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Prof. dr. A.L. (Ton) Spek

Emeritus Professor 
Science
Chemistry
Chemistry
Hugo R. Kruytgebouw
Padualaan 8
Kamer N801
3584 CH Utrecht

Prof. dr. A.L. (Ton) Spek

Emeritus Professor
Chemistry
+31 30 253 2538
a.l.spek@uu.nl
Profile Publications Ancillary activities Contact
Profile Publications Ancillary activities Contact

Publications

2018

Scholarly publications

Spek, A. L. (2018). What makes a crystal structure report valid? Inorganica Chimica Acta, 470, 232-237. https://doi.org/10.1016/j.ica.2017.04.036

2017

Scholarly publications

Spek, A. L. (2017). What makes a structure report valid? Acta Crystallographica Section A Foundations and Advances, A73(a2), C1319. https://doi.org/10.1107/S2053273317082560

2014

Scholarly publications

Van Walree, C. A., Dabirian, R., Lutz, M., Spek, A. L., Jenneskens, L. W., & Havenith, R. W. A. (2014). Erratum: Molecular and solid state structure of 4,4′- bis(tetrahydrothiopyranyl) (Journal of Molecular Structure (2013) 1036 (115-120)). Journal of Molecular Structure, 1065-1066(1), 262. https://doi.org/10.1016/j.molstruc.2014.02.049
Batema, G. D., Lutz, M., Spek, A. L., van Walree, C. A., van Klink, G. P. M., & van Koten, G. (2014). Organometallic benzylidene anilines: donor-acceptor features in NCN-pincer Pt(II) complexes with a 4-(E)-[(4-R-phenyl)imino]methyl substituent. Dalton Transactions, 43(32), 12200-12209. https://doi.org/10.1039/c4dt01023j
Pijnenburg, N. J. M., Tomás-Mendivil, E., Mayland, K. E., Kleijn, H., Lutz, M., Spek, A. L., Van Koten, G., & Klein Gebbink, B. (2014). Monomeric and dendritic second generation Grubbs- and Hoveyda-Grubbs-type catalysts for olefin metathesis Metallodendrimers Special Issue. Inorganica Chimica Acta, 409(PART A), 163-173. https://doi.org/10.1016/j.ica.2013.06.018
Moelands, M. A. H., Schamhart, D. J., Folkertsma, E., Lutz, M., Spek, A. L., & Klein Gebbink, B. (2014). Facial triad modelling using ferrous pyridinyl prolinate complexes: synthesis and catalytic applications. Dalton Transactions, 43(18), 6769-6785. https://doi.org/10.1039/c3dt53266f

2013

Scholarly publications

Moelands, M. A. H., Nijsse, S., Folkertsma, E., de Bruin, B., Lutz, M., Spek, A. L., & Klein Gebbink, R. J. M. (2013). Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands. Inorganic Chemistry, 52(13), 7394-7410. https://doi.org/10.1021/ic400096e

2012

Scholarly publications

Bocokić, V., Lutz, M., Spek, A. L., & Reek, J. N. H. (2012). Bis-(thiosemicarbazonato) Zn(II) complexes as building blocks for construction of supramolecular catalysts. Dalton Transactions, 41, 3740-3750. https://doi.org/10.1039/C2DT12096H

2011

Scholarly publications

Snelders, D. J. M., Siegler, M. A. M., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2011). Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines. Dalton Transactions, 40(11), 2588-2600. https://doi.org/10.1039/C0DT01105C
Berding, J., Lutz, M., Spek, A. L., & Bouwman, E. (2011). Nickel N-heterocyclic carbene complexes in the vinyl polymerization of norbornene. Applied Organometallic Chemistry, 25(1), 76-81. https://doi.org/10.1002/aoc.1714
den Heeten, R., Zuidema, E., Lutz, M., Spek, A. L., van Leeuwen, P. W. N. M., & Kamer, P. C. J. (2011). Bisxantphos: stereoselective synthesis and coordination behaviour of a new class of cyclic double bridged diphosphines. Journal of Organometallic Chemistry, 696(19), 3113-3120. https://doi.org/10.1016/j.jorganchem.2011.06.019
Chuchuryukin, A. V., Huang, R., van Faassen, E. E. H., van Klink, G. P. M., Lutz, M., Chadwick, J. C., Spek, A. L., & van Koten, G. (2011). Mono N,C,N-pincer complexes of titanium, vanadium and niobium : synthesis, structure and catalytic activity in olefin polymerisation. Dalton Transactions, 40(35), 8887-8895. https://doi.org/10.1039/C1DT10482A
Wolf, R., Ehlers, A. W., Khusniyarov, M. M., Hartl, F., de Bruin, B., Long, G. J., Grandjean, F., Schappacher, F. M., Pöttgen, R., Slootweg, J. C., Lutz, M., Spek, A. L., & Lammertsma, K. (2011). Homoleptic Diphosphacyclobutadiene Complexes [M(η4-P2C2R2)2]x- (M=Fe, Co; x=0, 1). Chemistry-A European Journal, 16(48), 14322-14334. https://doi.org/10.1002/chem.201001913
Bruijnincx, P. C. A., Buurmans, I. L. C., Huang, Y., Juhász, G., Viciano-Chumillas, M., Quesada, M., Lutz, M., Spek, A. L., Münck, E., Bominaar, E. L., & Klein Gebbink, R. J. M. (2011). Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): Structure, magnetic properties and catalytic oxidation studies. Inorganic Chemistry, 50(19), 9243-9255. https://doi.org/10.1021/ic200332y

2010

Scholarly publications

Marques Gallego, P., Amparo Gamiz-Gonzalez, M., Fortea-Pérez, F. R., Lutz, M., Spek, A. L., Pevec, A., Kozlevar, B., & Reedijk, J. (2010). Quinoxaline-2-carboxamide as a carrier ligand in two new platinum(ii) compounds: Synthesis, crystal structure, cytotoxic activity and DNA interaction. Dalton Transactions, 39(21), 5152-5158. https://doi.org/10.1039/c001158d
Li, J., Lutz, M., Spek, A. L., van Klink, G. P. M., van Koten, G., & Klein Gebbink, R. J. M. (2010). Chiral amino alcohol derived bis-phosphoramidite pincer palladium complexes and their applications in asymmetric allylation of aldimines. Organometallics, 29(6), 1379-1387. https://doi.org/10.1021/om100021p
Campos Carrasco, A., Pidko, E. A., Masdeu-Bultó, A. M., Lutz, M., Spek, A. L., Vogt, D., & Müller, C. (2010). 2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i). New Journal of Chemistry, 34(8), 1547-1550. https://doi.org/10.1039/c0nj00030b
Berthon-Gelloz, G., Siegler, M. A., Spek, A. L., Tinant, B., Reek, J. N. H., & Markó, I. E. (2010). IPr* an easily accessible highly hindered N-heterocyclic carbene. Dalton Transactions, 39(6), 1444-1446. https://doi.org/10.1039/b921894g

2009

Scholarly publications

Marson, A., Ernsting, J. E., Lutz, M., Spek, A. L., van Leeuwen, P. W. N. M., & Kamer, P. C. J. (2009). A novel hemilabile calix[4],quinoline-based P,N-ligand: coordination chemistry and complex characterisation. Dalton Transactions, 2009(4), 621-633.
Roy, S., Maheswari, P. U., Lutz, M., Spek, A. L., den Dulk, H., Barends, S., van Wezel, G. P., Hartl, F., & Reedijk, J. (2009). DNA cleavage and antitumour activity of platinum(II) and copper(II) compounds derived from 4-methyl-2-N-(2-pyridylmethyl)aminophenol: spectroscopic, electrochemical and biological investigation. Dalton Transactions, 2009(48), 10846-10860.
https://dspace.library.uu.nl/bitstream/handle/1874/44358/b911542k.pdf?sequence=1
Berding, J., Lutz, M., Spek, A. L., & Bouwman, E. (2009). Synthesis of novel chelating benzimidazole-based carbenes and their nickel(II) complexes: activity in the Kumada coupling reaction. Organometallics, 28(6), 1845-1854.
Kuil, M., Puijk, I. M., Kleij, A. W., Tooke, D. M., Spek, A. L., & Reek, J. N. H. (2009). The assembly of supramolecular boxes and coordination polymers based on bis-zinc-salphen building blocks. Chemistry - An Asian Journal, 4(1), 50-57.
Li, J., Siegler, M. A. M., Luz, V. B., Spek, A. L., Klein Gebbink, R. J. M., & van Koten, G. (2009). Chiral ortho-Palladated and -Platinated Arylphosphite Complexes. Organometallics, 28(18), 5323-5332. http://www.acs.org
Bertini, F., Wit, J. B. M., Ünal, M., de Kanter, F. J. J., Schakel, M., Slootweg, J. C., Ehlers, A. W., Nijbacker, T., Komen, C. M. D., Lutz, M., Spek, A. L., & Lammertsma, K. (2009). Phosphinidene addition to conjugated allenes. Advanced synthesis & catalysis, 351(7-8), 1132-1138.
Rubio, M., Jellema, E., Siegler, M. A. M., Spek, A. L., Reek, J. N. H., & de Bruin, B. (2009). Supramolecular NHC ligands: on the influence of ZnII-templates on the activity of RhI(cod) complexes in carbene polymerization. Dalton Transactions, 2009(41), 8970-8976.
https://dspace.library.uu.nl/bitstream/handle/1874/44384/b911339h.pdf?sequence=1
Wadman, S. H., Lutz, M., Tooke, D. M., Spek, A. L., Hartl, F., Havenith, R. W. A., van Klink, G. P. M., & van Koten, G. (2009). Consequences of N,C,N'-and C,N,N'-coordination modes on electronic and photophysical properties of cyclometalated aryl ruthenium(ll) complexes. Inorganic Chemistry, 48(5), 1887-1900.
Warsink, S., Hauwert, P., Siegler, M. A. M., Spek, A. L., & Elsevier, C. J. (2009). Palladium(0) pre-catalysts with heteroditopic NHC-amine ligands by transmetallation from their silver(I) complexes. Applied Organometallic Chemistry, 23(6), 225-228.
Virboul, M. A. N., Lutz, M., Siegler, M. A. M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2009). One-Pot Synthesis and Immobilisation of Sulfonate-Tethered N-Heterocyclic Carbene Complexes on Polycationic Dendrimers. Chemistry-A European Journal, 15(39), 9981-9986.
Hooft, R. W. W., Straver, L. H., & Spek, A. L. (2009). Probability plots based on student’s t-distribution. Acta crystallographica. Section A, foundations of crystallography, A65, 319-321.
https://dspace.library.uu.nl/bitstream/handle/1874/43747/zm5057.pdf?sequence=2
Scheffelaar, R., Klein Nijenhuis, R. A., Paravidino, M., Lutz, M., Spek, A. L., Ehlers, A. W., de Kanter, F. J. J., Groen, M. B., Orru, R. V. A., & Ruijter, E. (2009). Synthesis of conformationally constrained peptidomimetics using multicomponent reactions. Journal of Organic Chemistry, 74(2), 660-668.
Patureau, F. W., de Boer, S., Kuil, M., Meeuwissen, J., Breuil, P-AR., Siegler, M. A. M., Spek, A. L., de Bruin, B., & Reek, J. N. H. (2009). Sulfonamido−phosphoramidite ligands in cooperative dinuclear hydrogenation catalysis. Journal of the American Chemical Society, 131(19), 6683-6685.
Spek, A. L. (2009). Structure validation in chemical crystallography. Acta crystallographica. Section D, biological crystallography, D65, 148-155.
Bonnet, S. A., Li, J., Siegler, M. A. M., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2009). Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands. Chemistry-A European Journal, 15(14), 3340-3343. http://www.wiley-vch.de
Bonnet, S. A., Molnar, G., Sanchez Costa, J., Siegler, M. A. M., Spek, A. L., Bousseksou, A., Fu, W. T., Gamez, P., & Reedijk, J. (2009). Influence of sample preparation, temperature, light, and pressure on the two-step spin crossover mononuclear compound. Chemistry of Materials, 21(6), 1123-1136.
Wolf, R., Slootweg, J. C., Ehlers, A. W., Hartl, F., de Bruin, B., Lutz, M., Spek, A. L., & Lammertsma, K. (2009). A phosphorus analogue of Bis(η4-cyclobutadiene)iron(0). Angewandte Chemie-International Edition, 48(17), 3104-3107.
Aktas, H., Slootweg, J. C., Ehlers, A. W., Lutz, M., Spek, A. L., & Lammertsma, K. (2009). N-Heterocyclic carbene functionalized goup 7-9 transition metal. Organometallics, 28(17), 5166-5172.

