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Prof. dr. R.J.M. (Bert) Klein Gebbink

Vicedecaan 
Bètawetenschappen
Bètawetenschappen
Hoogleraar 
Bètawetenschappen
Scheikunde
Institute for Sust and Cir Chemistry
Organic Chemistry and Catalysis
Organic Chemistry and Catalysis
David de Wiedgebouw
Universiteitsweg 99
Kamer 5.80
3584 CG Utrecht

Prof. dr. R.J.M. (Bert) Klein Gebbink

Vicedecaan
Bètawetenschappen
Hoogleraar
Organic Chemistry and Catalysis
030 253 1889
r.j.m.kleingebbink@uu.nl
Profiel Publicaties Onderwijs Nevenwerkzaamheden Contact
Profiel Publicaties Onderwijs Nevenwerkzaamheden Contact
Expertises
Onderzoeksthema's

Publicaties

2023

Wetenschappelijke publicaties

Zaree, P., Tomris, I., de Vos, S. D., van der Woude, R., Flesch, F. M., Klein Gebbink, R. J. M., de Vries, R. P., & Pieters, R. J. (2023). Facile electrochemical affinity measurements of small and large molecules. RSC Advances, 13(14), 9756-9760. https://doi.org/10.1039/d3ra01029e

2022

Wetenschappelijke publicaties

Van beek, C. B., Killian, L., Lutz, M., Weingarth, M., Asundi, A. S., Sarangi, R., Klein gebbink, R. J. M., & Broere, D. L. J. (2022). E‐selective Semi‐hydrogenation of Alkynes under Mild Conditions by a Diruthenium Hydride Complex. Chemistry – A European Journal, 28(69), [e202202527]. https://doi.org/10.1002/chem.202202527
Monkcom, E. C., Negenman, H. A., Masferrer‐rius, E., Lutz, M., Ye, S., Bill, E., & Klein Gebbink, R. J. M. (2022). 2H1C Mimicry: Bioinspired Iron and Zinc Complexes Supported by N,N,O Phenolate Ligands. European Journal of Inorganic Chemistry, 2022(9), 1-14. [e202101046]. https://doi.org/10.1002/ejic.202101046
Van Beek, C. B., Van Leest, N. P., Lutz, M., De Vos, S. D., Klein Gebbink, R. J. M., De Bruin, B., & Broere, D. L. J. (2022). Combining metal–metal cooperativity: metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes. Chemical Science, 13(7), 2094-2104. https://doi.org/10.1039/d1sc05473b

2021

Wetenschappelijke publicaties

Masferrer‐Rius, E., Borrell, M., Lutz, M., Costas, M., & Klein Gebbink, R. J. M. (2021). Front Cover Picture: Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes (15/2021). Advanced synthesis & catalysis, 363(15), 3615-3615. https://doi.org/10.1002/adsc.202100744
Masferrer-rius, E., Li, F., Lutz, M., & Klein Gebbink, R. J. M. (2021). Exploration of highly electron-rich manganese complexes in enantioselective oxidation catalysis; a focus on enantioselective benzylic oxidation. Catalysis Science & Technology, 11(23), 7751-7763. https://doi.org/10.1039/d1cy01642c
Masferrer‐rius, E., Borrell, M., Lutz, M., Costas, M., & Klein Gebbink, R. J. M. (2021). Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes. Advanced synthesis & catalysis, 363(15), 3783-3795. https://doi.org/10.1002/adsc.202001590
Monkcom, E. C., de Bruin, D., de Vries, A. J., Lutz, M., Ye, S., & Klein Gebbink, R. J. (2021). Structurally Modelling the 2‐His‐1‐Carboxylate Facial Triad with a Bulky N,N,O Phenolate Ligand. Chemistry-A European Journal, 27(16), 5191-5204. https://doi.org/10.1002/chem.202004633

2020

Wetenschappelijke publicaties

Ghosh, P., Vos, S., Lutz, M., Gloaguen, F., Schollhammer, P., Moret, ME., & Klein Gebbink, R. J. M. (2020). Cover Feature: Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H 2 Formation (Chem. Eur. J. 55/2020). Chemistry-A European Journal, 26(55), 12490-12490. https://doi.org/10.1002/chem.202003332
Cianfanelli, M., Olivo, G., Milan, M., Klein Gebbink, R. J. M., Ribas, X., Bietti, M., & Costas, M. (2020). Enantioselective C-H Lactonization of Unactivated Methylenes Directed by Carboxylic Acids. Journal of the American Chemical Society, 142(3), 1584-1593. https://doi.org/10.1021/jacs.9b12239
Hessels, J., Masferrer-Rius, E., Yu, F., Detz, R. J., Klein Gebbink, R. J. M., & Reek, J. N. H. (2020). Nickel is a Different Pickle: Trends in Water Oxidation Catalysis for Molecular Nickel Complexes. ChemSusChem, 13(24), 6629-6634. https://doi.org/10.1002/cssc.202002164
Li, J., Lutz, M., & Klein Gebbink, R. J. M. (2020). A Cp‐based Molybdenum Catalyst for the Deoxydehydration of Biomass‐derived Diols. ChemCatChem, 12(24), 6356-6365. https://doi.org/10.1002/cctc.202001115
Ghosh, P., Vos, S., Lutz, M., Gloaguen, F., Schollhammer, P., Moret, M., & Klein Gebbink, R. J. M. (2020). Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H2 Formation. Chemistry-A European Journal, 26(55), 12560-12569. https://doi.org/10.1002/chem.201905746
LI, J., Lutz, M. H., & Klein Gebbink, R. J. M. (2020). N-Donor Ligand Supported “ReO2+”: A Pre-Catalyst for the Deoxydehydration of Diols and Polyols. Catalysts, 10(7), [754]. https://doi.org/10.3390/catal10070754
Masferrer-rius, E., Hopman, R. M., Van Der Kleij, J., Lutz, M., & Klein Gebbink, R. J. M. (2020). On the Ability of Nickel Complexes Derived from Tripodal Aminopyridine Ligands to Catalyze Arene Hydroxylations. Chimia, 74(6), 489-494. https://doi.org/10.2533/chimia.2020.489
Monkcom, E. C., Ghosh, P., Folkertsma, E., Negenman, H. A., Lutz, M., & Klein Gebbink, R. J. M. (2020). Bioinspired Non-Heme Iron Complexes: the Evolution of Facial N, N, O Ligand Design. Chimia, 74(6), 450-466. https://doi.org/10.2533/chimia.2020.450
Li, J., Lutz, M., & Klein Gebbink, R. J. M. (2020). N,N,O-Coordinated tricarbonylrhenium precatalysts for the aerobic deoxydehydration of diols and polyols. Catalysis Science & Technology, 10(11), 3782-3788. https://doi.org/10.1039/D0CY00618A

2019

Wetenschappelijke publicaties

Chen, J., De Liedekerke Beaufort, M., Gyurik, L., Dorresteijn, J., Otte, M., & Klein Gebbink, R. J. M. (2019). Highly efficient epoxidation of vegetable oils catalyzed by a manganese complex with hydrogen peroxide and acetic acid. Green Chemistry, 21(9), 2436-2447. https://doi.org/10.1039/c8gc03857k
Chen, J., & Klein Gebbink, R. J. M. (2019). Deuterated N2Py2 Ligands: Building More Robust Non-Heme Iron Oxidation Catalysts. ACS Catalysis, 9(4), 3564-3575. https://doi.org/10.1021/acscatal.8b04463
Riemersma, C. F., Monkcom, E. C., Klein Gebbink, R. J. M., & Lutz, M. (2019). Crystal structure of tetra­kis­(tetra­hydro­furan-κO)bis­(tri­fluoro­methane­sulfonato-κO)iron(II). Acta Crystallographica Section E Crystallographic Communications, 75(10), 1548-1551. https://doi.org/10.1107/S2056989019013094
Klein Gebbink, R. J. M., & Moret, M-E. (Eds.) (2019). Non-noble metal catalysis: molecular approaches and reactions. Wiley. https://doi.org/10.1002/9783527699087

