastrzebski, J. T. B. H., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1998). Synthesis of arylplatinum(II) complexes with chiral monoanionic aryldiamine ligands. The X-ray crystal structure of (-)-[(1R,1′R)-2,6-bis{1-(dimethylamino)propyl}phenyl]chloroplatinum(II). Journal of Organometallic Chemistry, 551(1-2), 1-7.
Donkervoort, J. G., Vicario, J. L., Rijnberg, E., Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & Van Koten, G. (1998). Formation of mixed aryl-, alkyl-lithium aggregates in the heteroatom assisted lithiation of α,α′-dialkyl substituted 1,3-bis[(dimethylamino)methyl]benzene. Journal of Organometallic Chemistry, 550(1-2), 463-467.
Meijer, M. D., Rump, M., Gossage, R. A., Jastrzebski, J. H. T. B., & Van Koten, G. (1998). New 'bucky-ligands'. Potentially monoanionic terdentate diamino aryl pincer ligands anchored to C60. Tetrahedron Letters, 39(37), 6773-6776.
Kronenburg, C. M. P.
, Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1998).
A model structure for the resting state of cyanocuprate reagents R2Cu(CN)Li2. The X-ray crystal structure of [Ar2Cu(CN)Li2(THF)4](∞)1[5].
Journal of the American Chemical Society,
120(37), 9688-9689.
https://doi.org/10.1021/ja9802448Kleijn, H.
, Jastrzebski, J. T. B. H., Gossage, R. A.
, Kooijman, H., Spek, A. L., & Van Koten, G. (1998).
Ortho-bis(amino)arylnickel(II) halide complexes containing perfluoroalkyl chains as model catalyst precursors for use in fluorous biphase systems.
Tetrahedron,
54(7), 1145-1152.
https://doi.org/10.1016/S0040-4020(97)10214-91997
Wetenschappelijke publicaties
Gerold, A., Jastrzebski, J. T. B. H., Kronenburg, C. M. P., Krause, N., & Van Koten, G. (1997). Determination of the degree of aggregation of organocopper compounds by cryoscopy in tetrahydrofuran. Angewandte Chemie: International Edition, 36(7), 755-757.
Van Koten, G., Grove, D. M., & Jastrzebski, J. T. B. H. (1997). Supramolecular aryl transition metal catalysts; Selective product formation with organometallic radicals. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (1 ed., Vol. 38, pp. 640-641)
Rijnberg, E., Boersma, J., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1997). The role of neutral and radical anionic organozinc complexes in the alkylation reactions of 1,4-diaza-1,3-butadienes with diorganozinc compounds. Organometallics, 16(14), 3158-3164.
Rijnberg, E., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Spek, A. L., & Van Koten, G. (1997). Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) 6[Zn(CH2Ph)3]2. Journal of Organometallic Chemistry, 541(1-2), 181-185.
Donkervoort, J. G., Jastrzebski, J. T. B. H., Deelman, B. J., Kooijman, H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Novel aryltitanium(IV) complexes containing η 3-NCN- pseudofacial- and η 3-NCN-meridional-bonded [C 6H 3(CH 2NME 2) 2-2,6]-(abbreviated as NCN) ligands. Organometallics, 16(19), 4174-4184.
Donkervoort, J. G., Kronenburg, C. M. P., Deelman, B. J., Jastrzebski, J. T. B. H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Aryltitaniumf( IV) complexes with the η3-C,N,N′-pseudofacially coordinating ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]-. The X-ray crystal structure of [TiCl2( CNN)( O-i-Pr)]. Journal of Organometallic Chemistry, 547(2), 349-355.
Wijkens, P., Jastrzebski, J. T. B. H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Self-assembling of bis-ortho chelated diaminobenzyl- (NC′N) and butyl-lithium units to give 2: 2 mixed alkyllithium aggregates (NC′N)Li2Bu2Li2(NC′N) with a ladder structure. Chemical Communications, (22), 2143-2144.
Huls, D., Gunther, H., Van Koten, G., Wijkens, P., & Jastrzebski, J. T. B. H. (1997). Detection of scalar 6Li,15N coupling across coordinative Li-N bonds. Angewandte Chemie: International Edition, 36(23), 2629-2631.
Steenwinkel, P., Jastrzebski, J. T. B. H., Deelman, B. J., Grove, D. M., Kooijman, H., Veldman, N., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1997). Hypercoordinate aryltrialkylsilanes and -stannanes and their use in the synthesis of homodinuclear organometallic complexes with a 1,4-phenylene bridge. Organometallics, 16(25), 5486-5498.