2008

Scholarly publications

Köcher, S., Walfort, B., Mills, A. M., Spek, A. L., van Klink, G. P. M., van Koten, G., & Lang, H. (2008). Synthesis and reaction chemistry of 4-nitrile-substituted NCN-pincer palladium(II) and platinum(II) complexes (NCN = [NC-4-C6H2(CH2NMe2)2-2,6]−). Journal of Organometallic Chemistry, 693(11), 1991-1996.
https://dspace.library.uu.nl/bitstream/handle/1874/33212/788.pdf?sequence=1
Kruithof, C. A., Dijkstra, H. P., Lutz, M., Spek, A. L., Egmond, M. R., Klein Gebbink, R. J. M., & van Koten, G. (2008). Non-tethered organometallic phosphonate inhibitors for lipase inhibition: positioning of the metal center in the active site of cutinase. European Journal of Inorganic Chemistry, 2008(28), 4425-4432.
https://dspace.library.uu.nl/bitstream/handle/1874/33216/790.pdf?sequence=1
Chase, P. A., Lutz, M., Spek, A. L., Gossage, R. A., & van Koten, G. (2008). Solid-state and solution structures of hetero-aggregates formed between nBuLi and NCN pincer aryl lithium. Dalton Transactions, 2008(42), 5783-5790.
https://dspace.library.uu.nl/bitstream/handle/1874/33260/794.pdf?sequence=1
Lutz, M., Spek, A. L., van der Geer, E. P. L., van Koten, G., & Klein Gebbink, R. J. M. (2008). Indole-3-thiouronium nitrate. Acta crystallographica. Section E, Structure reports, E64(1), o194.
https://dspace.library.uu.nl/bitstream/handle/1874/32995/762.pdf?sequence=1
Roy, S., Hagen, K. D., Maheswari, P. U., Lutz, M., Spek, A. L., Reedijk, J., & van Wezel, G. P. (2008). Phenanthroline derivatives with improved selectivity as dna-targeting anticancer or antimicrobial drugs. ChemMedChem, 3, 1427-1434.
https://dspace.library.uu.nl/bitstream/handle/1874/33040/37.pdf?sequence=1
Müller, C., Pidko, E. A., Staring, A. J. P. M., Lutz, M., Spek, A. L., van Santen, R. A., & Vogt, D. (2008). Developing a new class of axial chiral phosphorus ligands: preparation and characterization of enantiopure atropisomeric phosphinines. Chemistry-A European Journal, 14(16), 4899-4905.
https://dspace.library.uu.nl/bitstream/handle/1874/33059/34.pdf?sequence=1
Ligthart, J. G. M., Guo, D. A., Spek, A. L., Kooijman, H., Zuilhof, H., & Sijbesma, R. P. (2008). Ureidobenzotriazine multiple h-bonding arrays: the importance of geometrical details on the stability of h-bonds. Journal of Organic Chemistry, 73(1), 111-117.
https://dspace.library.uu.nl/bitstream/handle/1874/33068/23.pdf?sequence=1
Gosiewska, S., Herreras Martinez, S. D., Lutz, M., Spek, A. L., Havenith, R. W. A., van Klink, G. P. M., van Koten, G., & Klein Gebbink, R. J. M. (2008). Synthesis, structure, and catalytic performance of diastereopure five-coordinated NCN-pincer palladium(II) complexes bearing bulky amino acid substituents. Organometallics, 27(11), 2549-2559.
https://dspace.library.uu.nl/bitstream/handle/1874/33022/782.pdf?sequence=1
Lutz, M., Spek, A. L., van der Geer, E. P. L., van Koten, G., & Klein Gebbink, R. J. M. (2008). Indole-3-thiouronium iodide. Acta crystallographica. Section E, Structure reports, E64(1), o195.
https://dspace.library.uu.nl/bitstream/handle/1874/32996/763.pdf?sequence=1
Jansen, H., Rosenthal, A. J., Slootweg, J. C., Ehlers, A. W., Lutz, M., Spek, A. L., & Lammertsma, K. (2008). Diastereoselective formation of complexed methylenediphosphiranes. Organometallics, 27, 2868-2872.
https://dspace.library.uu.nl/bitstream/handle/1874/33073/18.pdf?sequence=1
de Greef, T. F. A., Ligthart, G. B. W. L., Lutz, M., Spek, A. L., & Meijer, E. W. (2008). The mechanism of ureido-pyrimidinone:2,7-diamido-naphthyridine complexation and the presence of kinetically controlled pathways in multicomponent hydrogen-bonded systems. Journal of the American Chemical Society, 130, 5479-5486.
https://dspace.library.uu.nl/bitstream/handle/1874/33079/14.pdf?sequence=1
Wolf, R., Ehlers, A. W., Slootweg, J. C., Lutz, M., Gudat, D., Hunger, M., Spek, A. L., & Lammertsma, K. (2008). The homoleptic sandwich anion [Co(P2C2tBu2)2]-: a versatile building block for phosphaorganometallic chemistry. Angewandte Chemie-International Edition, 47, 4584-4587.
https://dspace.library.uu.nl/bitstream/handle/1874/33036/39.pdf?sequence=1

2007

Scholarly publications

Bon, R. S., de Kanter, F. J. J., Lutz, M., Spek, A. L., Jahnke, M., Hahn, F. E., Groen, M. B., & Orru, R. V. A. (2007). Multicomponent Synthesis of N-Heterocyclic Carbene Complexes. Organometallics, 26, 3639-3650.
https://dspace.library.uu.nl/bitstream/handle/1874/26893/06.pdf?sequence=1
Suijkerbuijk, B. M. J. M., Tooke, D. M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2007). One-Dimensional, Cofacial Porphyrin Polymers Formed by Self-Assembly of meso-Tetrakis(ERE Donor) Zinc(II) Porphyrins. Chemistry - An Asian Journal, 2(7), 889-903.
https://dspace.library.uu.nl/bitstream/handle/1874/26805/754.pdf?sequence=1
Corral, E., Kooijman, H., Spek, A. L., & Reedijk, J. (2007). Nucleic acids in two dimensions: layers of base pairs linked by carboxylate. New journal of chemistry = Nouveau journal de chimie, 31, 21-24.
Hubregtse, T., Kooijman, H., Spek, A. L., Maschmeyer, T., Sheldon, R. A., Arends, I. W. C. E., & Hanefeld, U. (2007). Study on the isomerism in meso-amavadin and an amavadin analogue. Journal of Inorganic Biochemistry, 101, 900-908.
https://dspace.library.uu.nl/bitstream/handle/1874/26917/33.pdf?sequence=1
van Walree, C. A., van der Wiel, B. C., Jenneskens, L. W., Lutz, M., Spek, A. L., Havenith, R. W. A., & van Lenthe, J. H. (2007). On the structure of cross-conjugated 2,3-diphenylbutadiene. European Journal of Organic Chemistry, 2007(28), 4746-4751.
https://dspace.library.uu.nl/bitstream/handle/1874/26728/2_LWJ.pdf?sequence=1
Godbole, M. D., Prat Puig, M., Tanase, S., Kooijman, H., Spek, A. L., & Bouwman, E. (2007). Iron complexes of chiral phenol-oxazoline ligands: Structural studies and oxidation catalysis. Inorganica Chimica Acta, 360, 1954-1960.
https://dspace.library.uu.nl/bitstream/handle/1874/26915/30.pdf?sequence=1
Bruijnincx, P. C. A., Buurmans, I. L. C., Gosiewska, S., Moelands, M. A. H., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2007). Iron(II) Complexes with Bio-Inspired N,N,O Ligands as Oxidation Catalysts: Olefin Epoxidation and cis-Dihydroxylation. Chemistry-A European Journal, 14, 1228-1237.
https://dspace.library.uu.nl/bitstream/handle/1874/26894/07.pdf?sequence=1
Bruijnincx, P. C. A., Lutz, M., Spek, A. L., Hagen, W. R., Weckhuysen, B. M., van Koten, G., & Gebbink, R. J. M. K. (2007). Modeling the 2-his-1-carboxylate facial triad: Iron-catecholato complexes as structural and functional models of the extradiol cleaving dioxygenases. Journal of the American Chemical Society, 129(8), 2275-2286. https://doi.org/10.1021/ja064816x
van Steenis, D. J. V. C., Marcelli, T., Lutz, M., Spek, A. L., van Maarseveen, J. H., & Hiemstra, H. (2007). Construction of Adjacent Quaternary and Tertiary Stereocenters via an Organocatalytic Allylic Alkylation of Morita-Baylis-Hillman Carbonates. Advanced synthesis & catalysis, 349(3), 281-286.
https://dspace.library.uu.nl/bitstream/handle/1874/26964/44.pdf?sequence=1
von Chrzanowski, L. S., Lutz, M., & Spek, A. L. (2007). 1,1'-Bis(ferrocenylphenylphosphino)-ferrocene. Acta crystallographica. Section E, Structure reports, E63, m2098.
https://dspace.library.uu.nl/bitstream/handle/1874/26899/15.pdf?sequence=1
von Chrzanowski, L. S., Lutz, M., & Spek, A. L. (2007). α-Tris(2,4-pentanedionato-k2O,O')aluminium(III) at 240, 210, 180, 150 and 110 K: a new δ phase at 110 K. Acta Crystallographica. Section C, Crystal Structure Communications, C63, m129-m134.
https://dspace.library.uu.nl/bitstream/handle/1874/26897/12.pdf?sequence=1
Stol, M., Snelders, D. J. M., Kooijman, H., Spek, A. L., van Klink, G. P. M., & van Koten, G. (2007). A new, easily recyclable arylating agent based on a diphosphino-digold(I) complex. Dalton Transactions, 2007(24), 2589-2593.
Angamuthu, R., Kooijman, H., Lutz, M., Spek, A. L., & Bouwman, E. (2007). Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks. Journal of the Chemical Society. Dalton transactions : inorganic chemistry, 4641-4643.

