PhD defence: Spectroscopy of the Catalytic Hydrogenation of CO and CO2


The scientific study described in this thesis aims to achieve understanding of the thermal behavior and thermal stability of nanostructured transition metal oxides (TMOs) by means of in-situ experimentation in the transmission electron microscope (TEM). TMO nanocrystals are proper candidate materials for catalysis, gas sensing, and biomedical applications. The properties at the nanoscale are different from those of the corresponding bulk materials due to surface effects and confinement effects.

The thermal evolution and stability of nanocrystals in different size ranges and in various shapes, consequently affect their performance in applications. This study used primarily in-situ TEM as the main method to achieve real-time inspection of changes taking place at elevated temperatures while imaging at high spatial resolution. The TMO nanocrystals investigated in this thesis include Co3O4, TiO2, MoO3 and WO3.

The common trend found for all TMO samples is that transformations to lower-valence state oxides, or eventually to pure metals, always occurred when heated at elevated temperatures in the electron microscope. The same transformations also occurred in the reference ex-situ experiments for most of the samples. We conclude that the (very low) partial oxygen pressure in the vacuum of the TEM column is of importance for the specific temperatures at which these transformations take place.

Considering changes in nanoparticle morphology, processes of coalescence and sublimation were often observed, and were sometimes found to be dependent on the areal concentration of dropcast nanoparticles. The study described in this thesis, confirms the wildly diverse behavior of nanoparticles.

Start date and time
End date and time
Academiegebouw, Domplein 29 & online (livestream link)
PhD candidate
I.C. ten Have
Spectroscopy of the Catalytic Hydrogenation of CO and CO2
PhD supervisor(s)
prof. dr. ir. B.M. Weckhuysen
dr. F. Meirer
More information
Full text via Utrecht University Repository