Rietveld, M. H. P., Klumpers, E. G., Jastrzebski, J. T. B. H., Grove, D. M., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Alkylidene-centered rearrangement of a tantalum alkylidene alkoxide species with the N,C,N-bis-ortho-chelated 1,2,6-trisubstituted aryldiamine ligand [C6H3(CH2NMe2)2-2,6] - to a product with a C,N-mono-ortho-chelated 1,2,4-Trisubstituted aryldiamine ligand. Organometallics, 16(20), 4260-4267.
Rijnberg, E., Hovestad, N. J., Kleij, A. W., Jastrzebski, J. T. B. H., Boersma, J., Janssen, M. D., Spek, A. L., & Van Koten, G. (1997). Application of S,N-chelating chiral zinc bis(aminoarenethiolates) as new precursor catalysts in the enantioselective addition of dialkylzincs to aldehydes. Organometallics, 16(13), 2847-2857.
Rijnberg, E., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). 1: 1 and 2:1 lithium zincates with intramolecular coordination. structures of Li(thf)Zn(C6H4CH2NMe2-2)3 and Li2Zn(C6H4CH2NMe2-2) 4. Organometallics, 16(11), 2239-2245.
1996
Wetenschappelijke publicaties
Hogerheide, M. P., Ringelberg, S. N., Grove, D. M., Jastrzebski, J. T. B. H., Boersma, J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1996). A Proposal for Positive Cooperativity in Anion-Cation Binding in Yttrium and Lutetium Complexes Based on o-Amino-Substituted Phenolate Ligands. on the Way to Coordination Polymers by Self-Assembly. Molecular Structures of [ClLu(OAr)3Na] (X-ray) and [ClY(OAr')3Y(OAr')3Na] (X-ray and 89Y-NMR). Inorganic Chemistry, 35(5), 1185-1193.
Donkervoort, J. G., Vicario, J. L., Jastrzebski, J. T. B. H., Cahiez, G., & Van Koten, G. (1996). Novel organomanganese(II) complexes active as homogeneous catalysts in manganese(II)/copper(I) catalyzed carbon-carbon bond formation reactions. Recueil des Travaux Chimiques des Pays-Bas, 115(11-12), 547-548.
1995
Wetenschappelijke publicaties
Hogerheide, M. P., Grove, D. M., Boersma, J.
, Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & van Koten, G. (1995).
New Coordinatively Unsaturated Lutetium Mono‐ and Bis(alkyl) Complexes with a Bis(ortho)‐Chelating Aryldiamine Ligand—Crystal Structures of [LuCl2{2,6‐(Me2NCH2)2C6H3}(μ‐Cl)(μ‐Li(thf)2)]2 and [Lu(μ‐Cl){2,6‐(Me2NCH2)2C6H3}(CH2SiMe3)]2.
Chemistry – A European Journal,
1(6), 343-350.
https://doi.org/10.1002/chem.19950010604Wijkens, P., Van Koten, E. M., Janssen, M. D., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1995). The formation of a mixed organolithium aggregate Li4R2nBu2 during the heteroatom-assisted lithiation of 1,3-bis(dimethylaminomethyl)-2,4,6-trimethylbenzene (R = 2,6-(CH2NMe2)2-3,5-Me2C 6HCH2). Angewandte Chemie: International Edition, 34(2), 219-222.
Rijnberg, E., Boersma, J.
, Jastrzebski, J. T. B. H., Lakin, M. T.
, Spek, A. L., & Van Koten, G. (1995).
Heteroleptic metallacyclic potassium organodiamido zincate complex. Synthesis and structure of polymeric {[K(thf)][MeZn(ButNCH=CHNBu t)]}n.
Journal of the Chemical Society, Chemical Communications, (18), 1839-1840.
https://doi.org/10.1039/C39950001839van Maanen, H. L., Kleijn, H., Jastrzebski, J. TBH., & van Koten, G. (1995). Diastereocontrol via cosolvents in the zinc ester eeolate-imine condensation route to β-lactams. Bulletin de la Societe Chimique de France, 132(1), 86-94.
Hogerheide, M. P., Wesseling, M., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Spek, A. L., & Van Koten, G. (1995). Versatility in phenolate bonding in organoaluminum complexes containing mono- and bis-ortho-chelating phenolate ligands. X-ray structures of Al{OC6H2(CH2NMe2) 2-2,6-Me-4}3, Al(Me)2{OC6H2(CH2NMe 2)2-2,6-Me-4}·N-AlMe ... Organometallics, 14(10), 4483-4492.