2018

Wetenschappelijke publicaties

Basauri-molina, M., & Gebbink, R. J. M. K. (2018). Artificial Metalloenzymes for Hydrogenation and Transfer Hydrogenation Reactions. In Artificial Metalloenzymes and MetalloDNAzymes in Catalysis: From Design to Applications (pp. 171-197). Wiley - VCH Verlag GmbH & CO. KGaA. https://doi.org/10.1002/9783527804085.ch6
Ayad, M., Klein Gebbink, R. J. M., Le Mest, Y., Schollhammer, P., Le Poul, N., Pétillon, F. Y., & Mandon, D. (2018). Mononuclear iron(ii) complexes containing a tripodal and macrocyclic nitrogen ligand: synthesis, reactivity and application in cyclohexane oxidation catalysis. Dalton Transactions, 47(43), 15596-15612. https://doi.org/10.1039/C8DT02952K
Li, J., Lutz, M., Otte, M., & Klein Gebbink, R. J. M. (2018). A Cptt‐Based Trioxo‐Rhenium Catalyst for the Deoxydehydration of Diols and Polyols. ChemCatChem, 10(20), 4755-4760. https://doi.org/10.1002/cctc.201801151
Folkertsma, E., Benthem, S. H., Jastrzebski, J. T. B. H., Lutz, M., Moret, M., & Klein Gebbink, R. J. M. (2018). 1,2-Addition of Diethylzinc to a Bis(Imidazolyl)ketone Ligand. European Journal of Inorganic Chemistry, 2018(10), 1167-1175. https://doi.org/10.1002/ejic.201701363
Verhoeven, D. G. A., Van Wiggen, M. A. C., Kwakernaak, J., Lutz, M., Klein Gebbink, R. J. M., & Moret, M. (2018). Periodic Trends in the Binding of a Phosphine-Tethered Ketone Ligand to Fe, Co, Ni, and Cu. Chemistry - A European Journal, 24(20), 5163-5172. https://doi.org/10.1002/chem.201703254

2017

Wetenschappelijke publicaties

Jacobse, P. H., Moret, M. E., Klein Gebbink, R. J. M., & Swart, I. (2017). Tracking On-Surface Chemistry with Atomic Precision. Synlett, 28(19), 2509-2516. https://doi.org/10.1055/s-0036-1590867
Schulz, F., Jacobse, P. H., Canova, F. F., Van Der Lit, J., Gao, D. Z., Van Den Hoogenband, A., Han, P., Klein Gebbink, R. J. M., Moret, M. E., Joensuu, P. M., Swart, I., & Liljeroth, P. (2017). Precursor Geometry Determines the Growth Mechanism in Graphene Nanoribbons. Journal of Physical Chemistry C, 121(5), 2896-2904. https://doi.org/10.1021/acs.jpcc.6b12428
Chen, J., Lutz, M., Milan, M., Costas, M., Otte, M., & Klein Gebbink, B. (2017). Non-Heme Iron Catalysts with a Rigid Bis-Isoindoline Backbone and Their Use in Selective Aliphatic C−H Oxidation. Advanced Synthesis and Catalysis, 359(15), 2590-2595. https://doi.org/10.1002/adsc.201700239
Ghosh, P., Naastepad, R., Riemersma, C. F., Lutz, M., Moret, M., & Klein Gebbink, R. J. (2017). Noninnocent β-Diiminate Ligands: Redox Activity of a Bis(alkylimidazole)methane Ligand in Cobalt and Zinc Complexes. Chemistry - A European Journal, 23(45), 10732-10737. https://doi.org/10.1002/chem.201701215
van Ravensteijn, B. G. P., Schild, D. J., Kegel, W. K., & Klein Gebbink, R. J. M. (2017). The Immobilization of a Transfer Hydrogenation Catalyst on Colloidal Particles. ChemCatChem, 9(3), 440-450. https://doi.org/10.1002/cctc.201601096
Folkertsma, E., Benthem, S. H., Witteman, L., Van Slagmaat, C. A. M. R., Lutz, M., Klein Gebbink, R. J. M., & Moret, M. (2017). Formation of Exceptionally Weak C–C Bonds by Metal-Templated Pinacol Coupling. Dalton Transactions, 46(19), 6177-6182. https://doi.org/10.1039/C7DT01130J
Folkertsma, E., Van Der Lit, J., Di Cicco, F., Lutz, M., Klein Gebbink, R. J. M., Swart, I., & Moret, M. (2017). Combination of Scanning Probe Microscopy and Coordination Chemistry: Structural and Electronic Study of Bis(methylbenzimidazolyl)ketone and Its Iron Complex. ACS Omega, 2(4), 1372-1379. https://doi.org/10.1021/acsomega.6b00510
Otte, M., Lutz, M., & Klein Gebbink, R. J. M. (2017). Selective Synthesis of Hetero-Sequenced Aza-Cyclophanes. European Journal of Organic Chemistry, 2017(12), 1657-1661. https://doi.org/10.1002/ejoc.201700106
Raju, S., Van Slagmaat, C. A. M. R., Lutz, M., Kleijn, H., Jastrzebski, J. T. B. H., Moret, M., & Klein Gebbink, R. J. (2017). Synthesis of Cyclopentadienyl-based Tricarbonyl Rhenium Complexes and some Unusual Reactivities of Cp-substituents. European Journal of Inorganic Chemistry, 2017(3), 741-751. https://doi.org/10.1002/ejic.201601220

2016

Wetenschappelijke publicaties

Jacobse, P. H., van den Hoogenband, A., Moret, M. E., Klein Gebbink, R. J. M., & Swart, I. (2016). Aryl Radical Geometry Determines Nanographene Formation on Au(111). Angewandte Chemie - International Edition, 55(42), 13052-13055. https://doi.org/10.1002/anie.201606440
Weckhuysen, B. M., Bruijnincx, P. C. A., Lamers, M. F. A., & Klein Gebbink, R. J. M. (2016). The Seventeenth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis Utrecht July 12–15 2015. Topics in Catalysis, 59(19-20), 1669-1670. https://doi.org/10.1007/s11244-016-0692-x
De Lima Oliveira, R., Nijholt, T., Shakeri, M., De Jongh, P. E., Klein Gebbink, B., & De Jong, K. P. (2016). Encapsulation of chiral Fe(salen) in mesoporous silica structures for use as catalysts to produce optically active sulfoxides. Catalysis Science and Technology, 6, 5124-5133. https://doi.org/10.1039/c6cy00113k
Bramwell, P. L., Gao, J., de Waal, B., de Jong, K. P., Klein Gebbink, R. J. M., & de Jongh, P. E. (2016). A transition-metal-free hydrogenation catalyst: Pore-confined sodium alanate for the hydrogenation of alkynes and alkenes. Journal of Catalysis, 344, 129-135. https://doi.org/10.1016/j.jcat.2016.09.024
Font, D., Canta, M., Milan, M., Cussó, O., Ribas, X., Klein Gebbink, R. J. M., & Costas, M. (2016). Readily Accessible Bulky Iron Catalysts exhibiting Site Selectivity in the Oxidation of Steroidal Substrates. Angewandte Chemie-International Edition, 55(19), 5776-5779. https://doi.org/10.1002/anie.201600785
Cussó, O., Cianfanelli, M., Ribas, X., Klein Gebbink, R. J. M., & Costas, M. (2016). Iron Catalyzed Highly Enantioselective Epoxidation of Cyclic Aliphatic Enones with Aqueous H2O2. Journal of the American Chemical Society, 138(8), 2732–2738. https://doi.org/10.1021/jacs.5b12681
Tiddens, M. R., Klein Gebbink, R. J. M., & Otte, M. (2016). The B(C6F5)3-Catalyzed Tandem Meinwald Rearrangement-Reductive Amination. Organic Letters, 18(15), 3714-3717. https://doi.org/10.1021/acs.orglett.6b01744
Raju, S., Van Slagmaat, C. A. M. R., Li, J., Lutz, M., Jastrzebski, J. T. B. H., Moret, M., & Klein Gebbink, R. J. M. (2016). Synthesis of Cyclopentadienyl-Based Trioxo-rhenium Complexes and Their Use as Deoxydehydration Catalysts. Organometallics, 35(13), 2178-2187. https://doi.org/10.1021/acs.organomet.6b00120
van der Lit, J., Marsman, J. L., Koster, R. S., Jacobse, P., den Hartog, S., Vanmaekelbergh, D., Klein Gebbink, B., Filion, L., & Swart, I. (2016). Modeling the Self-Assembly of Organic Molecules in 2D Molecular Layers with Different Structures. Journal of Physical Chemistry C, 120(1), 318-323. [120]. https://doi.org/10.1021/acs.jpcc.5b09889
Witteman, L., Evers, T., Shu, Z., Lutz, M., Klein Gebbink, B., & Moret, M. (2016). Hydrosilylation in Aryliminopyrrolide-Substituted Silanes. Chemistry - A European Journal, 22(17), 6087-6099. https://doi.org/10.1002/chem.201505033
Folkertsma, E., De Waard, E. F., Korpershoek, G., Van Schaik, A. J., Solozabal Mirón, N., Borrmann, M., Nijsse, S., Moelands, M., Lutz, M., Otte, M., Moret, M., & Klein Gebbink, R. J. M. (2016). Mimicry of the 2-His-1-Carboxylate Facial Triad Using Bulky N,N,O-Ligands: Non-Heme Iron Complexes Featuring a Single Facial Ligand and Easily Exchangeable Co-Ligands. European Journal of Inorganic Chemistry, 2016(9), 1319-1332. https://doi.org/10.1002/ejic.201501406