2006

Scholarly publications

Gosiewska, S., Veld, M. H. I., de Pater, J. J. M., Bruijnincx, P. C. A., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2006). Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with l-proline chiral auxiliaries: mer η3-N,C,N versus square planar η4-N,C,N,O coordination. Tetrahedron Asymmetry, 17(4), 674-686. https://doi.org/10.1016/j.tetasy.2005.12.040
Köcher, S., Lutz, M., Spek, A. L., Prasad, R., van Klink, G. P. M., van Koten, G., & Lang, H. (2006). Heterobimetallic Fe–Pd and Fe–Pt NCN pincer complexes (NCN = [C6H2(CH2NMe2)2-2,6][1]). Inorganica Chimica Acta, 359, 4454-4462.
https://dspace.library.uu.nl/bitstream/handle/1874/21191/728.pdf?sequence=1
van Zutphen, S., Pantoja, E., Soriano, R., Soro, C., Tooke, D. M., Spek, A. L., den Dulk, H., Brouwer, J., & Reedijk, J. (2006). New antitumour active platinum compounds containing carboxylate ligands in trans geometry: synthesis, crystal structure and biological activity. Dalton Transactions, 1020-1023. https://doi.org/10.1039/b512357g
Aromí, G., Gamez, P., Boldron, C., Kooijman, H., Spek, A. L., & Reedijk, J. (2006). A Zig-Zag [MnII] Cluster from a Novel Bis(β-diketonate) Ligand. European Journal of Inorganic Chemistry, 2006(10), 1940-1944.
https://dspace.library.uu.nl/bitstream/handle/1874/20069/10.1002-ejic.200600105.pdf?sequence=1
Spek, A. L. (2006). Structure Validation. In P. Müller (Ed.), Crystal structure refinement : a crystallographer’s guide to SHELXL (pp. 159-165). (IUCr texts on crystallography; No. 8). Oxford University Press.
Kleijn, H., Kleij, A. W., de Pater, J. J. M., Lutz, M., Spek, A. L., Jastrzebski, J. T. B. H., Deelman, B. J., & van Koten, G. (2006). 2-(1-(Dimethylamino)ethyl)phenylpalladium(II) complexes 5-functionalized with fluorous silyl tails. Inorganica Chimica Acta, 359, 2674-2682.
https://dspace.library.uu.nl/bitstream/handle/1874/20011/720.pdf?sequence=1
van Buijtenen, J., Meuldijk, J., Vekemans, J. A. J. M., Hulshof, L. A., Kooijman, H., & Spek, A. L. (2006). Dinuclear Ruthenium Complexes Bearing Dicarboxylate and Phosphine Ligands. Acceptorless Catalytic Dehydrogenation of 1-Phenylethanol. Organometallics, 25, 873-881. https://doi.org/10.1021/om050789s
Quesada, M., de Hoog, P., Gamez, P., Roubeau, O., Aromí, G., Donnadieu, B., Massera, C., Lutz, M., Spek, A. L., & Reedijk, J. (2006). Coordination Dependence of Magnetic Properties within a Family of Related [FeII2] Complexes of a Triazine-Based Ligand. European Journal of Inorganic Chemistry, 2006(7), 1353-1361.
https://dspace.library.uu.nl/bitstream/handle/1874/20087/10.1002-ejic.200501022.pdf?sequence=1
Chuchuryukin, A. V., Chase, P. A., Mills, A. M., Lutz, M., Spek, A. L., van Klink, G. P. M., & van Koten, G. (2006). Hydroxy- and Mercaptopyridine Pincer Platinum and Palladium Complexes Generated by Silver-Free Halide Abstraction. Inorganic Chemistry, 45(5), 2045-2054. https://doi.org/10.1021/ic051773x
Kleij, A. W., Kuil, M., Lutz, M., Tooke, D. M., Spek, A. L., Kamer, P. C. J., van Leeuwen, P. W. N. M., & Reek, J. N. H. (2006). Supramolecular zinc(II)salphen motifs: Reversible dimerization and templated dimeric structures. Inorganica Chimica Acta, 359, 1807-1814. https://doi.org/10.1016/j.ica.2005.06.069

2005

Scholarly publications

Bruijnincx, PCA., Lutz, M., Spek, AL., van Faassen, EE., Weckhuysen, BM., van Koten, G., & Gebbink, RJMK. (2005). Bis(1-methylimidazol-2-yl)propionates and bis(1-methylbenzimidazol-2-yl)-propionates: A new family of biomimetic N,N,O Ligands - Synthesis, structures and Cu-II coordination complexes. European Journal of Inorganic Chemistry, (4), 779-787. https://doi.org/10.1002/ejic.200400830
Bruijnincx, P. C. A., Lutz, M. H., Spek, A. L., van Faassen, E. E. H., Weckhuysen, B. M., van Koten, G., & Klein Gebbink, R. J. M. (2005). Bis(1-methylimidazol-2-yl)propionates and Bis(1-methylbenzimidazol-2-yl)propionates: A New Family of Biomimetic N,N,O Ligands - Synthesis, Structures and CuII Coordination Complexes. European Journal of Inorganic Chemistry, 779-787.
https://dspace.library.uu.nl/bitstream/handle/1874/14698/ejic.200400830.pdf?sequence=1
Borst, M. L. G., van Riet, N., Lemmens, R. H., de Kanter, F. J. J., Schakel, M., Ehlers, A. W., Mills, A. M., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2005). Strained, Stable 2-Aza-1-Phosphabicyclo[n.1.0]alkane and -alkene Fe(CO)4 Complexes with Dynamic Phosphinidene Behavior. Chemistry-A European Journal, 11, 3631-3642.
https://dspace.library.uu.nl/bitstream/handle/1874/14697/chem.200401249.pdf?sequence=1
Marsman, A. W., van Poecke, B. L. A., Jenneskens, L. W., Spek, A. L., Lutz, E. T. G., & van der Maas, J. H. (2005). 4-(Tetrahydro-4H-thiopyran-1-oxide-4-ylidene)-cyclohexanone oxime in the solid-state. A two dimensional network of enantiomorphous chains interconnected by weak hydrogen bonds. Organic & Biomolecular Chemistry, 1402-1409.
https://dspace.library.uu.nl/bitstream/handle/1874/14836/b500527b.pdf?sequence=1
van Gorkum, R., Buda, F., Kooijman, H., Spek, A. L., Bouwman, E., & Reedijk, J. (2005). Trigonal-Prismatic vs. Octahedral Geometry for Mn(II) Complexes with Innocent Didentate Ligands: A Subtle Difference as Shown by XRD and DFT on [Mn(acac)2(bpy)]. European Journal of Organic Chemistry, 2255-2261.
https://dspace.library.uu.nl/bitstream/handle/1874/14709/ejic.200401005.pdf?sequence=1
Lutz, M., Spek, A. L., Kreiter, R., Klein Gebbink, R. J. M., & van Koten, G. (2005). trans-Dichlorobis(tris{4-[(dimethylamino)methyl]phenyl}phosphine)platinum(II). Acta crystallographica. Section E, Structure reports, E61(12), m2728-m2729.
https://dspace.library.uu.nl/bitstream/handle/1874/14830/bt6791.pdf?sequence=1
Slootweg, J. C., Krill, S., de Kanter, F. J. J., Schakel, M., Ehlers, A. W., Lutz, M., Spek, A. L., & Lammertsma, K. (2005). Valence Isomerization of 2-Phosphabicyclo-[1.1.0]butanes. Angewandte Chemie-International Edition, 44(40), 6579-6582. https://doi.org/10.1002/anie.200502248
Kooijman, H., Leemhuis, M., van Nostrum, C. F., Hennink, W. E., & Spek, A. L. (2005). (3S,6R)-3-Benzyloxymethyl-6-methyl-1,4-dioxane-2,5-dione. Acta crystallographica. Section E, Structure reports, 61, o898-o900. https://doi.org/10.1107/S1600536805006902
Amijs, C. H. M., Berger, A., Soulimani, F., Visser, T., van Klink, G. P. M., Lutz, M., Spek, A. L., & van Koten, G. (2005). Neutral Pyridyl-Functionalized C,N-ortho-Chelated Aminoaryl Platinum(II) Corner Building Blocks for Application in Coordination Reactions. Inorganic Chemistry, 44(19), 6567-6578.
https://dspace.library.uu.nl/bitstream/handle/1874/14820/ic050697v.pdf?sequence=1
Slootweg, J. C., van Zeist, W-J., de Kanter, F. J. J., Schakel, M., Ehlers, A. W., Lutz, M., Spek, A. L., & Lammertsma, K. (2005). Phosphaspiropentene as a Transient Intermediate. Organometallics, 24, 5172-5175.
https://dspace.library.uu.nl/bitstream/handle/1874/14859/om050530%2B.pdf?sequence=2
Boldron, C., Gamez, P., Tooke, D. M., Spek, A. L., & Reedijk, J. (2005). Copper-Mediated Selective Oxidation of a C-H Bond. Angewandte Chemie-International Edition, 44(23), 3585-3587. https://doi.org/10.1002/anie.200462946
Tanase, S., Aromi, G., Bouwman, E., Kooijman, H., Spek, A. L., & Reedijk, J. (2005). New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(mu4-O)4(phpz)8(thf)4]. Chemical Communications, 3147-3149.
https://dspace.library.uu.nl/bitstream/handle/1874/14727/b504215a.pdf?sequence=1
Freixa, Z., Kamer, P. C. J., Lutz, M. H., Spek, A. L., & van Leeuwen, P. W. N. M. (2005). Activity of SPANphos Rhodium Dimers in Methanol Carbonylation. Angewandte Chemie, 117(28), 4459-4462. https://doi.org/10.1002/ange.200500226
Tooke, D. M., Lutz, M. H., & Spek, A. L. (2005). A second polymorph of cyclo-tetrakis{mu2-[dimethylamino)methyl]phenyl-kappa3C2:C2,N}copper tetrahydrofuran solvate. Acta crystallographica. Section E, Structure reports, 61, m1245-m1247.
https://dspace.library.uu.nl/bitstream/handle/1874/14721/lh6430.pdf?sequence=1
Kooijman, H., Hogenbirk, M., Schat, G., Akkerman, O. S., Bickelhaupt, F., & Spek, A. L. (2005). (mu2-n2-2-tert-Butylethyn-1-yl)(mu2-chloro)bis{[bis-(n5-cyclopentadienyl)dimethylsilane]titanium}. Acta crystallographica. Section E, Structure reports, 61, m1329-m1331.
https://dspace.library.uu.nl/bitstream/handle/1874/8493/lh6444.pdf?sequence=2
Hotze, A. C. G., van der Geer, E. P. L., Kooijman, H., Spek, A. L., Haasnoot, J. G., & Reedijk, J. (2005). Characterization by NMR Spectroscopy, X-ray Analysis and Cytotoxic Activity of the Ruthenium(II) Compounds [RuL3](PF6)2 (L=2-Phenylazopyridine or o-Tolylazopyridine) and [RuL'2L''](PF6)2 (L', L''=2-Phenylazopyridine, 2,2'-Bipyridine). European Journal of Inorganic Chemistry, 2648-2657.
https://dspace.library.uu.nl/bitstream/handle/1874/14841/ejic.200500110.pdf?sequence=1
Spek, A. L., & de Jong, B. H. W. S. (2005). Potassium sodium phyllosilicate, K1.33Na0.67Si2O5. Acta crystallographica. Section E, Structure reports, E61, 1188-1190.
https://dspace.library.uu.nl/bitstream/handle/1874/7963/br6203.pdf?sequence=2
Tooke, D. M., & Spek, A. L. (2005). Fourier3D: visualization of electron density and solvent-accessible voids in small-molecule crystallography. Journal of Applied Crystallography, 38, 572-573.
https://dspace.library.uu.nl/bitstream/handle/1874/14722/os5024.pdf?sequence=2
Kannappan, R., Tooke, D. M., Spek, A. L., & Reedijk, J. (2005). An alternating chain of spider-like tris(peptides) stabilized by stacking and by N-H...N and N-H...O=C hydrogen bonding. Journal of Molecular Structure, 751, 55-59.
https://dspace.library.uu.nl/bitstream/handle/1874/14843/j.molstruc.2005.04.043.pdf?sequence=1
Borst, M. L. G., Bulo, R. E., Winkel, C. W., Gibney, D. J., Ehlers, A. W., Schakel, M., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2005). Phosphepines: Convenient Access to Phosphinidene Complexes. Journal of the American Chemical Society, 127, 5800-5801.
https://dspace.library.uu.nl/bitstream/handle/1874/14696/ja050817y.pdf?sequence=1
Vergeer, F. W., Lutz, M., Spek, A. L., Calhorda, M. J., Stufkens, D. J., & Hartl, F. (2005). Heterosite Effects in Novel Heteronuclear Clusters [Os2Ru(CO)11(PPh3)] and [Os2Ru(CO)10(2-acetylpyridine-N-isopropylimine)]. European Journal of Inorganic Chemistry, 2206-2222.
https://dspace.library.uu.nl/bitstream/handle/1874/14862/ejic.200401040.pdf?sequence=1
Kleij, A. W., Lutz, M., Spek, A. L., van Leeuwen, P. W. N. M., & Reek, J. N. H. (2005). Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis. Chemical Communications, 3661-3663.
https://dspace.library.uu.nl/bitstream/handle/1874/14847/b503708e.pdf?sequence=1
van der Drift, R. C., Gagliardo, M., Kooijman, H., Spek, A. L., Bouwman, E., & Drent, E. (2005). Scope, mechanism and diene inhibition of isomerization of allylic alcohols to saturated ketones catalyzed by ruthenium(II)-cyclopentadienyl complexes. Journal of Organometallic Chemistry, 690, 1044-1055.
https://dspace.library.uu.nl/bitstream/handle/1874/14702/j.jorganchem.2004.11.017.pdf?sequence=1
Spek, A. L., Tooke, D. M., Garza-Ortiz, A., & Reedijk, J. (2005). Non-merohedrally twinned mer-trichloro(dimethyl sulfoxide-kS)(1,10-phenanthroline) ruthenium(III) chloroform solvate, with Z'=6. Acta crystallographica. Section E, Structure reports, E61, m2428-m2430.
https://dspace.library.uu.nl/bitstream/handle/1874/14861/hb6296.pdf?sequence=1
Kooijman, H., Leemhuis, M., van Nostrum, C. F., Hennink, W. E., & Spek, A. L. (2005). (3S)-3-benzyloxymethyl-1,4-dioxane-2,5-dione. Acta crystallographica. Section E, Structure reports, 61, O3480-O3481. https://doi.org/10.1107/S1600536805030564