Van Maanen, H. L., Kleijn, H., Jastrzebski, J. T. B. H., Verweij, J., Kieboom, A. P. G., & Van Koten, G. (1995). Asymmetric synthesis of β-lactams via the zinc-mediated glycine ester enolate - Imine condensation reaction using α-amino esters as the chiral auxiliary. Journal of Organic Chemistry, 60(14), 4331-4338.
1994
Wetenschappelijke publicaties
van Maanen, H. L.
, Kleijn, H., Jastrzebski, J. T. B. H., & van Koten, G. (1994).
The synthesis of 3‐alkyl‐ and 3‐aryl‐β‐lactams from zinc enolates and imines.
Recueil des Travaux Chimiques des Pays‐Bas,
113(12), 567-572.
https://doi.org/10.1002/recl.19941131207Hogerheide, M. P., Jastrzebski, J. T. B. H., Boersma, J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1994). Cooperative binding of Na+ and Cl- in Na{M[OC6H2(CH2NMe2) 2-2,6-Me-4]3Cl}: Synthesis (M = Lu, Y) and X-ray structure (M = Lu) of new heterometallic complexes of lutetium and yttrium containing bis(o-amino)phenolate ligands. Inorganic Chemistry, 33(20), 4431-4432.
Van Maanen, H. L., Kleijn, H., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1994). Dualistic reactivity of lithium and zinc dienolates with imines: Effects of counterion, temperature, and substituents on α- and γ-coupling. Journal of Organic Chemistry, 59(25), 7839-7848.
Rijnberg, E.
, Jastrzebski, J. T. B. H., Janssen, M. D., Boersma, J.
, & Van Koten, G. (1994).
Application of N,S-chelating chiral zinc bis(arenethiolate) complexes as new precursor catalysts in the enantioselective addition of diethylzinc to aldehydes.
Tetrahedron Letters,
35(35), 6521-6524.
https://doi.org/10.1016/S0040-4039(00)78262-1Van Maanen, H. L.
, Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & Van Koten, G. (1994).
Highly functionalized β-enamino esters via C-C coupling reactions of lithium enolates of protected glycine esters and isothiocyanates.
Tetrahedron,
50(39), 11509-11526.
https://doi.org/10.1016/S0040-4020(01)89288-71993
Wetenschappelijke publicaties
Wehman-Ooyevaar, I. C. M., Vedral, J. A.
, Jastrzebski, J. T. B. H., Grove, D. M.
, & van Koten, G. (1993).
Novel rhodate and iridate complexes containing C,N chelating arylamine ligand systems.
Journal of Organometallic Chemistry,
451(1-2), 195-204.
https://doi.org/10.1016/0022-328X(93)83026-RWissing, E.
, Jastrzebski, J. T. B. H., Boersma, J.
, & van Koten, G. (1993).
An unexpected 1,2-alkyl shift within a chelate bonded organoaluminium-enamine.
Journal of Organometallic Chemistry,
459(1-2), 11-16.
https://doi.org/10.1016/0022-328X(93)86050-RVan Der Schaaf, P. A., Jastrzebski, J. T. B. H., Hogerheide, M. P., Smeets, W. J. J., Spek, A. L., Boersma, J., & Van Koten, G. (1993). Mono- and bis-ortho-chelated lithium and sodium phenolates. Molecular structures of the first lithium phenolate with a stable, trinuclear structure and of a tetranuclear sodium analog, [MOC6H2(CH2NMe2) 2-2,6-Me-4]x (M = Li, x = 3; M = Na, x = 4). Inorganic Chemistry, 32(19), 4111-4118.
Jastrzebski, J. T. B. H., & Van Koten, G. (1993).
The zinc mediated condensation of amino acid esters with imines to β- lactams.
Bioorganic & Medicinal Chemistry Letters,
3(11), 2351-2356.
https://doi.org/10.1016/S0960-894X(01)80954-9 Van Maanen, H. L.
, Jastrzebski, J. T. B. H., Verweij, J., Kieboom, A. P. G.
, Spek, A. L., & Van Koten, G. (1993).
(R)-2-Phenylglycine as a chiral auxiliary in the asymmetric synthesis of 2-azetidinones.
Tetrahedron-Asymmetry,
4(7), 1441-1444.
https://doi.org/10.1016/S0957-4166(00)80336-51992
Wetenschappelijke publicaties
Abbenhuis, H. C. L., Faiken, N., Grove, D. M., Jastrzebski, J. T. B. H., Kooijman, H., Van Der Sluis, P., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1992). Use of an aryldiamine pincer ligand in the study of tantalum alkylidene-centered reactivity: Tantalum-mediated alkene synthesis via reductive rearrangements and wittig-type reactions. Journal of the American Chemical Society, 114(25), 9773-9781.