2015

Wetenschappelijke publicaties

Vliegenthart, A. B., Welling, F. A. L., Roemelt, M., Klein Gebbink, R. J. M., & Otte, M. (2015). Synthesis and Characterization of a Brønsted Pair Functionalized Shape-Persistent Macrocycle. Organic Letters, 17(17), 4172-4175. https://doi.org/10.1021/acs.orglett.5b01931
De Lima Oliveira, R., He, W., Klein Gebbink, R. J. M., & De Jong, K. P. (2015). Palladium nanoparticles confined in thiol-functionalized ordered mesoporous silica for more stable Heck and Suzuki catalysts. Catalysis Science & Technology, 5(3), 1919-1928. https://doi.org/10.1039/c4cy01517g
Spannring, P., Yazerski, V. A., Chen, J., Otte, M., Weckhuysen, B. M., Bruijnincx, P. C. A., & Klein Gebbink, R. J. M. (2015). Regioselective Cleavage of Electron-Rich Double Bonds in Dienes to Carbonyl Compounds with [Fe(OTf)2(mix-BPBP)] and a Combination of H2O2 and NaIO4. European Journal of Inorganic Chemistry, 2015(21), 3462-3466. https://doi.org/10.1002/ejic.201500213
Basauri-Molina, M., Riemersma, C. F., Würdemann, M. A., Kleijn, H., & Klein Gebbink, R. J. M. (2015). Lipase active site covalent anchoring of Rh(NHC) catalysts: Towards chemoselective artificial metalloenzymes. Chemical Communications, 51(31), 6792-6795. https://doi.org/10.1039/c4cc09700a
Warsink, S., Derrah, E. J., Boon, C. A., Cabon, Y., De Pater, J. J. M., Lutz, M., Klein Gebbink, B., & Deelman, B. J. (2015). Intramolecularly stabilised group 10 metal stannyl and stannylene complexes: Multi-pathway synthesis and observation of platinum-to-tin alkyl transfer. Chemistry - A European Journal, 21(4), 1765-1779. https://doi.org/10.1002/chem.201404071
Saes, B. W. H., Verhoeven, D. G. A., Lutz, M., Klein Gebbink, R. J. M., & Moret, M. E. (2015). Coordination of a Diphosphine-Ketone Ligand to Ni(0), Ni(I), and Ni(II): Reduction-Induced Coordination. Organometallics, 34(12), 2710-2713. https://doi.org/10.1021/acs.organomet.5b00264
Raju, S., Jastrzebski, J. T. B. H., Lutz, M., Witteman, L., Dethlefsen, J. R., Fristrup, P., Moret, M. E., & Klein Gebbink, B. (2015). Spectroscopic Characterization of a Monomeric, Cyclopentadienyl-Based Rhenium(V) Dioxo Complex. Inorganic Chemistry, 54(22), 11031-11036. https://doi.org/10.1021/acs.inorgchem.5b02366
Basauri-Molina, M., Verhoeven, D. G. A., Van Schaik, A. J., Kleijn, H., & Klein Gebbink, R. J. M. (2015). Ring-Closing and Cross-Metathesis with Artificial Metalloenzymes Created by Covalent Active Site-Directed Hybridization of a Lipase. Chemistry - A European Journal, 21(44), 15676-15685. https://doi.org/10.1002/chem.201502381
Raju, S., Moret, M., & Klein Gebbink, B. (2015). Rhenium-Catalyzed Dehydration and Deoxydehydration of Alcohols and Polyols: Opportunities for the Formation of Olefins from Biomass. ACS Catalysis, 5(1), 281-300. https://doi.org/10.1021/cs501511x

2014

Wetenschappelijke publicaties

Iman, M., Davood, A., Gebbink, B. K., Azerang, P., Alibolandi, M., & Sardari, S. (2014). Design and Antimicrobial Evaluation of 1-Methylimidazole Derivatives as New Antifungal and Antibacterial Agents. Pharmaceutical Chemistry Journal, 48(8), 513-519. https://doi.org/10.1007/s11094-014-1140-5
Spannring, P., Bruijnincx, P. C. A., Weckhuysen, B. M., & Klein Gebbink, B. (2014). Transition metal-catalyzed oxidative double bond cleavage of simple and bio-derived alkenes and unsaturated fatty acids. Catalysis Science & Technology, 4(8), 2182-2209. https://doi.org/10.1039/c3cy01095c
Korstanje, T. J., Lutz, M., Jastrzebski, J. T. B. H., & Klein Gebbink, B. (2014). Synthesis and Characterization of Rhenium(V) Oxo Complexes Bearing PNP-Pincer Ligands. Organometallics, 33(9), 2201-2209. https://doi.org/10.1021/om401228u
De Lima Oliveira, R., Hooijmans, J. B. F., de Jongh, P. E., Klein Gebbink, B., & de Jong, K. P. (2014). Stabilization of Palladium Catalysts for the Heck Reaction by Support Functionalization and Solvent Selection. ChemCatChem, 6(11), 3223-3230. https://doi.org/10.1002/cctc.201402523
Shakeri, M., Roiban, L., Yazerski, V., Prieto Gonzalez, G., Klein Gebbink, B., de Jongh, P. E., & de Jong, K. P. (2014). Engineering and Sizing Nanoreactors To Confine Metal Complexes for Enhanced Catalytic Performance. ACS Catalysis, 4(10), 3791-3796. https://doi.org/10.1021/cs500777q
Derrah, E. J., Warsink, S., de Pater, J. J. M., Cabon, Y., Reboule, I., Lutz, M., Klein Gebbink, B., & Deelman, B-J. (2014). Correction to Oxidative Addition of Sn-C Bonds on Palladium(0): Identification of Palladium-Stannyl Species and a Facile Synthetic Route to Diphosphinostannylene-Palladium Complexes (vol 29, pg 5904, 2010). Organometallics, 33(11), 2914-2918. https://doi.org/10.1021/om500005y
Lutz, M., Huang, Y., Moret, M. E., & Klein Gebbink, B. (2014). Phase transitions and twinned low-temperature structures of tetraethylammonium tetrachloridoferrate(III). Acta crystallographica. Section C, Structural chemistry, 70(5), 470-476. https://doi.org/10.1107/S2053229614007955
Yazerski, V. A., Spannring, P., Gatineau, D., Woerde, C. H. M., Wieclawska, S. M., Lutz, M., Kleijn, H., & Klein Gebbink, B. (2014). Making Fe(BPBP)-catalyzed C-H and CC oxidations more affordable. Organic & Biomolecular Chemistry, 12(13), 2062-2070. https://doi.org/10.1039/c3ob42249f
Spannring, P., Prat, I., Costas, M., Lutz, M., Bruijnincx, P. C. A., Weckhuysen, B. M., & Klein Gebbink, B. (2014). Fe(6-Me-PyTACN)-catalyzed, one-pot oxidative cleavage of methyl oleate and oleic acid into carboxylic acids with H2O2 and NaIO4. Catalysis Science & Technology, 4(3), 708-716. https://doi.org/10.1039/c3cy00851g
Pijnenburg, N. J. M., Tomás-Mendivil, E., Mayland, K. E., Kleijn, H., Lutz, M., Spek, A. L., Van Koten, G., & Klein Gebbink, B. (2014). Monomeric and dendritic second generation Grubbs- and Hoveyda-Grubbs-type catalysts for olefin metathesis Metallodendrimers Special Issue. Inorganica Chimica Acta, 409(PART A), 163-173. https://doi.org/10.1016/j.ica.2013.06.018
Huang, Y., Moret, M-E., & Klein Gebbink, B. (2014). Iron-Mediated Direct Arylation of Unactivated Arenes in Air. European Journal of Organic Chemistry, 2014(18), 3788-3793. https://doi.org/10.1002/ejoc.201301620
Moelands, M. A. H., Schamhart, D. J., Folkertsma, E., Lutz, M., Spek, A. L., & Klein Gebbink, B. (2014). Facial triad modelling using ferrous pyridinyl prolinate complexes: synthesis and catalytic applications. Dalton Transactions, 43(18), 6769-6785. https://doi.org/10.1039/c3dt53266f