2004

Scholarly publications

Bulo, R. E., Jansen, H., Ehlers, A. W., De Kanter, F. J. J., Schakel, M., Lutz, M., Spek, A. L., & Lammertsma, K. (2004). The Circumambulation of a Phosphirane: Taking 9-Phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "Walk". Angewandte Chemie - International Edition, 43(6), 714-717. https://doi.org/10.1002/anie.200351855
Duran Pachon, L., Golobic, A., Kozlevcar, B., Gamez, P., Kooijman, H., Spek, A. L., & Reedijk, J. (2004). Intramolecular oxidation of the ligand 4-methyl-2-N-(2-pyridylmethyl)aminophenol (Hpyramol) upon coordination with iron(II) chloride and manganese(II) perchlorate. Inorganica Chimica Acta, 357, 3697-3702.
https://dspace.library.uu.nl/bitstream/handle/1874/14567/10.1016-j.ica.2004.04.019.pdf?sequence=1
Couzijn, E. P. A., Schakel, M., de Kanter, F. J. J., Ehlers, A. W., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2004). Dynamic Configurational Isomerism of a Stable Pentaorganosilicate. Angewandte Chemie-International Edition, 43, 3440-3442.
https://dspace.library.uu.nl/bitstream/handle/1874/14566/10.1002-anie.200353006.pdf?sequence=1
Tooke, D. M., Song, Y., van Albada, G. A., Reedijk, J., & Spek, A. L. (2004). 1,4-Bis(3,5-di-tert-butyl-2-hydroxybenzylideneaminomethyl)benzene. Acta crystallographica. Section E, Structure reports, E60, o1907-o1908.
https://dspace.library.uu.nl/bitstream/handle/1874/14593/10.1107-S1600536804023633.pdf?sequence=1
Hogenbirk, M., Schat, G., de Kanter, F. J. J., Akkerman, O. S., Bickelhaupt, F., Kooijman, H., & Spek, A. L. (2004). Investigations on the Reactivity of Bis(bromomagnesio)trimethylsilylmethane - Molecular Structure of a Tebbe-Type Spiro-Organomagnesium Compound. European Journal of Inorganic Chemistry, 2045-2052.
https://dspace.library.uu.nl/bitstream/handle/1874/14569/10.1002-ejic.200300836.pdf?sequence=1
Bulo, R. E., Trion, L., Ehlers, A. W., de Kanter, F. J. J., Schakel, M., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2004). C-C Bond Insertion of a complexed Phosphinidene into 1,6- Methanol[10]annulene. Chemistry-A European Journal, 10, 5332-5337.
https://dspace.library.uu.nl/bitstream/handle/1874/14565/10.1002-chem.200400519.pdf?sequence=1
Slootweg, J. C., Schakel, M., de Kanter, F. J. J., Ehlers, A. W., Kozhushkov, S. I., de Meijere, A., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2004). Branched Phospha[7]triangulanes. Journal of the American Chemical Society, 126, 3050-3051.
https://dspace.library.uu.nl/bitstream/handle/1874/14432/10.1021-ja031648p.pdf?sequence=1
Tooke, D. M., Mills, A. M., Spek, A. L., van der Vlugt, J. I., & Vogt, D. (2004). Bis[mu-3,3',5,5'-tetra-tert-butylbiphenyl-2,2'-diyl phosphonato(1-)]bis(acetonitrile)carbonylrhodium(I)] dichloromethane sesquisolvate. Acta crystallographica. Section E, Structure reports, E60, m943-m945.
https://dspace.library.uu.nl/bitstream/handle/1874/14592/10.1107-S1600536804013406.pdf?sequence=1
Aromi, G., Ribas, J., Gamez, P., Roubeau, O., Kooijman, H., Spek, A. L., Teat, S., MacLean, E., Stoeckli-Evans, H., & Reedijk, J. (2004). Aggregation of [Cu4 II] Building Blocks into [Cu8 II] Clusters or a [C4 II]infinite Chain through Subtle Chemical Control. Chemistry-A European Journal, 10, 6476-6488.
https://dspace.library.uu.nl/bitstream/handle/1874/14636/10.1002-chem.200400671.pdf?sequence=1
Tooke, D. M., & Spek, A. L. (2004). 3,5-Di-tert-butyl-2-hydroxybenzaldehyde. Acta crystallographica. Section E, Structure reports, E60, o766-o767.
https://dspace.library.uu.nl/bitstream/handle/1874/14594/10.1107-S160053680400830X.pdf?sequence=1
Kooijman, H., Keegstra, M. A., Brandsma, L., & Spek, A. L. (2004). Bis(benzyltrimethylammonium) tetrachloro-nickelate(II) N-methylpyrrolidin-2-one solvate. Acta crystallographica. Section E, Structure reports, E60, m1513-m1515.
https://dspace.library.uu.nl/bitstream/handle/1874/14577/10.1107-S1600536804023487.pdf?sequence=1
de Cires-Mejias, C., Tanase, S., Reedijk, J., Gonzales-Vilchez, F., Vilaplana, R., Mills, A. M., Kooijman, H., & Spek, A. L. (2004). Extended structures based on hydrogen bonding and π-π interactions: [synthesis and characterization of two zinc complexes: [Zn(dap)Cl2] and [Zn(dap)2Cl2]. Inorganica Chimica Acta, 357, 1494-1498.
https://dspace.library.uu.nl/bitstream/handle/1874/14434/10.1016-j.ica.2003.11.035.pdf?sequence=1
van Leeuwen, F. W. B., Beijleveld, H., Kooijman, H., Spek, A. L., Verboom, W., & Reinhoudt, D. N. (2004). Synthesis and Conformational Evaluation of p-tert-Butylthiacalix[4]arene-crowns. European Journal of Organic Chemistry, 69, 3928-3936.
https://dspace.library.uu.nl/bitstream/handle/1874/14582/10.1021-jo0401220.pdf?sequence=1
van der Vlugt, J. I., Hewat, A. C., Neto, S., Sablong, R., Mills, A. M., Lutz, M. H., Spek, A. L., Muller, C., & Vogt, D. (2004). Sterically Demanding Diphosphonite Ligands - Synthesis and Application in Nickel-Catalyzed Isomerization of 2-Methyl-3-Butenenitrile. Advanced synthesis & catalysis, 346, 993-1003.
https://dspace.library.uu.nl/bitstream/handle/1874/14599/10.1002-adsc.200303240.pdf?sequence=1
Koval, I. A., Gamez, P., Roubeau, O., Driessen, W. L., Lutz, M. H., Spek, A. L., & Reedijk, J. (2004). Additions and corrections to: Century-Known Copper Salt Cu(OAc)(OMe) proven To Be a Unique Magnetic Lattice Composed of Tetranuclear Copper(II) Species with a Rare Binding Mode of the Acetate Anion. Inorganic Chemistry, 43(1), 392-392.
https://dspace.library.uu.nl/bitstream/handle/1874/14445/10.1021-ic030315q.pdf?sequence=1
van der Vlugt, J. I., Paulusse, J. M. J., Zijp, E. J., Tijmensen, J. A., Mills, A. M., Spek, A. L., Claver, C., & Vogt, D. (2004). Coordination Chemistry and Asymmetric Catalysis with a Chiral Diphosphonite. European Journal of Inorganic Chemistry, 2004, 4193-4201.
https://dspace.library.uu.nl/bitstream/handle/1874/14600/10.1002-ejic.200400132.pdf?sequence=1
Arink, A. M., Kronenburg, C. M. P., Jastrzebski, J. T. B. H., Lutz, M., Spek, A. L., Gossage, R. A., & Van Koten, G. (2004). Diastereoselective self-assembly of chiral diamine-chelated aryllithiums to dimeric aggregates. Journal of the American Chemical Society, 126(49), 16249-16258. https://doi.org/10.1021/ja045914q
Sprengers, J. W., Agerbeek, M. J., Elsevier, C. J., Kooijman, H., & Spek, A. L. (2004). Synthesis and Crystal Structures of Zerovalent Platinum η2-Fumarate Bis(norbornene) Complexes and Their Application as Hydrosilylation Catalysts. Organometallics, 23, 3117-3125.
https://dspace.library.uu.nl/bitstream/handle/1874/14587/10.1021-om049913i.pdf?sequence=1
Hotze, A. C. G., van der Geer, E. P. L., Caspers, S. E., Kooijman, H., Spek, A. L., Haasnoot, J. G., & Reedijk, J. (2004). Coordination of 9-Ethylguanine to the Mixed-Ligand Compound α-[Ru(azpy)(bpy)Cl2] (azpy=2-Phenylazopyridine and bpy=2,2'-Bipyridine). An Unprecedented Ligand Positional Shift, Correlated to the Cytotoxicity of This Type of [RuL2Cl2] (with L=azpy or bpy) Complex. Inorganic Chemistry, 43, 4935-4943.
https://dspace.library.uu.nl/bitstream/handle/1874/14573/10.1021-ic035390f.pdf?sequence=1
Koval, I. A., Huisman, M., Stassen, A. F., Gamez, P., Lutz, M. H., Spek, A. L., Pursche, D., Krebs, B., & Reedijk, J. (2004). New dinuclear Co(II) and Mn(II) complexes of the phenol-based compartmental ligand containing formyl and amine functions: structural, spectroscopic and magnetic properties. Inorganica Chimica Acta, 357, 294-300. http://www.sciencedirect.com
Wu, J. Z., Bouwman, E., Mills, A. M., Spek, A. L., & Reedijk, J. (2004). Manganese(II) complexes of a set of 2-aminomethylpyridine-derived ligands bearing a methoxyalkyl arm: synthesis, structures and magnetism. Inorganica Chimica Acta, 357, 2694-2702.
https://dspace.library.uu.nl/bitstream/handle/1874/14601/10.1016-j.ica.2004.02.001.pdf?sequence=1
Hotze, A. C. G., Kooijman, H., Spek, A. L., Haasnoot, J. G., & Reedijk, J. (2004). Synthesis and characterization of ruthenium(II) complexes with the new ligand 2-phenylazopyridine-5-sulfonic acid (HSAZPY): in search for new anticancer agents. New journal of chemistry = Nouveau journal de chimie, 28, 565-569.
https://dspace.library.uu.nl/bitstream/handle/1874/14574/10.1039-b313746e.pdf?sequence=1
Kooijman, H., Hotze, A. C. G., Caspers, S. E., Haasnoot, J. G., Reedijk, J., & Spek, A. L. (2004). α-Dichlorobis(2-phenylazo-4,6-dimethyl-pyridine)ruthenium(II) chloroform solvate. Acta crystallographica. Section E, Structure reports, E60, m247-m249.
https://dspace.library.uu.nl/bitstream/handle/1874/14576/10.1107-S1600536804001618.pdf?sequence=1