Jastrzebski, J. T. B. H., Van Der Schaaf, P. A., Boersma, J., Van Koten, G., De Ridder, D. J. A., & Heijdenrijk, D. (1992). Evidence for hexacoordinate tin centers in triorganotin halides containing two 8-(dimethylamino)-1-naphthyl ligands. Organometallics, 11(4), 1521-1526.
Kleijn, H., van Maanen, H. L., Jastrzebski, J. T. B. H., & van Koten, G. (1992). Diastereo- and enantio-selective synthesis of trans-3-phenyl- and trans-3-styryl-2-azetidinones via zinc ester enolates and imines. Recueil des Travaux Chimiques des Pays-Bas, 111(11), 497-498.
Van Der Steen, F. H., Kleijn, H., Britovsek, G. J. P., Jastrzebski, J. T. B. H., & Van Koten, G. (1992). Enantioselective synthesis of 3-amino-2-azetidinones via the ester enolate-imine condensation. Journal of Organic Chemistry, 57(14), 3906-3916.
Brown, J. M., Pearson, M.
, Jastrzebski, J. T. B. H., & Van Koten, G. (1992).
Intramolecular facilitation of aryl-transfer from tin in palladium-catalysed cross-coupling.
Journal of the Chemical Society, Chemical Communications, (19), 1440-1441.
https://doi.org/10.1039/C39920001440Brown, J. M., Pearson, M., Jastrzebski, J. T. B. H., & Van Koten, G. (1992). Corigendum: Intramolecular facilitation of aryl-transfer from tin in palladium-catalysed cross-coupling (Journal Chemical Communications (1992) (1440)). Journal of the Chemical Society, Chemical Communications, (24), 1802.
1991
Wetenschappelijke publicaties
Jastrzebski, J. T. B. H., Grove, D. M., Boersma, J.
, van Koten, G., & Ernsting, JM. M. (1991).
119Sn NMR study of organotin compounds having intramolecular Sn—N coordination.
Magnetic Resonance in Chemistry,
29(13), S25-S30.
https://doi.org/10.1002/mrc.1260291308 Jastrzebski, J. T. B. H., Wehman, E., Boersma, J.
, van Koten, G., Goubitz, K., & Heijdenrijk, D. (1991).
Synthesis and structure of [2-(4,4-dimethyl-2-oxazoline)-5-methylphenyl]methylphenyltin bromide. A novel triorganotin halide having a configurationally stable chiral tin center.
Journal of Organometallic Chemistry,
409(1-2), 157-162.
https://doi.org/10.1016/0022-328X(91)86140-L Jastrzebski, J. T. B. H., Boersma, J., Esch, P. M., & Van Koten, G. (1991). Intramolecular penta- and hexacoordinate tetraorganotin compounds containing the 8-(dimethylamino)-1-naphthyl ligand. Organometallics, 10(4), 930-935.
Jastrzebski, J. T. B. H., Boersma, J.
, & van Koten, G. (1991).
Organotin(IV) compounds 2-(Me2NCHR)C6H4(SnR′R″Br) with a fixed s-cis arrangement of the chiral carbon and tin centers. Crystal structure of 2-(Me2NCHBut)C6H4SnMePhBr.
Journal of Organometallic Chemistry,
413(1-3), 43-53.
https://doi.org/10.1016/0022-328X(91)80037-K Jastrzebski, J. T. B. H., van der Schaaf, P. A., Boersma, J.
, van Koten, G., de Wit, M., Wang, Y., Heijdenrijk, D., & Stam, C. H. (1991).
Oxidative-addition reactions of molecular diiodine and dibromine to divalent organotin compounds. Crystal structures of bis[8-(dimethylamino)-1-naphthyl]tin(IV) dibromide and {2,6-[bis(dimethylamino)methyl]phenyl}- (4-tolyl)tin(IV) diodide.
Journal of Organometallic Chemistry,
407(3), 301-311.
https://doi.org/10.1016/0022-328X(91)86308-D Van Der Steen, F. H., Kleijn, H., Jastrzebski, J. T. B. H., & Van Koten, G. (1991). A new and efficient route to 3-amino-2-azetidinones via zinc enolates of N,N-disubstituted glycine esters. Journal of Organic Chemistry, 56(16), 5147-5158.
1990
Wetenschappelijke publicaties
Jastrzebski, J. T. B. H., Sypkens, H. A. J., des Tombe, F. J. A., van der Schaaf, P. A., Boersma, J.
, van Koten, G., Spek, A. L., & Duisenberg, A. J. M. (1990).