2013

Wetenschappelijke publicaties

Moelands, M. A. H., Nijsse, S., Folkertsma, E., de Bruin, B., Lutz, M., Spek, A. L., & Klein Gebbink, R. J. M. (2013). Bioinspired Nonheme Iron Complexes Derived from an Extended Series of N,N,O-Ligated BAIP Ligands. Inorganic Chemistry, 52(13), 7394-7410. https://doi.org/10.1021/ic400096e
Spannring, P., Yazerski, V., Bruijnincx, P. C. A., Weckhuysen, B. M., & Klein Gebbink, R. J. M. (2013). Fe-Catalyzed One-Pot Oxidative Cleavage of Unsaturated Fatty Acids into Aldehydes with Hydrogen Peroxide and Sodium Periodate. Chemistry-A European Journal, 19(44), 15012-15018. https://doi.org/10.1002/chem.201301371
Shakeri, M., Klein Gebbink, R. J. M., de Jongh, P. E., & de Jong, K. P. (2013). Tailoring the Windows Sizes to Control the Local Concentration and Activity of salen(Co) Catalysts in Plugged Nanochannels of SBA-15. Angewandte Chemie-International Edition, 52(41), 10854-10857. https://doi.org/10.1002/anie.201304640
Hausoul, P. J. C., Tefera, S. D., Blekxtoon, J., Bruijnincx, P. C. A., Klein Gebbink, R. J. M., & Weckhuysen, B. M. (2013). Pd/TOMPP-catalysed telomerisation of 1,3-butadiene with lignin-type phenols and thermal Claisen rearrangement of linear telomers. Catalysis Science & Technology, 3(5), 1215-1223. https://doi.org/10.1039/C2CY20522J
Korstanje, T. J., Folkertsma, E., Lutz, M., Jastrzebski, J. T. B. H., & Klein Gebbink, R. J. M. (2013). Synthesis, Characterization, and Catalytic Behavior of Dioxomolybdenum Complexes Bearing AcAc-Type Ligands. European Journal of Inorganic Chemistry, 2013(12), 2195-2204. https://doi.org/10.1002/ejic.201201350
Pijnenburg, N. J. M., Cabon, Y. H. M., van Koten, G., & Klein Gebbink, R. J. M. (2013). Mechanistic Studies on the SCS-Pincer Palladium(II)-Catalyzed Tandem Stannylation/Electrophilic Allylic Substitution of Allyl Chlorides with Hexamethylditin and Benzaldehydes. Chemistry-A European Journal, 19(15), 4858-4868. https://doi.org/10.1002/chem.201203049
Hausoul, P. J. C., Eggenhuisen, T. M., Nand, D., Baldus, M., Weckhuysen, B. M., Klein Gebbink, R. J. M., & Bruijnincx, P. C. A. (2013). Development of a 4,4’-biphenyl/phosphine-based COF for the heterogeneous Pd-catalysed telomerisation of 1,3-butadiene. Catalysis Science & Technology, 3(10), 2571-2579. https://doi.org/10.1039/c3cy00188a
Yazerski, V., Orue, A., Evers, T., Kleijn, H., & Klein Gebbink, R. J. M. (2013). Molecularly enlarged S,S-BnTsDPEN ligands for iron-catalyzed asymmetric olefin epoxidation reactions using hydrogen peroxide. Catalysis Science & Technology, 3(10), 2810-2818. https://doi.org/10.1039/C3CY00484H
Molenbroek, E., Straathof, N., Dück, S., Rashid, Z., van Lenthe, J. H., Lutz, M., Gandubert, A., Klein Gebbink, R. J. M., De Cola, L., & Bonnet, S. (2013). Zinc coordination to the bapbpy ligand in homogeneous solutions and at liposomes: zinc detection via fluorescence enhancement. Dalton Transactions, 42, 2973-2984. https://doi.org/10.1039/c2dt32488a
Huang, Y., Moret, M., Klein Gebbink, R. J. M., & Lutz, M. (2013). Crystallographic Space Group Choice and Its Chemical Consequences: Revised Crystal Structure of [Fe(phen)2Cl2]NO3. European Journal of Inorganic Chemistry, 2013(13), 2467-2469. https://doi.org/10.1002/ejic.201201452
Raju, S., Jastrzebski, J. T. B. H., Lutz, M., & Klein Gebbink, R. J. M. (2013). Catalytic Deoxydehydration of Diols to Olefins by using a Bulky Cyclopentadiene-based Trioxorhenium Catalyst. Chemistry & sustainability, energy & materials, 6(9), 1673-1680. https://doi.org/10.1002/cssc.201300364
Korstanje, T. J., Kleijn, H., Jastrzebski, J. T. B. H., & Klein Gebbink, R. J. M. (2013). Biopropionic acid production via molybdenumcatalyzed deoxygenation of lactic acid. Green Chemistry, 15(4), 982-988. https://doi.org/10.1039/C3GC36874B
Hausoul, P. J. C., Lutz, M., Jastrzebski, J. T. B. H., Bruijnincx, P. C. A., Weckhuysen, B. M., & Klein Gebbink, R. J. M. (2013). Mechanistic Study of the Pd/TOMPP-Catalyzed Telomerization of 1,3-Butadiene: Influence of Aromatic Solvents on Bis-Phosphine Complex Formation and Regioselectivity. Organometallics, 32(18), 5047-5057. https://doi.org/10.1021/om400246a
Shakeri, M., Klein Gebbink, R. J. M., de Jongh, P. E., & de Jong, K. P. (2013). Control and assessment of plugging of mesopores in SBA-15 materials. Microporous and Mesoporous Materials, 170, 340-345. https://doi.org/10.1016/j.micromeso.2012.12.018

2012

Wetenschappelijke publicaties

Bruijnincx, P. C. A., Jastrzebski, R., Hausoul, P. J. C., Klein Gebbink, R. J. M., & Weckhuysen, B. M. (2012). Pd-Catalyzed Telomerization of 1,3-Dienes with Multifunctional Renewable Substrates: Versatile Routes for the Valorization of Biomass-Derived Platform Molecules. In MAR. Meier, BM. Weckhuysen, & PCA. Bruijnincx (Eds.), Organometallics And Renewables (pp. 45-101). (Topics in Organometallic Chemistry; Vol. 39). Springer Nature. https://doi.org/10.1007/978-3-642-28288-1_2
Korstanje, T. J., & Klein Gebbink, R. J. M. (2012). Catalytic Oxidation and Deoxygenation of Renewables with Rhenium Complexes. Topics in Organometallic Chemistry, 39, 129-174. https://doi.org/10.1007/978-3-642-28288-1_4
Hausoul, P. J. C., Bruijnincx, P. C. A., Weckhuysen, B. M., & Klein Gebbink, R. J. M. (2012). Pd/TOMPP-catalyzed telomerization of 1,3-butadiene: From biomass-based substrates to new mechanistic insights. Pure and Applied Chemistry, 84(8), 1713-1727. https://doi.org/10.1351/PAC-CON-11-12-06
Korstanje, T. J., de Waard, E. F., Jastrzebski, J. T. B. H., & Klein Gebbink, R. J. M. (2012). Rhenium-Catalyzed Dehydration of Nonbenzylic and Terpene Alcohols to Olefins. ACS Catalysis, 2012(2), 2173-2181. https://doi.org/10.1021/cs300455w
Virboul, M. A. N., & Klein Gebbink, R. J. M. (2012). Incorporation of an n-Butylsulfonate Functionality To Induce Aqueous Solubility on Ruthenium(II) η6-Arene Complexes. Organometallics, 31, 85-91. https://doi.org/10.1021/om2005595