2003

Scholarly publications

Stassen, A. F., Grunert, M., Mills, A. M., Spek, A. L., Haasnoot, J. G., Reedijk, J., & Linert, W. (2003). Linkage isomers of dibromobis(1-(2-methoxyethyl)tetrazole)-copper(II) containing either a bromide or a unique tetrazole bridge. Dalton Transactions, 3628-3633.
https://dspace.library.uu.nl/bitstream/handle/1874/14941/10.1039-b303422d.pdf?sequence=1
van der Vlugt, J. I., Bonet, J. M., Mills, A. M., Spek, A. L., & Vogt, D. (2003). Modular diphosphine ligands based on bisphenol A backbones. Tetrahedron Letters, 44, 4389-4392.
https://dspace.library.uu.nl/bitstream/handle/1874/14321/10.1016-S0040-4039%2803%2900948-1.pdf?sequence=1
Verhagen, J. A. W., Lutz, M., Spek, A. L., & Bouwman, E. (2003). Synthesis and Characterisation of New Nickel-Iron Complexes with an S4 Coordination Environment around the Nickel Centre. European Journal of Inorganic Chemistry, 3968-3974.
https://dspace.library.uu.nl/bitstream/handle/1874/14943/10.1002-ejic.200300285.pdf?sequence=1
Driessen, W. L., Chang, L., Finazzo, C., Gorter, S., Rehorst, D., Reedijk, J., Lutz, M. H., & Spek, A. L. (2003). Two pyrazolato-bridged, linear trinuclear Cu(II) complexes. Crystal structures and magnetic properties. Inorganica Chimica Acta, 350, 25-31.
https://dspace.library.uu.nl/bitstream/handle/1874/14297/10.1016-S0020-1693%2802%2901509-8.pdf?sequence=1
Termaten, A. T., Nijbacker, T., Schakel, M., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2003). Synthesis and reactions of terminal osmium and ruthenium complexed phosphinidenes [(eta6-Ar)(L)M=PMes*]. Chemistry-A European Journal, 9, 2200-2208.
https://dspace.library.uu.nl/bitstream/handle/1874/14320/10.1002-chem.200204582.pdf?sequence=1
Schuitema, A. M., Aubel, P. G., Koval, I. A., van Engelen, M., Driessen, W. L., Reedijk, J., Lutz, M., & Spek, A. L. (2003). Dinuclear copper(II) complexes of four new pyrazole-containing macrocyclic ligands are active catalysts in the oxidative coupling of 2,6-dimethylphenol. Inorganica Chimica Acta, 355, 374-385.
https://dspace.library.uu.nl/bitstream/handle/1874/14949/10.1016-S0020-1693%2803%2900362-1.pdf?sequence=1
van Belzen, R., Elsevier, C. J., Dedieu, A., Veldman, N., & Spek, A. L. (2003). Stereospecific Reaction of Molecular Halogens with Palladacyclopentadienes Containing Bidentate Nitrogen Ligands To Give 1,4-Dihalo-1,3-dienes via Palladium(IV) Intermediates. Organometallics, 22, 722-736.
https://dspace.library.uu.nl/bitstream/handle/1874/14293/10.1021-om020586t.pdf?sequence=1
Bianchini, C., Meli, A., Oberhauser, W., van Leeuwen, P. W. N. M., Zuideveld, M. A., Freixa, Z., Kamer, P. C. J., Spek, A. L., Gusev, O. V., & Kal'sin, A. M. (2003). Methoxycarbonylation of ethene by palladium(II) complexes with 1,1'-bis(diphenylphosphino)ferrocene (dppf) and 1,1'-bis(diphenylphosphino)octamethylferrocene (dppomf). Organometallics, 22, 2409-2421.
https://dspace.library.uu.nl/bitstream/handle/1874/14294/10.1021-om021049b.pdf?sequence=1
Dijkstra, H. P., Slagt, M. Q., McDonald, A. R., Kruithof, C. A., Kreiter, R., Mills, A. M., Lutz, M. H., Spek, A. L., Klopper, W. M., van Klink, G. P. M., & van Koten, G. (2003). Para-functionalized NCN-pincer palladium(ll) complexes: synthesis, catalysis, and DFT calculations. European Journal of Inorganic Chemistry, 2003, 830-838.
https://dspace.library.uu.nl/bitstream/handle/1874/14658/10.1002-ejic.200390113.pdf?sequence=1
Koval, I. A., Gamez, P., Roubeau, O., Driessen, W. L., Lutz, M. H., Spek, A. L., & Reedijk, J. (2003). Century-Known Copper Salt (Cu(OAc)(OMe) Proven To Be a Unique Magnetic Lattice Composed of Tetranuclear Copper(II) Species with a Rare Binding Mode of the Acetate Anion. Inorganic Chemistry, 42, 868-872.
https://dspace.library.uu.nl/bitstream/handle/1874/14307/10.1021-ic026034k.pdf?sequence=1
Kaats-Richters, V. E. M., Cleij, T. J., Jenneskens, L. W., Lutz, M. H., Spek, A. L., & van Walree, C. A. (2003). Synthesis and structure of cis-1,4-di(1-pyrenyl)decamethylcyclohexasilane. Organometallics, 22, 2249-2258.
https://dspace.library.uu.nl/bitstream/handle/1874/14303/10.1021-om020980r.pdf?sequence=1
Roelfes, G., Vrajmasu, V., Chen, K., Ho, R. Y. N., Rohde, J-U., Zondervan, C., la Crois, R. M., Schudde, E. P., Lutz, M. H., Spek, A. L., Hage, R., Feringa, B. L., Munck, E., & Que, L. (2003). End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry. Inorganic Chemistry, 42(8), 2639-2653.
https://dspace.library.uu.nl/bitstream/handle/1874/14313/10.1021-ic034065p.pdf?sequence=1
Chalbot, M-C., Mills, A. M., Spek, A. L., Long, G. J., & Bouwman, E. (2003). Structure and Electronic Properties of [Ni(dsdm){Fe(CO)3}2], un Unusual, Triangular Nickel Diiron Compound. European Journal of Inorganic Chemistry, 453-457.
https://dspace.library.uu.nl/bitstream/handle/1874/14296/10.1002-ejic.200390064.pdf?sequence=1
Termaten, A. T., Aktas, H., Schakel, M., Ehlers, A. W., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2003). Terminal Phosphinidene complexes CpR(L)M=PAr of the group 9 transition metals cobalt, rhodium, and iridium. Synthesis, structures, and properties. Organometallics, 22, 1827-1834.
https://dspace.library.uu.nl/bitstream/handle/1874/14319/10.1021-om0208624.pdf?sequence=1
Chuchuryukin, A. V., Dijkstra, H. P., Suijkerbuijk, B. M. J. M., Klein Gebbink, R. J. M., van Klink, G. P. M., Mills, A. M., Spek, A. L., & van Koten, G. (2003). Template-directed synthesis of macroheterocycles by ring-closing metathesis of olefin-substituted pyridines in the coordination sphere of triplatinum complex. Russian Journal of Organic Chemstry, 39, 422-429.
https://dspace.library.uu.nl/bitstream/handle/1874/6597/13084.pdf?sequence=2
Slagt, M. Q., Dijkstra, H. P., McDonald, A. R., Klein Gebbink, R. J. M., Lutz, M. H., Ellis, D. D., Mills, A. M., Spek, A. L., & van Koten, G. (2003). Self-Assembly of p-Nitro NCN-Pincer Palladium Complexes into Dimers through Electron Donor-Acceptor Interactions. Organometallics, 22, 27-29.
https://dspace.library.uu.nl/bitstream/handle/1874/14315/10.1021-om020743o.pdf?sequence=1
Kitbunnadaj, R., Zuiderveld, O. P., Esch, I. J. P. D., Vollinga, R. C., Bakker, R., Lutz, M. H., Spek, A. L., Cavoy, E., Deltent, M-F., Menge, W. M. P. B., Timmerman, H., & Leurs, R. (2003). Synthesis and Structure-Activity Relationships of Conformationally Constrained Histamine H3 Receptor Agonists. Journal of Medicinal Chemistry, 46, 5445-5457.
https://dspace.library.uu.nl/bitstream/handle/1874/14406/10.1021-jm030905y.pdf?sequence=1
van den Broeke, J., Stam, M., Lutz, M. H., Kooijman, H., Spek, A. L., Deelman, B. J., & van Koten, G. (2003). Designing ionic liquids: 1-butyl-3-methylimidazolium cations with substituted tetraphenylborate counterions. European Journal of Inorganic Chemistry, 2798-2811.
https://dspace.library.uu.nl/bitstream/handle/1874/14404/10.1002-ejic.200300057.pdf?sequence=1
de Hoog, P., Gamez, P., Roubeau, O., Lutz, M. H., Driessen, W. L., Spek, A. L., & Reedijk, J. (2003). Novel zigzag 1D coordination polymer from copper(II) chloride and N,N'-{2,4-di[(di-pyridin-2-yl)amine]-1,3,5-triazine}ethylenediamine exhibiting ferromagnetic interactions. New journal of chemistry = Nouveau journal de chimie, 27, 18-21.
https://dspace.library.uu.nl/bitstream/handle/1874/14301/10.1039-b206344a.pdf?sequence=1