Crystal structure of zinc[bis[3-(dimethylamino)propyl-C,N]tin]bis(dibenzoylmethanato)-(SnZn). The first example of a dialkyltin(II) compound stabilized by SnZn coordination.
Journal of Organometallic Chemistry,
396(1), 25-31.
https://doi.org/10.1016/0022-328X(90)85189-6 1989
Wetenschappelijke publicaties
Jastrzebski, J. T. B. H., van der Schaaf, P. A., Boersma, J.
, van Koten, G., Zoutberg, M. C., & Heijdenrijk, D. (1989).
Synthesis and Characterization of {2, 6-Bis[(dimethylamino)methyl]phenyl}tin(II) Chloride and {2, 6-Bis[(dimethylamino)methyl]phenyl}4-tolyltin(II), the First Example of a Mixed Dlaryitin(II) Compound.
Organometallics,
8(5), 1373-1375.
https://doi.org/10.1021/om00107a038 Jastrzebski, J. T. B. H., van der Schaaf, P. A., Boersma, J.
, Koten, G. V., Heijdenrijk, D., Goubitz, K., & de Ridder, D. J. A. (1989).
Synthesis and characterization of a stable bis-naphthyltin(II) compound. Bis[8-(dimethylamino)-1-naphthyl-C,N]tin(II) and its W(CO)5 adduct.
Journal of Organometallic Chemistry,
367(1-2), 55-68.
https://doi.org/10.1016/0022-328X(89)87205-5 Wehman, E., Van Koten, G., Erkamp, C. J. M., Knotter, D. M., Jastrzebski, J. T. B. H., & Stam, C. H. (1989). Bis-ortho-chelated arylcopper compounds. Synthesis and X-ray crystal structure of Cu4Br2[C6H3(CH2NMe 2)2-o,o′2. Organometallics, 8(1), 94-99.
van Koten, G., & Jastrzebski, J. T. B. H. (1989).
Polynuclear aryl-copper species and neutral aryl-cuprates with a chiral-CH(Me)NMe2 ortho substituent.
Tetrahedron,
45(2), 569-578.
https://doi.org/10.1016/0040-4020(89)80084-5 Van Der Steen, F. H.
, Kleijn, H., Jastrzebski, J. T. B. H., & Van Koten, G. (1989).
The synthesis of β-lactams from zinc enolates of n,n-disubstituted α-aminoacid esters and imines: Substituent and solvent effects.
Tetrahedron Letters,
30(6), 765-768.
https://doi.org/10.1016/S0040-4039(01)80304-X1988
Wetenschappelijke publicaties
Wehman, E.
, Jastrzebski, J. T. B. H., Ernsting, J. M., Grove, D. M.
, & van Koten, G. (1988).
Structural investigations of aryllithium clusters in solution II. A. 13C and 7Li NMR study of substituted phenyllithium compounds containing ortho-directing NME2 and CH2NMe2 groups.
Journal of Organometallic Chemistry,
353(2), 145-155.
https://doi.org/10.1016/0022-328X(88)83058-4Jastrzebski, J. T. B. H., van Koten, G., & van de Mieroop, W. F. (1988).
X-ray crystal structure of the hexameric lithium enolate of ethyl N, N-diethylglycinate.
Inorganica Chimica Acta,
142(2), 169-171.
https://doi.org/10.1016/S0020-1693(00)81551-0 Zoet, R., Jastrzebski, J. T. B. H., Van Koten, G., Mahabiersing, T., Vrieze, K., Heijdenrijk, D., & Stam, C. H. (1988). Synthesis and characterization of two isomers of decacarbonyl(1,4-dialkyl-1,4-diaza-1,3-butadiene)triosmium: Os3(CO)10(R-DAB). Fluxional behavior of Os3(CO)10(i-Pr-DAB(4e)). Molecular structures of the 48e cluster Os3(CO)10(i-Pr-DAB(4e)) and of the 50e cluster Os3(CO)10 ... Organometallics, 7(10), 2108-2117.
Jastrzebski, J. T. B. H., Boersma, J., van Koten, G., Smeets, W. J. J., & Spek, A. L. (1988). X-ray crystal structure of the ethylzinc enolate of 1-(2,4-cyclopentadienyl)-2-(diethylamino)-1-ethanone, the unexpected reaction product from cyclopentadienyl(ethyl)zinc and ethyl N, N-diethylglycinate. Recueil des Travaux Chimiques des Pays-Bas, 107(3), 263-266.
Wehman, E., Van Koten, G., Jastrzebski, J. T. B. H., Rotteveel, M. A., & Stam, C. H. (1988). Functionally substituted arylcopper compounds: Synthesis, structure, and reactivity of (2-(2-oxazolinyl)aryl)copper(I) species. Organometallics, 7(7), 1477-1485.