2011

Wetenschappelijke publicaties

Parvulescu, A. N., Hausoul, P. J. C., Bruijnincx, P. C. A., Korhonen, S. T., Teodorescu, C. M., Klein Gebbink, R. J. M., & Weckhuysen, B. M. (2011). Telomerization of 1,3-butadiene with biomass-derived alcohols over a heterogeneous Pd/TPPTS catalyst based on layered double hydroxides. ACS Catalysis, 1(5), 526-536. https://doi.org/10.1021/cs1001477
Wieczorek, B., Träff, A., Krumlinde, P., Dijkstra, H. P., Egmond, M. R., van Koten, G., Bäckvall, J-E., & Klein Gebbink, R. J. M. (2011). Covalent anchoring of a racemization catalyst to CALB-beads: towards dual immobilization of DKR catalysts. Tetrahedron Letters, 52(14), 1601-1604. https://doi.org/10.1016/j.tetlet.2011.01.106
Snelders, D. J. M., Siegler, M. A. M., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2011). Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines. Dalton Transactions, 40(11), 2588-2600. https://doi.org/10.1039/C0DT01105C
Yazerski, V., & Klein Gebbink, R. J. M. (2011). Heterogenization of Homogeneous Catalysts on Dendrimers. In P. Barbaro, & F. Liguori (Eds.), Heterogenized homogeneous catalysts for fine chemicals production : materials and processes (pp. 171-201). (Catalysis by metal complexes; No. 33). Springer. https://doi.org/10.1007/978-90-481-3696-4_5
https://dspace.library.uu.nl/bitstream/handle/1874/202660/fulltext.pdf?sequence=1
Bruijnincx, P. C. A., Buurmans, I. L. C., Huang, Y., Juhász, G., Viciano-Chumillas, M., Quesada, M., Lutz, M., Spek, A. L., Münck, E., Bominaar, E. L., & Klein Gebbink, R. J. M. (2011). Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): Structure, magnetic properties and catalytic oxidation studies. Inorganic Chemistry, 50(19), 9243-9255. https://doi.org/10.1021/ic200332y
van Koten, G., & Klein Gebbink, R. J. M. (2011). The monoanionic pincer–metal platform: a scaffold for meeting challenges in catalysis and materials research. Dalton Transactions, 40(35), 8731-8732. https://doi.org/10.1039/C1DT90120F
Cabon, Y. H. M., Klein Gebbink, R. J. M., & Deelman, B. J. (2011). Palladium-catalyzed dehydrostannylation of n-alkyltin trichlorides. Dalton Transactions, 40(34), 8651-8655. https://doi.org/10.1039/C1DT10330J
Pijnenburg, N. J. M., Dijkstra, H. P., van Koten, G., & Klein Gebbink, R. J. M. (2011). SCS-pincer palladium-catalyzed auto-tandem catalysis using dendritic catalysts in semi-permeable compartments. Dalton Transactions, 40(35), 8896-8905. https://doi.org/10.1039/C1DT10502G
Snelders, D. J. M., van Koten, G., & Klein Gebbink, R. J. M. (2011). Steric, electronic, and secondary effects on the coordination chemistry of ionic phosphine ligands and the catalytic behavior of their metal complexes. Chemistry-A European Journal, 17(1), 42-57. https://doi.org/10.1002/chem.201002508
Bonnet, S. A., van Lenthe, J. H., van Dam, H. J. J., van Koten, G., & Klein Gebbink, R. J. M. (2011). SO2-binding properties of cationic η6,η1-NCN-pincer arene ruthenium platinum complexes: spectroscopic and theoretical studies. Dalton Transactions, 40(11), 2542-2548. https://doi.org/10.1039/c0dt01437k

2010

Wetenschappelijke publicaties

Korstanje, T. J., Jastrzebski, J. T. B. H., & Klein Gebbink, B. (2010). Catalytic dehydration of benzylic alcohols to styrenes by rhenium complexes. Chemistry & sustainability, energy & materials, 3(6), 695-697. https://doi.org/10.1002/cssc.201000055
Li, J., Lutz, M., Spek, A. L., van Klink, G. P. M., van Koten, G., & Klein Gebbink, R. J. M. (2010). Chiral amino alcohol derived bis-phosphoramidite pincer palladium complexes and their applications in asymmetric allylation of aldimines. Organometallics, 29(6), 1379-1387. https://doi.org/10.1021/om100021p
Wieczorek, B., Lemcke, B., Dijkstra, H. P., Egmond, M. R., Klein Gebbink, R. J. M., & van Koten, G. (2010). Site-selective ser-hydrolase labelling with a luminescent organometallic NCN-platinum complex. European Journal of Inorganic Chemistry, 13, 1929-1938. https://doi.org/10.1002/ejic.200900980
Li, J., Siegler, M., Lutz, M., Spek, A. L., Klein Gebbink, R. J. M., & van Koten, G. (2010). PCN- and PCS-pincer palladium complexes as tandem catalysts in homoallylation reactions. Advanced synthesis & catalysis, 352(14-15), 2474-2488. https://doi.org/10.1002/adsc.201000204
Bonnet, S., Siegler, M. A., van Lenthe, J. H., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2010). Ruthenium-to-platinum interactions in η6,η1 NCN-pincer arene heterobimetallic complexes: An experimental and theoretical study. European Journal of Inorganic Chemistry, 2010(29), 4667-4677. https://doi.org/10.1002/ejic.201000448
Suijkerbuijk, B. M. J. M., Tooke, D. M., Lutz, M., Spek, A. L., Jenneskens, L. W., van Koten, G., & Klein Gebbink, R. J. M. (2010). Synthesis of and evidence for electronic communication within heteromultimetallic Tetrakis(NCN-pincer metal) - (Metallo)porphyrin Hybrids. Journal of Organic Chemistry, 75(5), 1534-1549. https://doi.org/10.1021/jo902402g
Bonnet, S., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2010). Bimetallic η6,η1-and PCP-pincer ruthenium palladium complexes: synthesis, structure, and catalytic activity. Organometallics, 29(5), 1157-1167. https://doi.org/10.1021/om900984t
Cabon, Y., Reboule, I. D., Lutz, M., Klein Gebbink, R. J. M., & Deelman, B. J. (2010). Oxidative addition of Sn-C bonds on palladium(0): identification of palladium-stannyl species and a facile synthetic route to diphosphinostannylene- palladium complexes. Organometallics, 29(22), 5904-5911. https://doi.org/10.1021/om1007067
https://dspace.library.uu.nl/bitstream/handle/1874/202495/Oxidative-addition-pall.pdf?sequence=1
Siegler, M. A., Bonnet, S., Schreurs, A. M. M., Klein Gebbink, R. J. M., Koten, G. V., & Spek, A. L. (2010). On the two closely related phases of [Ru(C5Me 5(η6-1,3-(Me2NCH2) 2C6H4)](BF4) and the reversible solid-solid order-disorder phase transition. Journal of Chemical Crystallography, 40(9), 753-760. https://doi.org/10.1007/s10870-010-9732-8
https://dspace.library.uu.nl/bitstream/handle/1874/202519/On-the-Two-Closely_2010_Journal.pdf?sequence=1
Suijkerbuijk, B. M. J. M., Schamhart, D. J., Kooijman, H., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2010). Mono(NCN-pincer palladium)-metalloporphyrin catalysts: evidence for supramolecular bimetallic catalysis. Dalton Transactions, 39(27), 6198-6216. https://doi.org/10.1039/b925236n

2009

Wetenschappelijke publicaties

Wander, M., Hausoul, P. J. C., Sliedregt, L. A. J. M., van Steen, B. J., van Koten, G., & Klein Gebbink, R. J. M. (2009). Synthesis of polyaryl rigid-core carbosilane dendrimers for supported organic synthesis. Organometallics, 28, 4406-4415. http://www.acs.org/
Li, J., Siegler, M. A. M., Luz, V. B., Spek, A. L., Klein Gebbink, R. J. M., & van Koten, G. (2009). Chiral ortho-Palladated and -Platinated Arylphosphite Complexes. Organometallics, 28(18), 5323-5332. http://www.acs.org
O'Leary, P., van Walree, C. A., Mehendale, N. C., Summerel, J., Morse, D. E., van Koten, G., & Klein Gebbink, R. J. M. (2009). Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments. Dalton Transactions, 22, 4289-4291. http://www.acs.org
Rutten, L., Wieczorek, B., Mannie, J-PBA., Kruithof, C. A., Dijkstra, H. P., Egmond, M. R., Lutz, M., Klein Gebbink, R. J. M., Gros, P., & van Koten, G. (2009). Solid-state structural characterization of cutinase-ECE-pincer-metal hybrids. Chemistry-A European Journal, 15(17), 4270-4280.
Virboul, M. A. N., Lutz, M., Siegler, M. A. M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2009). One-Pot Synthesis and Immobilisation of Sulfonate-Tethered N-Heterocyclic Carbene Complexes on Polycationic Dendrimers. Chemistry-A European Journal, 15(39), 9981-9986.
Bonnet, S. A., Li, J., Siegler, M. A. M., von Chrzanowski, L. S., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2009). Synthesis and resolution of Planar-Chiral Ruthenium-Palladium complexes with ECE pincer ligands. Chemistry-A European Journal, 15(14), 3340-3343. http://www.wiley-vch.de
Wieczorek, B., Dijkstra, H. P., Egmond, M. R., Klein Gebbink, R. J. M., & van Koten, G. (2009). Incorporating ECE-pincer metal complexes as functional building blocks in semisynthetic metalloenzymes, supramolecular polypeptide hybrids, tamoxifen derivatives, biomarkers and sensors. Journal of Organometallic Chemistry, 694(6), 812-822. http://www.elsevier.com
Hausoul, P. J. C., Bruijnincx, P. C. A., Klein Gebbink, R. J. M., & Weckhuysen, B. M. (2009). Base-free Pd/TOMPP-Catalyzed Telomerization of 1,3-Butadiene with Carbohydrates and sugar alcohols. Chemistry & sustainability, energy & materials, 2(9), 855-858. https://doi.org/10.1002/cssc.200900115
Kruithof, C. A., Berger, A., Dijkstra, H. P., Soulimani, F., Visser, T., Lutz, M., Spek, A. L., Klein Gebbink, R. J. M., & van Koten, G. (2009). Sulfato-bridged ECE-pincer palladium(II) complexes: structures in the solid-state and in solution, and catalytic properties. Dalton Transactions, 2009(17), 3306-3314. http://www.acs.org
Bonnet, S. A., van Lenthe, J. H., Siegler, M. A. M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2009). Bimetallic η6,η1 NCN-pincer ruthenium palladium complexes with η6-RuCp coordination: synthesis, X-ray structures, and catalytic properties. Organometallics, 28, 2325-2333. http://www.acs.org
Li, J., Minnaard, A. J., Klein Gebbink, R. J. M., & van Koten, G. (2009). P'CP'-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines. Tetrahedron Letters, 50, 2232-2235. http://www.elsevier.com
McDonald, A. R., Mores, D., de Mello-Donega, C., van Walree, C. A., Klein Gebbink, R. J. M., Lutz, M., Spek, A. L., Meijerink, A., van Klink, G. P. M., & van Koten, G. (2009). Supramolecular Dendriphores: Anionic Organometallic Phosphors Embedded in Polycationic Dendritic Species. Organometallics, 28(4), 1082-1093.
Marie, S., Lutz, M., Spek, A. L., Klein Gebbink, R. J. M., van Koten, G., Kervarec, N., Michaud, F., Salaün, J. Y., & Jaffrès, P. A. (2009). Application of a base-induced [1,2]-rearrangement to synthesize thiophosphonate bidentate S(sp2)–N monoanionic ligand: Characterization of its silver and palladium complexes. Journal of Organometallic Chemistry, 694(25), 4001-4007.
Snelders, D. J. M., van Koten, G., & Klein Gebbink, R. J. M. (2009). Hexacationic Dendriphos ligands in the Pd-catalyzed Suzuki-Miyaura cross-coupling reaction: scope and mechanistic studies. Journal of the American Chemical Society, 131(32), 11407-11416. http://www.acs.org