2002

Scholarly publications

Kronenburg, C. M. P., Jastrzebski, J. T. B. H., Boersma, J., Lutz, M., Spek, A. L., & Van Koten, G. (2002). The first homologous series of self-assembled aryl bromo- and aryl cyanocuprates, -argentates, and -aurates; MLi2XAr2(M = CuI, AgI, AuI; X = Br, C≡N; Ar = [C6H4CH2N(Et)CH2CH2NEt2-2]-). Journal of the American Chemical Society, 124(39), 11675-11683. https://doi.org/10.1021/ja026945t
Vlaar, M. J. M., Lor, M. H., Ehlers, A. W., Schakel, M., Lutz, M., Spek, A. L., & Lammertsma, K. (2002). Synthesis, Structures, and Strain Energies of Dispirophosphiranes. Comparisons with Dispirocyclopropanes. Journal of Organometallic Chemistry, 67, 2485-2493.
https://dspace.library.uu.nl/bitstream/handle/1874/14936/10.1021-jo010945e.pdf?sequence=1
van der Drift, R. C., Bouwman, E., Drent, E., Kooijman, H., Spek, A. L., van Oort, A. B., & Mul, W. P. (2002). Structure, dynamic behavior, and catalytic activity of a novel ruthenium cyclopentadienyl complex with a tridentate P,P,O ligand. Organometallics, 21, 3401-3407.
https://dspace.library.uu.nl/bitstream/handle/1874/14330/10.1021-om020218p.pdf?sequence=1
Termaten, A. T., Nijbacker, T., Schakel, M., Lutz, M., Spek, A. L., & Lammertsma, K. (2002). Synthesis of Novel Terminal Iridium Phosphinidene Complexes. Organometallics, 21, 3196-3202.
https://dspace.library.uu.nl/bitstream/handle/1874/14930/10.1021-om020062t.pdf?sequence=1
Zuideveld, M. A., Swennenhuis, B. H. G., Boele, M. D. K., Guari, Y., van Strijdonck, G. P. F., Reek, J. N. H., Kamer, P. C. J., Goubitz, K., Fraanje, J., Lutz, M., Spek, A. L., & van Leeuwen, P. W. N. M. (2002). The coordination behaviour of large natural bite angle diphosphine ligands towards methyl and 4-cyanophenylpalladium(II) complexes. Journal of the Chemical Society. Dalton transactions : inorganic chemistry, 2308-2317.
https://dspace.library.uu.nl/bitstream/handle/1874/14933/10.1039-b111596k.pdf?sequence=1
Aromí, G., Gamez, P., Roubeau, O., Kooijman, H., Spek, A. L., Driessen, W. L., & Reedijk, J. (2002). Ligand-templated four-metal chains dimerize into a unique [CuII8] cluster. Angewandte Chemie-International Edition, 41, 1168-1170.
https://dspace.library.uu.nl/bitstream/handle/1874/14324/10.1002-1521-3773%2820020402%2941.pdf?sequence=1
Mimmi, M. C., Micciche, F., Kooijman, H., Spek, A. L., Warzeska, S. T., & Bouwman, E. (2002). Dinuclear iron complexes of the tridentate ligand N ,N-bis(2-ethyl-5-methyl-imidazol-4-ylmethyl)aminopropane (biap). Inorganica Chimica Acta, 340, 197-200.
https://dspace.library.uu.nl/bitstream/handle/1874/14921/10.1016-S0020-1693%2802%2901070-8.pdf?sequence=1
Suijkerbuijk, B. M. J. M., Slagt, M. Q., Klein Gebbink, R. J. M., Lutz, M., Spek, A. L., & van Koten, G. (2002). Platinum-pincer introduction using active ester chemistry. Tetrahedron Letters, 43, 6565-6568.
https://dspace.library.uu.nl/bitstream/handle/1874/14929/10.1016-S0040-4039%2802%2901468-5.pdf?sequence=1
Aromí, G., Gamez, P., Roubeau, O., Carrero-Berzal, P., Kooijman, H., Spek, A. L., Driessen, W. L., & Reedijk, J. (2002). The first case of local cis versus trans coordination as the controlling factor for the overall structure in dinuclear assemblies. European Journal of Inorganic Chemistry, 1046-1048.
https://dspace.library.uu.nl/bitstream/handle/1874/14276/Aromi_p1046-1048_02.pdf?sequence=1
Kronenburg, C. M. P., Amijs, C. H. M., Jastrzebski, J. T. B. H., Lutz, M., Spek, A. L., & van Koten, G. (2002). Induction of Chirotopicity in the Self-Assembly Process of Heterocuprates: Structual and Stereochemical Aspects of Neutral Culi2BrAryl2 Aggregates. Journal of the American Chemical Society, 21, 4662-4671.
https://dspace.library.uu.nl/bitstream/handle/1874/14913/10.1021-om0204540.pdf?sequence=1
Mills, A. M., Flinzner, K., Stassen, A. F., Haasnoot, J. G., & Spek, A. L. (2002). Tetrakis[1-(3-chloropropyl)-1,2,4-triazole-κN4]bis(tetrafluoroborato-κF)copper(II). Acta Crystallographica. Section C, Crystal Structure Communications, C58, m243-m245.
https://dspace.library.uu.nl/bitstream/handle/1874/14919/10.1107-S0108270102003086.pdf?sequence=1
Deerenberg, S., Schakel, M., de Keijzer, A. H. J. F., Kranenburg, M., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2002). Tetraalkylammonium pentaorganosilicates: the first highly stable silicates with five hydrocarbon ligands. Chemical Communications, 348-349.
https://dspace.library.uu.nl/bitstream/handle/1874/14327/10.1039-b109816k.pdf?sequence=1
van Albada, G. A., Mutikainen, I., Smeets, W. J. J., Spek, A. L., Turpeinen, U., & Reedijk, J. (2002). Synthesis, magnetism and X-ray structures of [Cu(2-aminopyrimidine)2(µ-OH)(CF3SO3)]2(2-aminopyrimidine)2, a new hydroxo-bridged dinuclear Cu(II) compound generating extremely small antiferromagnetism. Inorganica Chimica Acta, 327, 134-139.
https://dspace.library.uu.nl/bitstream/handle/1874/14274/10.1016-S0020-1693%2801%2900695-8.pdf?sequence=1
Rodriguez, G., Lutz, M., Spek, A. L., & van Koten, G. (2002). New Mono- and Tricyclopalladated Dentritic Systems with Encapsulated Catalytic Sites. Chemistry-A European Journal, 1(8), 45-57.
https://dspace.library.uu.nl/bitstream/handle/1874/14922/Rodriguez_p45-57_02.pdf?sequence=1
de Wolf, E., Spek, A. L., Kuipers, B. W. M., Philipse, A. P., Meeldijk, J. D., Bomans, P. H. H., Frederik, P. M., Deelman, B. J., & van Koten, G. (2002). Fluorous derivatives of [Rh(COD)(dppe)]BX4 (X=F, Ph): synthesis, physical studies and applications in catalytic hydrogenation of 1-alkenes and 4-alkenes. Tetrahedron Letters, 58, 3911-3922.
https://dspace.library.uu.nl/bitstream/handle/1874/14931/1407.pdf?sequence=1
Komeda, S., Lutz, M. H., Spek, A. L., Yamanaka, Y., Sato, T., Chikuma, M., & Reedijk, J. (2002). A Novel Isomerization on Interaction of Antitumor-Active Azole-Bridged Dinuclear Platinum(II) Complexes with 9-Ethylguanine. Platinum(II) Atom Migration from N2 to N3 on 1,2,3-Triazole. Journal of the American Chemical Society, 124, 4738-4746.
https://dspace.library.uu.nl/bitstream/handle/1874/14335/10.1021-ja0168559.pdf?sequence=1