Wehman, E.
, Jastrzebski, J. T. B. H., Ernsting, J. M., Grove, D. M.
, & van Koten, G. (1988).
Structural investigation of aryllithium clusters in solution I. A 13C and 7Li NMR study of phenyllithium and some methyl-substituted phenyllithium derivatives.
Journal of Organometallic Chemistry,
353(2), 133-143.
https://doi.org/10.1016/0022-328X(88)83057-2Wehman, E.
, Van Koten, G., Jastrzebski, J. T. B. H., Ossor, H., & Pfeffer, M. (1988).
Synthesis of cyclometallated naphthylpalladium complexes via transmetallation reactions of naphthylmercury with palladium species. Crystal structure determination of [{Pd(mxn)(O2CMe)}2].
Journal of the Chemical Society, Dalton Transactions, (12), 2975-2981.
https://doi.org/10.1039/DT9880002975Van der Steen, F. H.
, Jastrzebski, J. T. B. H., & Van Koten, G. (1988).
Stereoselective one-pot synthesis of trans-3-amino-β-lactams from zinc enolates of N-protected α-aminoacid esters and imines.
Tetrahedron Letters,
29(20), 2467-2470.
https://doi.org/10.1016/S0040-4039(00)87909-51987
Wetenschappelijke publicaties
Maassarani, F., Pfeffer, M., Le Borgne, G., Jastrzebski, J. T. B. H., & Van Koten, G. (1987). Organopalladium compounds with a chiral palladated carbon atom. Facile isolation of optically active cyclopalladated complexes containing the (S)- or (R)-[2-NMe2C6H4CH(SiMe3)] monoanion. Molecular structure of {2-[1-(S)-(dimethylamino)ethyl]phenyl}[2-(dimethylamino)-α- (trimethylsilyl)benzyl]palladium(II). Organometallics, 6(5), 1111-1118.
Van Vliet, M. R. P., Van Koten, G., Buysingh, P., Jastrzebski, J. T. B. H., & Spek, A. L. (1987). Reactivity of 1-Aza-4-oxa-1,3-butadienes (α -imino ketones) toward diorganozinc reagents: Regio- and chemoselective transfer of organo groups in the ZnR2/R1N=C(R2)C(R3)=O system and x-ray structure of the organozinc enolate [EtZn(Et)(t-Bu)NC(H)=C(Me)O]2. Organometallics, 6(3), 537-546.
van Vliet, M. R. P., Jastrzebski, J. T. B. H., Klaver, W. J., Goubitz, K., & van Koten, G. (1987). The unexpected formation of trans-β-lactams in the reaction of α-iminoesters (R-N=C(H)C(=O)OR′) with diethylzinc. Crystal structure of trans-1-(N-t-butyl)-3-(N-t-butyl-N-ethylamino)-4-methoxycarbonylazetidin-2-one. Recueil des Travaux Chimiques des Pays-Bas, 106(4), 132-134.
Jastrzebski, J. T. B. H., van der Steen, F. H., & van Koten, G. (1987). Selective formation of 1,3,4-Trisubstituted and 3,4-Disubstituted trans-β-lactams from Zinc enolates and imines. Recueil des Travaux Chimiques des Pays-Bas, 106(9), 516-518.
Spek, A. L., Jastrzebski, J. T. B. H., & Van Koten, G. (1987).
Structure of μ‐[1,2‐bis(tert‐butylamino‐1: 2κN)‐1,2‐di(2‐pyridyl‐κN)ethane]‐bis(ethylzinc).
Acta Crystallographica. Section C, Crystal Structure Communications,
43(10), 2006-2007.
https://doi.org/10.1107/S0108270187089261 1986
Wetenschappelijke publicaties
Wehman, E.
, Van Koten, G., & Jastrzebski, J. T. B. H. (1986).
Functionally substituted arylcopper compounds; crystal structure of the copper bromide complex of [2-(4,4-dimethyl-2-oxazoline)-4-methylphenylcopper].
Journal of Organometallic Chemistry,
302(2).
https://doi.org/10.1016/0022-328X(86)80095-XJastrzebski, J. T. B. H., Van Koten, G., Knaap, C. T., Schreurs, A. M. M., Kroon, J., & Spek, A. L. (1986). Organotin(IV) compounds derived from 2-Me2NC6H4CH2Li and its chiral α-Me3Si derivative. X-ray structure of pentacoordinate [{2-(dimethylamino)phenyl}(trimethylsilyl)methyl-C,N]methylphenyltin bromide having a chiral Sn center. Organometallics, 5(8), 1551-1558.