2008

Wetenschappelijke publicaties

Palkovits, R., Kruithof, C. A., Nieddu, I., Klein-Gebbink, R. J. M., & Weckhuysen, B. M. (2008). Telomerization of crude glycerol towards new surfactant molecules. In DGMK Tagungsbericht 2008-3 - Preprints of the Conference "Future Feedstocks for Fuels and Chemicals" (3 ed., pp. 145-152). (DGMK Tagungsbericht; No. 3).
Palkovits, R., Nieddu, I., Klein Gebbink, R. J. M., & Weckhuysen, B. M. (2008). Methoxy functionalized palladium triphenylphosphine complexes: Active catalysts for the telomerization of crude glycerol. In American Chemical Society - 235th National Meeting, Abstracts of Scientific Papers (ACS National Meeting Book of Abstracts).
Bruijnincx, P. C. A., van Koten, G., & Klein Gebbink, R. J. M. (2008). Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies. Chemical Society Reviews, 37(12), 2716-2744.
https://dspace.library.uu.nl/bitstream/handle/1874/32821/2.ChemSoc.Rev.37%282008%292716-2744_Bruijnincx.pdf?sequence=1
Kruithof, C. A., Dijkstra, H. P., Lutz, M., Spek, A. L., Egmond, M. R., Klein Gebbink, R. J. M., & van Koten, G. (2008). Non-tethered organometallic phosphonate inhibitors for lipase inhibition: positioning of the metal center in the active site of cutinase. European Journal of Inorganic Chemistry, 2008(28), 4425-4432.
https://dspace.library.uu.nl/bitstream/handle/1874/33216/790.pdf?sequence=1
Palkovits, R., Nieddu, I., Kruithof, C. A., Klein Gebbink, R. J. M., & Weckhuysen, B. M. (2008). Palladium-based telomerization of1,3-buta diene with glycerol using methoxy-functionalized triphenylphosphine ligands. Chemistry-A European Journal, 14(29), 8995-9005.
https://dspace.library.uu.nl/bitstream/handle/1874/32835/4.Chem.Eur.J.14%282008%298995%2C%2520Palkovits.pdf?sequence=1
Lutz, M., Spek, A. L., van der Geer, E. P. L., van Koten, G., & Klein Gebbink, R. J. M. (2008). Indole-3-thiouronium nitrate. Acta crystallographica. Section E, Structure reports, E64(1), o194.
https://dspace.library.uu.nl/bitstream/handle/1874/32995/762.pdf?sequence=1
van der Geer, E. P. L., van den Brom, C. R., Arfaoui, I., Houssiau, L., Rudolf, P., van Koten, G., Klein Gebbink, R. J. M., & Hessen, B. (2008). A 3:1 site-differentiated [4Fe-4S] cluster immobilized on a self-assembled monolayer. Journal of Physical Chemistry C, 112(44), 17225-17230.
https://dspace.library.uu.nl/bitstream/handle/1874/33268/800.pdf?sequence=1
Gosiewska, S., Herreras Martinez, S. D., Lutz, M., Spek, A. L., Havenith, R. W. A., van Klink, G. P. M., van Koten, G., & Klein Gebbink, R. J. M. (2008). Synthesis, structure, and catalytic performance of diastereopure five-coordinated NCN-pincer palladium(II) complexes bearing bulky amino acid substituents. Organometallics, 27(11), 2549-2559.
https://dspace.library.uu.nl/bitstream/handle/1874/33022/782.pdf?sequence=1
Lutz, M., Spek, A. L., van der Geer, E. P. L., van Koten, G., & Klein Gebbink, R. J. M. (2008). Indole-3-thiouronium iodide. Acta crystallographica. Section E, Structure reports, E64(1), o195.
https://dspace.library.uu.nl/bitstream/handle/1874/32996/763.pdf?sequence=1
Dieng, T., Fraix, A., Salaün, J. Y., Dez, I., Klein Gebbink, R. J. M., van Koten, G., & Jaffrès, P. A. (2008). Synthesis of O,O-diethyl arylthiophosphonate from O-Aryl-O,O-diethylthiophosphate. Synlett, 2008(20), 3121-3124.
https://dspace.library.uu.nl/bitstream/handle/1874/33293/801.pdf?sequence=1
Bruijnincx, P. C. A., Viciano-Chumillas, M., Lutz, M., Spek, A. L., Reedijk, J., van Koten, G., & Klein Gebbink, R. J. M. (2008). Oxidative double dehalogenation of tetrachlorocatechol by a bio-inspired Cu II complex: formation of chloranilic acid. Chemistry-A European Journal, 14(18), 5567-5576.
https://dspace.library.uu.nl/bitstream/handle/1874/32825/3.Chem.Eur.J.14%282008%295567-5576_Bruijnincx.pdf?sequence=1
Gagliardo, M., Selander, N., Mehendale, N. C., van Koten, G., Klein Gebbink, R. J. M., & Szabó, K. J. (2008). Catalytic performance of symmetrical and unsymmetrical sulfur-containing pincer complexes: synthesis and tandem catalytic activity of the first PCS-pincer palladium complex. Chemistry-A European Journal, 14(16), 4800-4809.
https://dspace.library.uu.nl/bitstream/handle/1874/33015/781.pdf?sequence=1
Pijnenburg, N. J. M., Korstanje, T. J., van Koten, G., & Klein Gebbink, R. J. M. (2008). Palladacycles on dendrimers and star-shaped molecules. In J. Dupont, & M. Pfeffer (Eds.), Palladacycles: synthesis, characterization and applications (pp. 361-398). Wiley.
Suijkerbuijk, B. M. J. M., & Klein Gebbink, R. J. M. (2008). Merging porphyrins with organometallics: synthesis and applications. Angewandte Chemie-International Edition, 47(39), 7396-7421.
https://dspace.library.uu.nl/bitstream/handle/1874/33259/792.pdf?sequence=1
Bonnet, S. A., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2008). η6-Coordination of a ruthenium(II) organometallic fragment to the arene ring of N,C,N-pincer metal complexes. Organometallics, 27(2), 159-162.
https://dspace.library.uu.nl/bitstream/handle/1874/33021/778.pdf?sequence=1
Wadman, S. H., van der Geer, E. P. L., Havenith, R. W. A., Klein Gebbink, R. J. M., van Klink, G. P. M., & van Koten, G. (2008). Comment on “Theoretical studies on the ground states in [M(terpyridine)2]2+ and [M(4-(4-(t-butyl)phenyl)terpyridine)2]2+ (M = Fe, Ru, Os) and excited states in [Ru(terpyridine)2]2+ using density functional theory”. Journal of Organometallic Chemistry, 693(19), 3188-3190.
https://dspace.library.uu.nl/bitstream/handle/1874/33214/791.pdf?sequence=1