2001

Scholarly publications

Driessen, WL., Baesjou, PJ., Bol, JE., Kooijman, H., Spek, AL., & Reedijk, J. (2001). A dinuclear copper(II) macrocyclic pyrazole compound catalyses the oxidative polymerisation of 2,6-dimethylphenol. Inorganica Chimica Acta, 324(1-2), 16-20.
Reedijk, J., Riggio, I., van Albada, G. A., Ellis, D. D., Mutikainen, I., Spek, A. L., & Turpeinen, U. (2001). X-ray crystal structures, spectroscopic and magnetic measurements of copper(II) and cobalt(II) halide compounds with bis(2-benzimidazolyl)alkane ligands. Polyhedron, 20, 2659-2666.
Oosterbaan, W. D., Havenith, R. W. A., van Walree, C. A., Jenneskens, L. W., Gleiter, R., Kooijman, H., & Spek, A. L. (2001). The occurrence of through-bond orbital interactions in an alfa, omega donor-acceptor substituted bi(cyclohexylidene) and bi(cyclohexyl). X-Ray diffraction, UV-Vis absorption and photoelectron spectroscopy, ab initio SCF-MO and natural bond orbital analyses. Journal of the Chemical Society, Perkin transactions, 2001(7), 1066-1074.
Bickelhaupt, F., Spek, A. L., van Es, D. S., van Eis, M. J., N'Krumah, S., Gret, N., Egberts, A., de Rijke, M., de Kanter, F. J. J., & de Wolf, W. H. (2001). 3-Aza(5)metacyclophanes:synthesis and reactions. Heterocycles, 54, 799-824.
Reedijk, J., Warzeska, S. T., Miccichè, M., Bouwman, E., Kooijman, H., & Spek, A. L. (2001). Tuning the coordination mode in mononuclear manganese complexes by changing the steric bulk of the carboxylates. Journal of the Chemical Society. Dalton transactions : inorganic chemistry, 3507-3512.
Reedijk, J., Riggio, I., van Albade, G. A., Ellis, D. D., & Spek, A. L. (2001). Synthesis, X-ray structure, spectroscopy and magnetism of polymeric bis(µ-dicyanamido)(µ-primidine)copper(II) monoacetonitrile; a 3D compound with dridging dicyanamide anions in two dimensions. Inorganica Chimica Acta, 313, 120-124.
Albrecht, M., Kocks, B. M., Spek, A. L., & van Koten, G. (2001). Chiral platinum and palladium complexes containing functionalized C2-symmetric bisaminoaryl 'pincer' ligands. Journal of Organometallic Chemistry, 624, 271-286.
Marsh, R. E., & Spek, A. L. (2001). Use of software to search for higher symmetry: space group C2. Acta Crystallographica, B57, 800-805.
Vlaar, M. J. M., Ehlers, A. W., Schakel, M., Clendenning, S. B., Nixon, J. F., Lutz, M. H., Spek, A. L., & Lammertsma, K. (2001). Die norbornadien-quadricyclan-valenzisomerisierung eines tetraphosphorderivats. Angewandte Chemie, 113(23), 4524-4527. https://doi.org/10.1002/1521-3757(20011203)113:23<4524::AID-ANGE4524>3.0.CO;2-G
van den Broeke, J., Lutz, M. H., Kooijman, H., Spek, A. L., Deelman, B. J., & van Koten, G. (2001). Increasing the lipophilic character of tetraphenylborate anions through silyl substituents. Organometallics, 20, 2114-2117.

2000

Scholarly publications

Richter, B., Spek, A. L., Van Koten, G., & Deelman, B-J. (2000). Fluorous versions of Wilkinson's catalyst. Activity in fluorous hydrogenation of 1-alkenes and recycling by fluorous biphasic separation. Journal of the American Chemical Society, 122(16), 3945-3951. https://doi.org/10.1021/ja993562v
Kleij, A. W., Gossage, R. A., Klein Gebbink, R. J. M., Brinkmann, N., Reijerse, E. J., Kragl, U., Lutz, M., Spek, A. L., & Van Koten, G. (2000). A "Dendritic Effect" in homogeneous catalysis with carbosilane-supported arylnickel(II) catalysts: Observation of active-site proximity effects in atom-transfer radical addition. Journal of the American Chemical Society, 122(49), 12112-12124. https://doi.org/10.1021/ja0026612
Baesjou, PJ., Driessen, WL., Reedijk, J., & Spek, AL. (2000). Structure of aqua-bis(ethylenediamine)copper(II) bis(2,6-dimethylphenolate). Inorganica Chimica Acta, 306(2), 237-240.
Kooijman, H., Spek, A. L., Kleijn, H., van Maanen, H. L., Jastrzebski, J. T., & van Koten, G. (2000). (3R,4S)-3-phenyl-1-[(R)-1-phenylethyl]-4-[(R)-1-phenylethyliminomethyl] azetidin-2-one. Acta Crystallographica. Section C, Crystal Structure Communications, 56, Pt 4/-.

1999

Scholarly publications

Kleij, A. W., Kleijn, H., Jastrzebski, J. T. B. H., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1999). Dendritic Carbosilanes Containing Silicon-Bonded 1-[C6H2(CH2NMe2) 2-3,5-Li-4] or 1-[C6H3(CH2NMe2)-4-Li-3] Mono- And Bis(amino)aryllithium End Groups: Structure of {[CH2SiMe2C6H3(CH 2NMe2)-4-Li-3]2}2. Organometallics, 18(2), 268-276.
Kleij, A. W., Kleijn, H., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1999). Carbosilane Molecules with Mono- And Bis(amino)arylmetal End Groups: Structures of {NiI[C6H2(CH2NMe2) 2-2,6-SiMe3-4]} and Tetranuclear {[CH2Si(Me)2C6H3(CH 2NMe2)-4-(PdCl)-3]2}2. Organometallics, 18(2), 277-285.
Hovestad, N. J., Hoare, J. L., Jastrzebski, J. T. B. H., Canty, A. J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1999). Periphery-palladated carbosilane dendrimers: Synthesis and reactivity of organopalladium(II) and -(IV) dendritic complexes. Crystal structure of [PdMe(C6H4(OCH2Ph)-4)(bpy)] (bpy = 2,2′-bipyridine). Organometallics, 18(16), 2970-2980.
Brandts, J. A. M., Kruiswijk, E., Boersma, J., Spek, A. L., & van Koten, G. (1999). C-H activation of a MeN grouping in one of the CH2NMe2 ortho substituents of a NCN 'pincer' ligand in tungsten chemistry: X-ray structure of [WCl2(NPh)(C6H3{CH2NMeCH2}-2-{CH2NMe2}-6)]. Journal of Organometallic Chemistry, 585, 93-99.
https://dspace.library.uu.nl/bitstream/handle/1874/14437/10.1016-S0022-328X%2899%2900199-0.pdf?sequence=1

1998

Scholarly publications

Donkervoort, J. G., L. Vicario, J., Jastrzebski, J. T. B. H., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1998). Synthesis of arylplatinum(II) complexes with chiral monoanionic aryldiamine ligands. The X-ray crystal structure of (-)-[(1R,1′R)-2,6-bis{1-(dimethylamino)propyl}phenyl]chloroplatinum(II). Journal of Organometallic Chemistry, 551(1-2), 1-7.
Donkervoort, J. G., Vicario, J. L., Rijnberg, E., Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & Van Koten, G. (1998). Formation of mixed aryl-, alkyl-lithium aggregates in the heteroatom assisted lithiation of α,α′-dialkyl substituted 1,3-bis[(dimethylamino)methyl]benzene. Journal of Organometallic Chemistry, 550(1-2), 463-467.
Kronenburg, C. M. P., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1998). A model structure for the resting state of cyanocuprate reagents R2Cu(CN)Li2. The X-ray crystal structure of [Ar2Cu(CN)Li2(THF)4](∞)1[5]. Journal of the American Chemical Society, 120(37), 9688-9689. https://doi.org/10.1021/ja9802448
Kleijn, H., Jastrzebski, J. T. B. H., Gossage, R. A., Kooijman, H., Spek, A. L., & Van Koten, G. (1998). Ortho-bis(amino)arylnickel(II) halide complexes containing perfluoroalkyl chains as model catalyst precursors for use in fluorous biphase systems. Tetrahedron, 54(7), 1145-1152. https://doi.org/10.1016/S0040-4020(97)10214-9

1997

Scholarly publications

Rijnberg, E., Boersma, J., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1997). The role of neutral and radical anionic organozinc complexes in the alkylation reactions of 1,4-diaza-1,3-butadienes with diorganozinc compounds. Organometallics, 16(14), 3158-3164.
Rijnberg, E., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Spek, A. L., & Van Koten, G. (1997). Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf) 6[Zn(CH2Ph)3]2. Journal of Organometallic Chemistry, 541(1-2), 181-185.
Donkervoort, J. G., Jastrzebski, J. T. B. H., Deelman, B. J., Kooijman, H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Novel aryltitanium(IV) complexes containing η 3-NCN- pseudofacial- and η 3-NCN-meridional-bonded [C 6H 3(CH 2NME 2) 2-2,6]-(abbreviated as NCN) ligands. Organometallics, 16(19), 4174-4184.
Donkervoort, J. G., Kronenburg, C. M. P., Deelman, B. J., Jastrzebski, J. T. B. H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Aryltitaniumf( IV) complexes with the η3-C,N,N′-pseudofacially coordinating ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]-. The X-ray crystal structure of [TiCl2( CNN)( O-i-Pr)]. Journal of Organometallic Chemistry, 547(2), 349-355.
Wijkens, P., Jastrzebski, J. T. B. H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Self-assembling of bis-ortho chelated diaminobenzyl- (NC′N) and butyl-lithium units to give 2: 2 mixed alkyllithium aggregates (NC′N)Li2Bu2Li2(NC′N) with a ladder structure. Chemical Communications, (22), 2143-2144.
Steenwinkel, P., Jastrzebski, J. T. B. H., Deelman, B. J., Grove, D. M., Kooijman, H., Veldman, N., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1997). Hypercoordinate aryltrialkylsilanes and -stannanes and their use in the synthesis of homodinuclear organometallic complexes with a 1,4-phenylene bridge. Organometallics, 16(25), 5486-5498.
Rietveld, M. H. P., Klumpers, E. G., Jastrzebski, J. T. B. H., Grove, D. M., Veldman, N., Spek, A. L., & Van Koten, G. (1997). Alkylidene-centered rearrangement of a tantalum alkylidene alkoxide species with the N,C,N-bis-ortho-chelated 1,2,6-trisubstituted aryldiamine ligand [C6H3(CH2NMe2)2-2,6] - to a product with a C,N-mono-ortho-chelated 1,2,4-Trisubstituted aryldiamine ligand. Organometallics, 16(20), 4260-4267.
Rijnberg, E., Hovestad, N. J., Kleij, A. W., Jastrzebski, J. T. B. H., Boersma, J., Janssen, M. D., Spek, A. L., & Van Koten, G. (1997). Application of S,N-chelating chiral zinc bis(aminoarenethiolates) as new precursor catalysts in the enantioselective addition of dialkylzincs to aldehydes. Organometallics, 16(13), 2847-2857.
Rijnberg, E., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Veldman, N., Spek, A. L., & Van Koten, G. (1997). 1: 1 and 2:1 lithium zincates with intramolecular coordination. structures of Li(thf)Zn(C6H4CH2NMe2-2)3 and Li2Zn(C6H4CH2NMe2-2) 4. Organometallics, 16(11), 2239-2245.
Kapteijn, GM., Baesjou, PJ., Alsters, PL., Grove, DM., Smeets, WJJ., Kooijman, H., Spek, AL., & vanKoten, G. (1997). Hydrogen bonding and conformational analysis of chelate-stabilized alkoxopalladium(II) complexes derived from amino alcohol ligands. Chemische berichte / Recueil, 130(1), 35-44.