1985
Wetenschappelijke publicaties
Jastrzebski, J. T. B. H., Van Koten, G., Christophersen, M. J. N., & Stam, C. H. (1985).
The unexpected formation of a lithium-enolate from bis2-[(dimethylamino)methyl]phenyl copper lithium. X-ray structure of Li4[OC(CH2)C6H4CH2NMe2-2]4.
Journal of Organometallic Chemistry,
292(3), 319-324.
https://doi.org/10.1016/0022-328X(85)80217-5 Van Koten, G., Jastrzebski, J. T. B. H., Muller, F., & Stam, C. H. (1985). Crystal structure of the neutral diarylcuprate Cu2Li2(C6H4CH2NMe 2-2)4: The asymmetric bonding configuration of organo groups bridging Cu and Li. Journal of the American Chemical Society, 107(3), 697-698.
1984
Wetenschappelijke publicaties
Van Koten, G., Jastrzebski, J. T. B. H., Stam, C. H., & Niemann, N. C. (1984). Solid-state structure of [Au2Li2(C6H4CH2NMe 2-2)4]: A model for the reactive structure of organocuprates. Journal of the American Chemical Society, 106(6), 1880-1881.
1983
Wetenschappelijke publicaties
Jastrzebski, J. T. B. H., van Koten, G., Goubitz, K., Arlen, C., & Pfeffer, M. (1983).
Synthesis of 8-(dimethylamino)-1-naphthyllithium etherate: its structure in the solid (x-ray) and in solution (7Li and 1H NMR).
Journal of Organometallic Chemistry,
246(3).
https://doi.org/10.1016/S0022-328X(00)98740-0 Jastrzebski, J. T. B. H., Knaap, C. T.
, & van Koten, G. (1983).
Pentacoordinate [8-(dimethylamino)naphthyl]diorganotin halides containing a rigid, flat NCCCSn chelate ring. An unexpected redistribution reaction between [8-(dimethylamino)naphthyl]trimethyltin and trimethyltin halide.
Journal of Organometallic Chemistry,
255(3), 287-293.
https://doi.org/10.1016/S0022-328X(00)99320-3 Van Vliet, M. R. P.
, Jastrzebski, J. T. B. H., Van Koten, G., Vrieze, K.
, & Spek, A. L. (1983).
Novel reactions of substituted 1-aza-4-oxobutadienes (α-iminoketones) with diorganozinc reagents. Selective ethyl transfer in the Et2Zn/t-BuNC(H)C(Me)O system and x-ray crystal structure of [EtZn(Et)(T-Bu)NC(H)C(Me)O]2.
Journal of Organometallic Chemistry,
251(1).
https://doi.org/10.1016/0022-328X(83)80256-3Van Koten, G., Jastrzebski, J. T. B. H., & Vrieze, K. (1983).
Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic syntheses.
Journal of Organometallic Chemistry,
250(1), 49-61.
https://doi.org/10.1016/0022-328X(83)85039-6 1982
Wetenschappelijke publicaties
Klerks, J. M.
, Jastrzebski, J. T. B. H., & Van Koten, G. (1982).
Regioselective ethyl transfer reactions between Diethylzinc and 1,4-Dialkyl-1,4-diaza-1,3-butadienes: Synthesis of EtZn[R(et)NCHCHNR].
Journal of Organometallic Chemistry,
224(2), 107-119.
https://doi.org/10.1016/S0022-328X(00)89030-0Jastrzebski, J. T. B. H., Van Koten, G., Konijn, M., & Stam, C. H. (1982). Intramolecularly chelated di- and tetranuclear aryllithium compounds: Crystal structure of Li4[C6H4(2-CH2NMe2)] 4 containing four-center two-electron-bonded C(aryl) atoms and heptacoordinate lithium atoms. Journal of the American Chemical Society, 104(20), 5490-5492.
1981
Wetenschappelijke publicaties
Jastrzebski, J. T. B. H., Klerks, J. M.
, van Koten, G., & Vrieze, K. (1981).
An unexpected ethyl transfer reaction between Et2Zn and DI(t-Butyl)-glyoxaldiimine (t-BuDAB). Studies of the persistent [EtZn(t-BuDAB)] radical which is in equilibrium with its CC coupled dimer.
Journal of Organometallic Chemistry,
210(3).
https://doi.org/10.1016/S0022-328X(00)80905-5 1980
Wetenschappelijke publicaties
Van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Verhoeckx, G. J.
, Spek, A. L., & Kroon, J. (1980).