2007

Wetenschappelijke publicaties

Dijkstra, H. P., Sprong, H., Aerts, B. N. H., Kruithof, C. A., Egmond, M. R., & Klein Gebbink, R. J. M. (2007). Selective and diagnostic labelling of serine hydrolases with reactive phosphonate inhibitors. Organic & Biomolecular Chemistry, 6, 523-531.
Suijkerbuijk, B. M. J. M., Tooke, D. M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2007). One-Dimensional, Cofacial Porphyrin Polymers Formed by Self-Assembly of meso-Tetrakis(ERE Donor) Zinc(II) Porphyrins. Chemistry - An Asian Journal, 2(7), 889-903.
https://dspace.library.uu.nl/bitstream/handle/1874/26805/754.pdf?sequence=1
Bruijnincx, P. C. A., Buurmans, I. L. C., Gosiewska, S., Moelands, M. A. H., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2007). Iron(II) Complexes with Bio-Inspired N,N,O Ligands as Oxidation Catalysts: Olefin Epoxidation and cis-Dihydroxylation. Chemistry-A European Journal, 14, 1228-1237.
https://dspace.library.uu.nl/bitstream/handle/1874/26894/07.pdf?sequence=1
Beale, A. M., Mesu, J. G., Kervinen, K. P., Visser, T., Soulimani, F., Bruijnincx, P. C. A., Klein Gebbink, R. J. M., van Koten, G., & Weckhuysen, B. M. (2007). Bio-inspired manipulation of catalytic sites via immobilization of metal ion complexes in zeolites. Studies in Surface Science and Catalysis, 170(2), 1546-1551.
https://dspace.library.uu.nl/bitstream/handle/1874/26824/760.pdf?sequence=1
McDonagh, C., O'Conghaile, P., Klein Gebbink, R. J. M., & O'Leary, P. F. (2007). Electrostatic immobilisation of copper(I) and copper(II) bis(oxazolinyl)pyridine catalysts on silica: application to the synthesis of propargylamines via direct addition of terminal alkynes to imines. Tetrahedron Letters, 48(25), 4387-4390.
https://dspace.library.uu.nl/bitstream/handle/1874/26800/753.pdf?sequence=1
Mehendale, N. C., Sietsma, J. R. A., de Jong, K. P., van Walree, C. A., Klein Gebbink, R. J. M., & van Koten, G. (2007). PCP- and SCS-pincer palladium complexes immobilized on mesoporous silica: application in C-C bond formation reactions. Advanced synthesis & catalysis, 349(17-18), 2619-2630.
https://dspace.library.uu.nl/bitstream/handle/1874/26727/1_LWJ.pdf?sequence=1
van de Coevering, R., Bruijnincx, P. C. A., van Walree, C. A., Klein Gebbink, R. J. M., & van Koten, G. (2007). Dendritic host molecules with a polycationic core and an outer Shell of dodecyl groups. European Journal of Organic Chemistry, 2007(18), 2931-2939.
https://dspace.library.uu.nl/bitstream/handle/1874/26730/3_LWJ.pdf?sequence=1
Gosiewska, S., Permentier, HP., Bruins, A. P., van Koten, G., & Klein Gebbink, R. J. M. (2007). Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III) alkylperoxo complex. Dalton Transactions, 2007(31), 3365-3368.
https://dspace.library.uu.nl/bitstream/handle/1874/26803/756.pdf?sequence=1
von Chrzanowski, L. S., Lutz, M., Spek, A. L., Suijkerbuijk, B. M. J. M., & Klein Gebbink, R. J. M. (2007). {2,6-Bis[(dimethylamino-κN)methyl]-4-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}phenyl-κC1}(diiodine)iodidoplatinum(II) dichloromethane hemisolvate. Acta crystallographica. Section E, Structure reports, 63(5), m1223-m1225.
https://dspace.library.uu.nl/bitstream/handle/1874/26758/742.pdf?sequence=1
Suijkerbuijk, B. M. J. M., Aerts, B. N. H., Dijkstra, H. P., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2007). “Click” 1,2,3-triazoles as tunable ligands for late transition metal complexes. Dalton Transactions, 2007(13), 1273-1276.

2006

Wetenschappelijke publicaties

Gosiewska, S., Veld, M. H. I., de Pater, J. J. M., Bruijnincx, P. C. A., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2006). Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with l-proline chiral auxiliaries: mer η3-N,C,N versus square planar η4-N,C,N,O coordination. Tetrahedron Asymmetry, 17(4), 674-686. https://doi.org/10.1016/j.tetasy.2005.12.040
Gosiewska, S., Herreras Martinez, S. D., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2006). Diastereopure Cationic NCN-Pincer Palladium Complexes with Square Planar η4-N,C,N,O Coordination. European Journal of Inorganic Chemistry, 2006(22), 4600-4607. https://doi.org/10.1002/ejic.200600508
Gosiewska, S., Huis in‘t Veld, M., de Pater, J. J. M., Bruijnincx, P. C. A., Lutz, M., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2006). Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with L-proline chiral auxiliaries: mer g3-N,C,N versus square planar g4-N,C,N,O coordination. Tetrahedron-Asymmetry, 17(4), 674-686.
https://dspace.library.uu.nl/bitstream/handle/1874/20008/715.pdf?sequence=1

2005

Wetenschappelijke publicaties

Bruijnincx, PCA., Lutz, M., Spek, AL., van Faassen, EE., Weckhuysen, BM., van Koten, G., & Gebbink, RJMK. (2005). Bis(1-methylimidazol-2-yl)propionates and bis(1-methylbenzimidazol-2-yl)-propionates: A new family of biomimetic N,N,O Ligands - Synthesis, structures and Cu-II coordination complexes. European Journal of Inorganic Chemistry, (4), 779-787. https://doi.org/10.1002/ejic.200400830
Bruijnincx, P. C. A., Lutz, M. H., Spek, A. L., van Faassen, E. E. H., Weckhuysen, B. M., van Koten, G., & Klein Gebbink, R. J. M. (2005). Bis(1-methylimidazol-2-yl)propionates and Bis(1-methylbenzimidazol-2-yl)propionates: A New Family of Biomimetic N,N,O Ligands - Synthesis, Structures and CuII Coordination Complexes. European Journal of Inorganic Chemistry, 779-787.
https://dspace.library.uu.nl/bitstream/handle/1874/14698/ejic.200400830.pdf?sequence=1
Lutz, M., Spek, A. L., Kreiter, R., Klein Gebbink, R. J. M., & van Koten, G. (2005). trans-Dichlorobis(tris{4-[(dimethylamino)methyl]phenyl}phosphine)platinum(II). Acta crystallographica. Section E, Structure reports, E61(12), m2728-m2729.
https://dspace.library.uu.nl/bitstream/handle/1874/14830/bt6791.pdf?sequence=1
Kruithof, C. A., Casado Lacabra, M. A., Guillena, G., Egmond, M. R., van der Kerk-van Hoof, A. C., Heck, A. J. R., Klein Gebbink, R. J. M., & van Koten, G. (2005). Lipase Active-Site-Directed Anchoring of Organometallics:Metallopincer/Protein Hybrids. Chemistry-A European Journal, 11, 6869-6877.
van de Coevering, R., Kreiter, R., Cardinali, F., van Koten, G., Nierengarten, J-F., & Klein Gebbink, R. J. M. (2005). An octa-cationic core-shell dendrimer as a molecular template for the assembly of anionic fullerene derivatives. Tetrahedron Letters, 46(19), 3353-3356.
van de Coevering, R., Kuil, M., Alfers, A. P., Visser, T., Lutz, M., Spek, A. L., Klein Gebbink, R. J. M., & van Koten, G. (2005). Organometallic Zwitterions: Arylpalladium(II) (Pincer) Complexes with a Tethered Sulfato Group as para-Substituent. Organometallics, 24(25), 6147-6158.
https://dspace.library.uu.nl/bitstream/handle/1874/14828/om050494e.pdf?sequence=2
van de Coevering, R., Klein Gebbink, R. J. M., & van Koten, G. (2005). Soluble organic supports for the non-covalent immobilization of homogeneous catalysts; modular approaches towards sustainable catalysts. Progress in Polymer Science, 30(3-4), 474-490.