1996

Scholarly publications

Van Walree, C. A., Roest, M. R., Schuddeboom, W., Jenneskens, L. W., Verhoeven, J. W., Warman, J. M., Kooijman, H., & Spek, A. L. (1996). Comparison between SiMe2 and CMe2 spacers as σ-bridges for photoinduced charge transfer. Journal of the American Chemical Society, 118(35), 8395-8407. https://doi.org/10.1021/ja960546e
Hogerheide, M. P., Ringelberg, S. N., Grove, D. M., Jastrzebski, J. T. B. H., Boersma, J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1996). A Proposal for Positive Cooperativity in Anion-Cation Binding in Yttrium and Lutetium Complexes Based on o-Amino-Substituted Phenolate Ligands. on the Way to Coordination Polymers by Self-Assembly. Molecular Structures of [ClLu(OAr)3Na] (X-ray) and [ClY(OAr')3Y(OAr')3Na] (X-ray and 89Y-NMR). Inorganic Chemistry, 35(5), 1185-1193.

1995

Scholarly publications

Hogerheide, M. P., Grove, D. M., Boersma, J., Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & van Koten, G. (1995). New Coordinatively Unsaturated Lutetium Mono‐ and Bis(alkyl) Complexes with a Bis(ortho)‐Chelating Aryldiamine Ligand—Crystal Structures of [LuCl2{2,6‐(Me2NCH2)2C6H3}(μ‐Cl)(μ‐Li(thf)2)]2 and [Lu(μ‐Cl){2,6‐(Me2NCH2)2C6H3}(CH2SiMe3)]2. Chemistry – A European Journal, 1(6), 343-350. https://doi.org/10.1002/chem.19950010604
Wijkens, P., Van Koten, E. M., Janssen, M. D., Jastrzebski, J. T. B. H., Spek, A. L., & Van Koten, G. (1995). The formation of a mixed organolithium aggregate Li4R2nBu2 during the heteroatom-assisted lithiation of 1,3-bis(dimethylaminomethyl)-2,4,6-trimethylbenzene (R = 2,6-(CH2NMe2)2-3,5-Me2C 6HCH2). Angewandte Chemie: International Edition, 34(2), 219-222.
Rijnberg, E., Boersma, J., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1995). Heteroleptic metallacyclic potassium organodiamido zincate complex. Synthesis and structure of polymeric {[K(thf)][MeZn(ButNCH=CHNBu t)]}n. Journal of the Chemical Society, Chemical Communications, (18), 1839-1840. https://doi.org/10.1039/C39950001839
Hogerheide, M. P., Wesseling, M., Jastrzebski, J. T. B. H., Boersma, J., Kooijman, H., Spek, A. L., & Van Koten, G. (1995). Versatility in phenolate bonding in organoaluminum complexes containing mono- and bis-ortho-chelating phenolate ligands. X-ray structures of Al{OC6H2(CH2NMe2) 2-2,6-Me-4}3, Al(Me)2{OC6H2(CH2NMe 2)2-2,6-Me-4}·N-AlMe ... Organometallics, 14(10), 4483-4492.

1994

Scholarly publications

van Nostrum, C. F., Benneker, F. B. G., Nolte, R. J. M., Veldman, N., Spek, A. L., & Schouten, AJ. J. (1994). Crystal Structure and Silver Ion Complexation of a Novel Porphyrazine Substituted with four Dithiacrown ether Rings. Recueil des Travaux Chimiques des Pays‐Bas, 113(2), 109-110. https://doi.org/10.1002/recl.19941130206
Hogerheide, M. P., Jastrzebski, J. T. B. H., Boersma, J., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1994). Cooperative binding of Na+ and Cl- in Na{M[OC6H2(CH2NMe2) 2-2,6-Me-4]3Cl}: Synthesis (M = Lu, Y) and X-ray structure (M = Lu) of new heterometallic complexes of lutetium and yttrium containing bis(o-amino)phenolate ligands. Inorganic Chemistry, 33(20), 4431-4432.
Van Maanen, H. L., Kleijn, H., Jastrzebski, J. T. B. H., Lakin, M. T., Spek, A. L., & Van Koten, G. (1994). Dualistic reactivity of lithium and zinc dienolates with imines: Effects of counterion, temperature, and substituents on α- and γ-coupling. Journal of Organic Chemistry, 59(25), 7839-7848.
Van Maanen, H. L., Jastrzebski, J. T. B. H., Kooijman, H., Spek, A. L., & Van Koten, G. (1994). Highly functionalized β-enamino esters via C-C coupling reactions of lithium enolates of protected glycine esters and isothiocyanates. Tetrahedron, 50(39), 11509-11526. https://doi.org/10.1016/S0040-4020(01)89288-7

1993

Scholarly publications

Van Der Schaaf, P. A., Jastrzebski, J. T. B. H., Hogerheide, M. P., Smeets, W. J. J., Spek, A. L., Boersma, J., & Van Koten, G. (1993). Mono- and bis-ortho-chelated lithium and sodium phenolates. Molecular structures of the first lithium phenolate with a stable, trinuclear structure and of a tetranuclear sodium analog, [MOC6H2(CH2NMe2) 2-2,6-Me-4]x (M = Li, x = 3; M = Na, x = 4). Inorganic Chemistry, 32(19), 4111-4118.
Van Maanen, H. L., Jastrzebski, J. T. B. H., Verweij, J., Kieboom, A. P. G., Spek, A. L., & Van Koten, G. (1993). (R)-2-Phenylglycine as a chiral auxiliary in the asymmetric synthesis of 2-azetidinones. Tetrahedron-Asymmetry, 4(7), 1441-1444. https://doi.org/10.1016/S0957-4166(00)80336-5

1992

Scholarly publications

Abbenhuis, H. C. L., Faiken, N., Grove, D. M., Jastrzebski, J. T. B. H., Kooijman, H., Van Der Sluis, P., Smeets, W. J. J., Spek, A. L., & Van Koten, G. (1992). Use of an aryldiamine pincer ligand in the study of tantalum alkylidene-centered reactivity: Tantalum-mediated alkene synthesis via reductive rearrangements and wittig-type reactions. Journal of the American Chemical Society, 114(25), 9773-9781.

1990

Scholarly publications

Jastrzebski, J. T. B. H., Sypkens, H. A. J., des Tombe, F. J. A., van der Schaaf, P. A., Boersma, J., van Koten, G., Spek, A. L., & Duisenberg, A. J. M. (1990). Crystal structure of zinc[bis[3-(dimethylamino)propyl-C,N]tin]bis(dibenzoylmethanato)-(SnZn). The first example of a dialkyltin(II) compound stabilized by SnZn coordination. Journal of Organometallic Chemistry, 396(1), 25-31. https://doi.org/10.1016/0022-328X(90)85189-6

1988

Scholarly publications

Jastrzebski, J. T. B. H., Boersma, J., van Koten, G., Smeets, W. J. J., & Spek, A. L. (1988). X-ray crystal structure of the ethylzinc enolate of 1-(2,4-cyclopentadienyl)-2-(diethylamino)-1-ethanone, the unexpected reaction product from cyclopentadienyl(ethyl)zinc and ethyl N, N-diethylglycinate. Recueil des Travaux Chimiques des Pays-Bas, 107(3), 263-266.

1987

Scholarly publications

Van Vliet, M. R. P., Van Koten, G., Buysingh, P., Jastrzebski, J. T. B. H., & Spek, A. L. (1987). Reactivity of 1-Aza-4-oxa-1,3-butadienes (α -imino ketones) toward diorganozinc reagents: Regio- and chemoselective transfer of organo groups in the ZnR2/R1N=C(R2)C(R3)=O system and x-ray structure of the organozinc enolate [EtZn(Et)(t-Bu)NC(H)=C(Me)O]2. Organometallics, 6(3), 537-546.
Spek, A. L., Jastrzebski, J. T. B. H., & Van Koten, G. (1987). Structure of μ‐[1,2‐bis(tert‐butylamino‐1: 2κN)‐1,2‐di(2‐pyridyl‐κN)ethane]‐bis(ethylzinc). Acta Crystallographica. Section C, Crystal Structure Communications, 43(10), 2006-2007. https://doi.org/10.1107/S0108270187089261

1986

Scholarly publications

Jastrzebski, J. T. B. H., Van Koten, G., Knaap, C. T., Schreurs, A. M. M., Kroon, J., & Spek, A. L. (1986). Organotin(IV) compounds derived from 2-Me2NC6H4CH2Li and its chiral α-Me3Si derivative. X-ray structure of pentacoordinate [{2-(dimethylamino)phenyl}(trimethylsilyl)methyl-C,N]methylphenyltin bromide having a chiral Sn center. Organometallics, 5(8), 1551-1558.

1983

Scholarly publications

Van Vliet, M. R. P., Jastrzebski, J. T. B. H., Van Koten, G., Vrieze, K., & Spek, A. L. (1983). Novel reactions of substituted 1-aza-4-oxobutadienes (α-iminoketones) with diorganozinc reagents. Selective ethyl transfer in the Et2Zn/t-BuNC(H)C(Me)O system and x-ray crystal structure of [EtZn(Et)(T-Bu)NC(H)C(Me)O]2. Journal of Organometallic Chemistry, 251(1). https://doi.org/10.1016/0022-328X(83)80256-3

1980

Scholarly publications

Van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Verhoeckx, G. J., Spek, A. L., & Kroon, J. (1980). Crystal and molecular structure of SnMePh[C10H5(OMe-5)(CH2NMe2-8)]Br and proton nuclear magnetic resonance study of the puckering of the chelate ring in five-co-ordinate triorganotin halides ... Journal of the Chemical Society, Dalton Transactions, (8), 1352-1358. https://doi.org/10.1039/DT9800001352

1978

Scholarly publications

van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Spek, A. L., & Schoone, J. C. (1978). Triorganotin cations stabilized by intramolecular SnN coordination; synthesis and characterization of {C,N,N′-2,6-bis[(dimethylamino)methyl]phenyl}diorganotin bromides {A figure is presented}. Journal of Organometallic Chemistry, 148(3), 233-245. https://doi.org/10.1016/S0022-328X(00)90980-X
Van Koten, G., Jastrzebski, J. T. B. H., Noltes, J. G., Pontenagel, W. M. G. F., Kroon, J., & Spek, A. L. (1978). Synthesis of C,Sn-chiral triorganotin halides via C-chiral arylcopper and arylgoldlithium intermediates. Crystal and molecular structure of one {2-[1-(S)-(dimethylamino)ethyl]phenyl}methylphenyltin bromide diastereomer. Journal of the American Chemical Society, 100(16), 5021-5028.

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