Crystal and molecular structure of SnMePh[C10H5(OMe-5)(CH2NMe2-8)]Br and proton nuclear magnetic resonance study of the puckering of the chelate ring in five-co-ordinate triorganotin halides ... Journal of the Chemical Society, Dalton Transactions, (8), 1352-1358.
https://doi.org/10.1039/DT9800001352 Van Koten, G., Schaap, C. A.
, Jastrzebski, J. T. B. H., & Noltes, J. G. (1980).
Group IB organometallic chemistry. XXXIII. ArAuPPh3, ArAu(CNR), (ArAu)n and Ar4Cu2Au2 compounds in which the aryl group contains 2-MeO, 2,6-(MeO)2, 2-Me2N, 2-Me2NCH2 and (S)- or (R)-2-Me2NCHMe substituents as potential ligands.
Journal of Organometallic Chemistry,
186(3), 427-445.
https://doi.org/10.1016/S0022-328X(00)82423-7 1979
Wetenschappelijke publicaties
Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1979).
Group IB organometallic chemistry. XXXII. Arylcopper compounds ArnCun as intermediates in organometallic synthesis. Single-step synthesis and dynamic NMR spectroscopy of diorganotin dihalides Ar2-nRnSnX2 (Ar 2-Me2NCH2C6H4 or (S)-2-Me2NCHMeC6H4; n 0 or 1).
Journal of Organometallic Chemistry,
177(1), 283-292.
https://doi.org/10.1016/S0022-328X(00)92354-4 1978
Wetenschappelijke publicaties
van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1978).
Group IB organometallic chemistry. XXII. Reactions of Ar4Cu2Li2 and Ar4Au2Li2 with RhI complexes: synthesis of 2-[(dimethylamino)methyl]phenylrhodium dicarbone monoxide, and electron-transfer induced selective formation of diaryl ketones ArC(O)Ar.
Journal of Organometallic Chemistry,
148(3), 317-325.
https://doi.org/10.1016/S0022-328X(00)90988-4 van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G.
, Spek, A. L., & Schoone, J. C. (1978).
Triorganotin cations stabilized by intramolecular SnN coordination; synthesis and characterization of {C,N,N′-2,6-bis[(dimethylamino)methyl]phenyl}diorganotin bromides {A figure is presented}.
Journal of Organometallic Chemistry,
148(3), 233-245.
https://doi.org/10.1016/S0022-328X(00)90980-X Van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Pontenagel, W. M. G. F., Kroon, J., & Spek, A. L. (1978). Synthesis of C,Sn-chiral triorganotin halides via C-chiral arylcopper and arylgoldlithium intermediates. Crystal and molecular structure of one {2-[1-(S)-(dimethylamino)ethyl]phenyl}methylphenyltin bromide diastereomer. Journal of the American Chemical Society, 100(16), 5021-5028.
1977
Wetenschappelijke publicaties
van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977).
Stable tetranuclear 4-tolyl-copperlithium ("cuprate") and -goldlithium ("aurate") compounds.
Journal of Organometallic Chemistry,
140(2).
https://doi.org/10.1016/S0022-328X(00)93202-9 Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977).
Determination by microwave titration of the stoichiometry of phosphine and amine complexes of cuprous trifluoromethanesulphonate (copper triflate).
Inorganica Chimica Acta,
21(C).
https://doi.org/10.1016/S0020-1693(00)86210-6 Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977). Group 1B organometallic chemistry. 18. Novel routes to stable hexanuclear copper-silver, silver-gold, and copper-gold cluster compounds starting from polymeric 2-(dimethylamino)phenylcopper and from bis[(2-dimethylamino)pheny l]goldlithium dimer. Inorganic Chemistry, 16(7), 1782-1787.
Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977). Selective formation of biaryls via interaction of polynuclear arylcopper compounds with copper(I) trifluoromethanesulfonate [copper(I) triflate]. Journal of Organic Chemistry, 42(12), 2047-2053.
Van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1977).
Interaction of arylmetal compounds of group 1B with copper(I) and silver(I) trifluoromethanesulphonate; a novel biaryl synthesis and a route to hexanuclear aryl-CuAg, -AgAu, and -CuAu clusters.
Journal of the Chemical Society, Chemical Communications, (7), 203-204.
https://doi.org/10.1039/C39770000203 1976
Wetenschappelijke publicaties
van Koten, G., Jastrzebski, J. T. B. H., & Noltes, J. G. (1976).
Are arylcopper compounds intermediates in the exchange reaction between aryl halides and copper(I) salts? Tetrahedron Letters,
17(3), 223-226.
https://doi.org/10.1016/0040-4039(76)80023-8