2004

Wetenschappelijke publicaties

Tromp, M., Van Bokhoven, J. A., Slagt, M. Q., Klein Gebbink, R. J. M., Van Koten, G., Ramaker, D. E., & Koningsberger, D. C. (2004). AXAFS as a Probe of Charge Redistribution within Organometallic Complexes. Journal of the American Chemical Society, 126(13), 4090-4091. https://doi.org/10.1021/ja031885s
Slagt, M. Q., van Zwieten, D. A. P., Moerkerk, A. J. C. M., Klein Gebbink, R. J. M., & van Koten, G. (2004). NCN-Pincer Palladium Complexes with Multiple Anchoring Points for Functional Groups. Coordination Chemistry Reviews, 248, 2275-2282.
https://dspace.library.uu.nl/bitstream/handle/1874/25915/672.pdf?sequence=1
Tromp, M., Slagt, M. Q., Klein Gebbink, R. J. M., van Koten, G., Ramaker, D. E., & Koningsberger, D. C. (2004). Atomic XAFS as a Probe of Electron Transfer within Organometallic Complexes: Data analysis and Theoretical Calculations. Physical Chemistry Chemical Physics, 6, 4397-4406.
Stiriba, S-E., Slagt, M. Q., Kautz, H., Klein Gebbink, R. J. M., Thomann, A., Frey, H., & van Koten, G. (2004). Synthesis and Supramolecular Association of Immobilized NCN-Pincer Platinum(II) Complexes on Hyperbranched Polyglycerol Supports. Chemistry-A European Journal, 10, 1267-1273.
https://dspace.library.uu.nl/bitstream/handle/1874/25911/681.pdf?sequence=1
O'Leary, P. F., Krosveld, N. P., de Jong, K. P., van Koten, G., & Klein Gebbink, R. J. M. (2004). Facile and rapid immobilization of copper(II) bis(oxazoline) catalysts on silica: application to Diels-Alder reactions, recycling, and unexpected effects on enantioselectivity. Tetrahedron Letters, 45, 3177-3180.
https://dspace.library.uu.nl/bitstream/handle/1874/26160/Tettra.Lett.-O%27Leary-2004.pdf?sequence=1
Suijkerbuijk, B. M. J. M., Lutz, M. H., Spek, A. L., van Koten, G., & Klein Gebbink, R. J. M. (2004). Pincer-Porphyrin Hybrids. Organic Letters, 6(18), 3023-3026.
https://dspace.library.uu.nl/bitstream/handle/1874/14589/670.pdf?sequence=1
Slagt, M. Q., Rodriguez, G., Grutters, M. M. P., Klein Gebbink, R. J. M., Klopper, W. M., Jenneskens, L. W., Lutz, M. H., Spek, A. L., & van Koten, G. (2004). Synthesis and Properties of para-Substituted NCN-Pincer Palladium and Platinum Complexes. Chemistry-A European Journal, 10, 1331-1344.
https://dspace.library.uu.nl/bitstream/handle/1874/14431/10.1002-chem.200305336.pdf?sequence=1
Chase, P. A., Klein Gebbink, R. J. M., & van Koten, G. (2004). Where Organometallics and Dendrimers Merge: The Incorporation of Organometallic Species into Dendritic Molecules. Journal of Organometallic Chemistry, 689, 4016-4054.
https://dspace.library.uu.nl/bitstream/handle/1874/25912/675.pdf?sequence=1

2003

Wetenschappelijke publicaties

Klein Gebbink, R. J. M., Watanabe, M., Pratt, R. C., & Stack, T. D. P. (2003). Oxidatively robust monophenolate-copper(II) complexes as potential models of galactose oxidase. Chemical Communications, (5), 630-631.
Chuchuryukin, A. V., Dijkstra, H. P., Suijkerbuijk, B. M. J. M., Klein Gebbink, R. J. M., van Klink, G. P. M., Mills, A. M., Spek, A. L., & van Koten, G. (2003). Template-directed synthesis of macroheterocycles by ring-closing metathesis of olefin-substituted pyridines in the coordination sphere of triplatinum complex. Russian Journal of Organic Chemstry, 39, 422-429.
https://dspace.library.uu.nl/bitstream/handle/1874/6597/13084.pdf?sequence=2
Kreiter, R., Klein Gebbink, R. J. M., & van Koten, G. (2003). Design and synthesis of tris[bis(benzylammonium)aryl]phosphines with bulky meta-substituents. Tetrahedron, 59, 3989-3997.
https://dspace.library.uu.nl/bitstream/handle/1874/6188/13064.pdf?sequence=2
Slagt, M. Q., Dijkstra, H. P., McDonald, A. R., Klein Gebbink, R. J. M., Lutz, M. H., Ellis, D. D., Mills, A. M., Spek, A. L., & van Koten, G. (2003). Self-Assembly of p-Nitro NCN-Pincer Palladium Complexes into Dimers through Electron Donor-Acceptor Interactions. Organometallics, 22, 27-29.
https://dspace.library.uu.nl/bitstream/handle/1874/14315/10.1021-om020743o.pdf?sequence=1
Slagt, M. Q., Jastrzebski, J. T. B. H., Klein Gebbink, R. J. M., van Ramesdonk, H. J., Verhoeven, J., Ellis, D. D., Spek, A. L., & van Koten, G. (2003). Pyrenoxy-based NCN-pincer palladium(II) molecular tweezers: synthesis, properties in solution and catalysis. European Journal of Organic Chemistry, 1692-1703.
https://dspace.library.uu.nl/bitstream/handle/1874/14316/10.1002-ejoc.200210601.pdf?sequence=1
Guillena, G., Kreiter, R., van de Coevering, R., Klein Gebbink, R. J. M., van Koten, G., Mazón, P., Chinchilla, R., & Nájera, C. (2003). Chiroptical properties and applications in PTC of new dendritic cinchonidine-derived ammonium salt. Tetrahedron: Asymmetry, 14, 3705-3712.
https://dspace.library.uu.nl/bitstream/handle/1874/6143/13077.pdf?sequence=2

2002

Wetenschappelijke publicaties

Klein Gebbink, R. J. M., Jonas, R. T., Goldsmith, C. R., & Stack, T. D. P. (2002). A periodic walk: A series of first-row transition metal complexes with the pentadentate ligand PY5. Inorganic Chemistry, 41(18), 4633-4641. https://doi.org/10.1021/ic025617r
Slagt, M. Q., Stiriba, S-E., Klein Gebbink, R. J. M., Kautz, H., Frey, H., & van Koten, G. (2002). Encapsulation of hydrophilic pincer-platinum(II) complexes in amphiphilic hyperbranched polyglycerol nanocapsules. Macromolecules, 35, 5734-5737.
https://dspace.library.uu.nl/bitstream/handle/1874/6219/13057.pdf?sequence=2
Suijkerbuijk, B. M. J. M., Slagt, M. Q., Klein Gebbink, R. J. M., Lutz, M., Spek, A. L., & van Koten, G. (2002). Platinum-pincer introduction using active ester chemistry. Tetrahedron Letters, 43, 6565-6568.
https://dspace.library.uu.nl/bitstream/handle/1874/14929/10.1016-S0040-4039%2802%2901468-5.pdf?sequence=1
Klein Gebbink, R. J. M., Kruithof, C. A., van Klink, G. P. M., & van Koten, G. (2002). Dendritic supports in organic synthesis. Reviews in Molecular Biotechnology, 90, 183-193.
https://dspace.library.uu.nl/bitstream/handle/1874/6185/12720.pdf?sequence=2
van de Coevering, R., Kuil, M., Klein Gebbink, R. J. M., & van Koten, G. (2002). A polycationic dendrimer as noncovalent support for anionic organometallic complexes. Chem. Commun., 1636-1637.
Mazón, P., Chinchilla, R., Nájera, C., Guillena, G., Kreiter, R., Klein Gebbink, R. J. M., & van Koten, G. (2002). Unexpected metal base-depentdent inversion of the enantioselectivity in the asymmetric synthesis of α-amino acids using phase-transfer catalysts derived from cinchonidine. Tetrahedron: Asymmetry, 13, 2181-2185.
https://dspace.library.uu.nl/bitstream/handle/1874/6655/12883.pdf?sequence=2

2001

Wetenschappelijke publicaties

Kreiter, R., Kleij, A. W., Klein Gebbink, R. J. M., & van Koten, G. (2001). Dendritic Catalysts. In Topics in Current Chemistry
Kleij, A. W., van de Coevering, R., Klein Gebbink, R. J. M., Noordman, A. M., Spek, A. L., & van Koten, G. (2001). Polycationic (Mixed) Core-Shell Dendrimers for Binding and Delivery of Inorganic/Organic Substrates. Chemistry-A European Journal, 7, 181-192.

2000

Wetenschappelijke publicaties

Kleij, A. W., Gossage, R. A., Klein Gebbink, R. J. M., Brinkmann, N., Reijerse, E. J., Kragl, U., Lutz, M., Spek, A. L., & Van Koten, G. (2000). A "Dendritic Effect" in homogeneous catalysis with carbosilane-supported arylnickel(II) catalysts: Observation of active-site proximity effects in atom-transfer radical addition. Journal of the American Chemical Society, 122(49), 12112-12124. https://doi.org/10.1021/ja0026612

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